Catalysis and Zeolites

Catalysis and Zeolites
Author: Jens Weitkamp
Publisher: Springer Science & Business Media
Total Pages: 582
Release: 2013-04-17
Genre: Science
ISBN: 3662037645
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Zeolites occur in nature and have been known for almost 250 years as alumino silicate minerals. Examples are clinoptilolite, mordenite, offretite, ferrierite, erionite and chabazite. Today, most of these and many other zeolites are of great interest in heterogeneous catalysis, yet their naturally occurring forms are of limited value as catalysts because nature has not optimized their properties for catalytic applications and the naturally occurring zeolites almost always contain undesired impurity phases. It was only with the advent of synthetic zeolites in the period from about 1948 to 1959 (thanks to the pioneering work of R. M. Barrer and R. M. Milton) that this class of porous materials began to playa role in catalysis. A landmark event was the introduction of synthetic faujasites (zeolite X at first, zeolite Y slightly later) as catalysts in fluid catalytic cracking (FCC) of heavy petroleum distillates in 1962, one of the most important chemical processes with a worldwide capacity of the order of 500 million t/a. Compared to the previously used amorphous silica-alumina catalysts, the zeolites were not only orders of magnitude more active, which enabled drastic process engineering improvements to be made, but they also brought about a significant increase in the yield of the target product, viz. motor gasoline. With the huge FCC capacity worldwide, the added value of this yield enhancement is of the order of 10 billion US $ per year.

Zeolites and Their Applications

Zeolites and Their Applications
Author: Mohamed Nageeb Rashed
Publisher: BoD – Books on Demand
Total Pages: 189
Release: 2018-06-27
Genre: Science
ISBN: 1789233429
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Zeolites are hydrated aluminosilicate minerals of the family of microporous solids. According to the US Geological Survey, there are about 40 naturally occurring zeolites, forming in sedimentary and volcanic rocks. The most commonly mined forms include clinoptilolite, chabazite and mordenite. There are over 200 synthetic zeolites. For their abundance, natural and synthetic zeolites are widely used in the industry, agriculture, water treatment, wastewater treatment and as dietary supplements to treat diarrhea, autism, cancer and other. This book Zeolites and Their Applications deals with several aspects of zeolite morphology, synthesis and applications. The book is divided into three sections and structured into nine chapters. The first section includes the introductory chapter, the second section explains mineralogy, morphology and synthesis of zeolites and the third section focuses on the different applications of both natural and synthetic zeolites. So, in this book, the readers will obtain updated information on mineralogy, morphology, synthesis and application of zeolites. Scientists from different scientific fields reported in this book their findings.

Zeolites in Catalysis

Zeolites in Catalysis
Author: Jiří Čejka
Publisher: Royal Society of Chemistry
Total Pages: 547
Release: 2017-06-07
Genre: Science
ISBN: 1782627847
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Accessible references for researchers and industrialists in this exciting field, covering both developments and applications of catalysis.

Zeolites and Zeolite-like Materials

Zeolites and Zeolite-like Materials
Author: Bert Sels
Publisher: Elsevier
Total Pages: 475
Release: 2016-07-29
Genre: Technology & Engineering
ISBN: 0444635149
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Zeolites and Zeolite-like Materials offers a comprehensive and up-to-date review of the important areas of zeolite synthesis, characterization, and applications. Its chapters are written in an educational, easy-to-understand format for a generation of young zeolite chemists, especially those who are just starting research on the topic and need a reference that not only reflects the current state of zeolite research, but also identifies gaps and opportunities. The book demonstrates various applications of zeolites in heterogeneous catalysis and biomass conversion and identifies the endless possibilities that exist for this class of materials, their structures, functions, and future applications. In addition, it demonstrates that zeolite-like materials should be regarded as a living body developing towards new modern applications, thereby responding to the needs of modern technology challenges, including biomass conversion, medicine, laser techniques, and nanomaterial design, etc. The book will be of interest not only to zeolite-focused researchers, but also to a broad scientific and non-scientific audience. Provides a comprehensive review of the literature pertaining to zeolites and zeolite-like materials since 2000 Covers the chemistry of novel zeolite-like materials such as Metal-Organic Frameworks (MOFs), Covalent Organic Frameworks (COFs), hierarchical zeolite materials, new mesoporous and composite zeolite-like micro/mesoporous materials Presents essential information of the new zeolite-like structures, with a balanced coverage of the most important areas of the zeolite research (synthesis, characterization, adsorption, catalysis, new applications of zeolites and zeolite-like materials) Contains chapters prepared by known specialists who are members of the International Zeolite Association

Zeolites

Zeolites
Author: B. Držaj
Publisher: Elsevier
Total Pages: 707
Release: 2011-09-22
Genre: Technology & Engineering
ISBN: 0080960588
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The synthesis of zeolites with desired structure and properties is of great importance for the preparation of highly active and selective catalysts for inorganic and organic reactions. The zeolite matrix offers unique possibilities for carrying out molecular shape-selective catalysis and this places the zeolite matrices among the most successful tools used in molecular engineering on a large scale.These proceedings cover the most recent developments in the fields of synthesis, structure determination and technological use of zeolites. The papers give detailed explanations of the processes involved in the mechanisms of zeolite synthesis. Special attention is focussed on complex ionic equilibria which occur in the starting hydrogel, to the ``templating effect'' and to the kinetics of zeolite formation. New powerful methods for structure determination of these materials, which usually consist of small crystals, are presented e.g. neutron diffraction and X-ray diffraction using synchrotron radiation. The distribution of tetrahedrally coordinated framework-constituent elements and their interaction with adsorbates is revealed by using high magnetic field nuclear magnetic resonance with sample spinning at ``magic'' angle (MAS NMR).Quite a number of articles are devoted to the dependence of the physico-chemical properties of zeolites on the parameters set during their synthesis. Descriptions are given of the possible technological use of synthetic zeolites in the fields of adsorption, catalysis, the production of laundry detergents, the removal of radioactive wastes, and the technological use of natural zeolites in the fields of animal feeding, municipal water treatment, paper and cement production, and energy storage. This book will be of interest to scientists working in the fields of catalysis, surface science, inorganic chemistry, materials science, petrochemistry, solid state physics, crystallography and geology.

Atlas of Zeolite Framework Types

Atlas of Zeolite Framework Types
Author: Ch. Baerlocher
Publisher: Elsevier
Total Pages: 405
Release: 2007-09-12
Genre: Technology & Engineering
ISBN: 0080554342
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Zeolite scientists, whether they are working in synthesis, catalysis, characterization or application development, use the Atlas of Zeolite Framework Types as a reference. It describes the main features of all of the confirmed zeolite framework structures, and gives references to the relevant primary structural literature. Since the last edition 34 more framwork types have been approved and are described in this new edition. A further new feature will be that characteristic building units will be listed for each of the framework types.Zeolites and their analogs are used as desiccants, as water softeners, as shape-selective acid catalysts, as molecular sieves, as concentrators of radioactive isotopes, as blood clotting agents, and even as additives to animal feeds. Recently, their suitability as hosts for nanometer spacing of atomic clusters has also been demonstrated. These diverse applications are a reflection of the fascinating structures of these microporous materials. Each time a new zeolite framework structure is reported, it is examined by the Structure Commission of the International Zeolite Association (IZA-SC), and if it is found to be unique and to conform to the IZA-SC's definition of a zeolite, it is assigned a 3-letter framework type code. This code is part of the official IUPAC nomenclature for microporous materials. The Atlas of Zeolite Framework Types is essentially a compilation of data for each of these confirmed framework types. These data include a stereo drawing showing the framework connectivity, features that characterize the idealized framework structure, a list of materials with this framework type, information on the type material that was used to establish the framework type, and stereo drawings of the pore openings of the type material. Clear stereo drawings of each of the framework types Description of the features of the framework type, allowing readers to quickly see if the framework type is suitable to their needs References to isotypic materials, readers can quickly identify related materials and consult the appropriate reference

Handbook of Zeolites

Handbook of Zeolites
Author: T. W. Wong
Publisher:
Total Pages: 704
Release: 2009
Genre: Science
ISBN:
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Zeolites are microporous crystalline solids with well-defined structures. Generally they contain silicon, aluminium and oxygen in their framework and cations, water and/or other molecules within their pores. Many occur naturally as minerals, and are extensively mined in many parts of the world. Others are synthetic, and are made commercially for specific uses, or produced by research scientists trying to understand more about their chemistry. Because of their unique porous properties, zeolites are used in a variety of applications with a global market of several million tonnes per annum. In the western world, major uses are in petrochemical cracking, ion-exchange (water softening and purification), and in the separation and removal of gases and solvents. Other applications are in agriculture, animal husbandry and construction. They are often also referred to as molecular sieves. This book presents leading research from around the world.

Chemistry of Zeolites and Related Porous Materials

Chemistry of Zeolites and Related Porous Materials
Author: Ruren Xu
Publisher: John Wiley & Sons
Total Pages: 616
Release: 2009-05-29
Genre: Science
ISBN: 0470822368
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Widely used in adsorption, catalysis and ion exchange, the family of molecular sieves such as zeolites has been greatly extended and many advances have recently been achieved in the field of molecular sieves synthesis and related porous materials. Chemistry of Zeolites and Related Porous Materials focuses on the synthetic and structural chemistry of the major types of molecular sieves. It offers a systematic introduction to and an in-depth discussion of microporous, mesoporous, and macroporous materials and also includes metal-organic frameworks. Provides focused coverage of the key aspects of molecular sieves Features two frontier subjects: molecular engineering and host-guest advanced materials Comprehensively covers both theory and application with particular emphasis on industrial uses This book is essential reading for researches in the chemical and materials industries and research institutions. The book is also indispensable for researches and engineers in R&D (for catalysis) divisions of companies in petroleum refining and the petrochemical and fine chemical industries.

Mesoporous Zeolites

Mesoporous Zeolites
Author: Javier García-Martínez
Publisher: John Wiley & Sons
Total Pages: 608
Release: 2015-05-26
Genre: Technology & Engineering
ISBN: 3527335749
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Authored by a top-level team of both academic and industrial researchers in the field, this is an up-to-date review of mesoporous zeolites. The leading experts cover novel preparation methods that allow for a purpose-oriented fine-tuning of zeolite properties, as well as the related materials, discussing the specific characterization methods and the applications in close relation to each individual preparation approach. The result is a self-contained treatment of the different classes of mesoporous zeolites. With its academic insights and practical relevance this is a comprehensive handbook for researchers in the field and related areas, as well as for developers from the chemical industry.

Zeolites and Catalysis

Zeolites and Catalysis
Author: Jiri Cejka
Publisher: John Wiley & Sons
Total Pages: 918
Release: 2010-05-27
Genre: Technology & Engineering
ISBN: 9783527630301
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This indispensable two-volume handbook covers everything on this hot research field. The first part deals with the synthesis, modification, characterization and application of catalytic active zeolites, while the second focuses on such reaction types as cracking, hydrocracking, isomerization, reforming and other industrially important topics. Edited by a highly experienced and internationally renowned team with chapters written by the "Who's Who" of zeolite research.