Vanadium and Chromium Complexes Supported by Sterically Demanding Ligands

Vanadium and Chromium Complexes Supported by Sterically Demanding Ligands
Author: Nathan Christopher Smythe
Publisher:
Total Pages: 414
Release: 2006
Genre:
ISBN:

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(Cont.) Chapter 4. TRAP (P(CH2CH2NH2)3), a phosphine containing analogue to TREN (N(CH2CH2NH2)3) was synthesized from PH3, but suitable conditions for arylation of the amine arms could not be found. Using the "pre-arylated" arm BrCH2CH2N(BOC)HIPT (BOC = tert-butoxycarbonyl; HIPT = 3,5-(2,4,6-i-Pr3C6H2)2C6H3) in the reaction with PH3 resulted in the isolation of H2PCH2CH2N(BOC)HIPT, but further substitution was unsuccessful. HIPTBr could be converted to HIPTNH2 using benzophenone imine and a rac-BINAP (2,2'-bis(diphenylphosphino)-1,1'-binaphthyl) supported Pd catalyst in preparation for DCC (dicyclohexylcarbodiimide) mediated coupling to tris-(3-propylcarboxylicacid)phosphine.

Live Hard Die Young

Live Hard Die Young
Author: Damien Francis Reardon
Publisher:
Total Pages: 492
Release: 2001
Genre: Organometallic catalysts
ISBN:

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Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes II

Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes II
Author: Giuliano GIAMBASTIANI
Publisher: Springer Science & Business Media
Total Pages: 272
Release: 2011-05-19
Genre: Science
ISBN: 9400706960

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Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes II: State-of-the-art and Perspectives provides a critical review of the state-of-the-art developments in industrially relevant processes connected to efficient and selective olefin upgrading. Specific attention is devoted to catalysts containing imine- and amine-based ligands. All the chapters in this book have been designed to provide a systematic account of the vast amount of information available for this type of catalyst as well as to highlight the factors that ultimately control the catalyst’s performance and productivity. A comprehensive panorama of catalyst precursors is presented, spanning from group 10 α-diimine complexes and iron and cobalt 2,6-bis(imino)pyridine derivatives, to vanadium, chromium, titanium, zirconium and lanthanide complexes supported by nitrogen-containing ligands. The authors of this collective work are currently involved in the development of imine-based catalysts for efficient and selective olefin upgrading and the majority of them have dedicated most of their scientific career to this important field. In writing this book, their major goal is to transfer as many ideas and experiences as possible to the global audience of scientists engaged in this area of research.

Preparation, Characterisation and Reactivity of Low Oxidation State d-Block Metal Complexes Stabilised by Extremely Bulky Amide Ligands

Preparation, Characterisation and Reactivity of Low Oxidation State d-Block Metal Complexes Stabilised by Extremely Bulky Amide Ligands
Author: Jamie Hicks
Publisher: Springer
Total Pages: 214
Release: 2016-10-24
Genre: Science
ISBN: 9811029059

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This thesis describes the synthesis and characterization of numerous metal-metal bonded complexes that are stabilized by extremely bulky amide ligands. It provides a comprehensive overview of the field, including discussions on groundbreaking complexes and reactions, before presenting in detail, exciting new findings from the PhD studies. The thesis appeals to researchers, professors and chemistry undergraduates with an interest in inorganic and/or organometallic chemistry.