Transition Metal Carbene Complexes

Transition Metal Carbene Complexes
Author: Karl Heinz Dötz
Publisher:
Total Pages: 282
Release: 1983
Genre: Carbenes (Methylene compounds).
ISBN:

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Advances in Metal Carbene Chemistry

Advances in Metal Carbene Chemistry
Author: U. Schubert
Publisher: Springer Science & Business Media
Total Pages: 405
Release: 2012-12-06
Genre: Science
ISBN: 9400923171

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There are only few topics in organometallic chemistry, which have stimulated research activities in as many areas, as transition-metal carbene (alkylidene) complexes. About 25 years after the first planned synthesis of a carbene complex in E.O. Fischer's laboratory in Munich the NATO Advanced Research Workshop on Transition-Metal Carbene Complexes was the first meeting which,brought together scientists from different disciplines to discuss inorganic, organic, theoretical structural catalysis-related aspects of metal carbene chemistry. The 70th birthday of Professor E.O. Fischer was a good occasion for this enterprise. The organizers of the meeting (K.D. Dotz, Marburg; F.R. KreiBl, Munchen; U. Schubert, Wurzburg) were encouraged by the fact that most of the leading scientists in this area were able to participate in the workshop. The very high standard of the contributions is reflected in this book, which contains papers from the majority of the participants. The Proceedings show the state of the art in metal carbene chemistry and will hopefully be a landmark in the development of this area of chemistry. Generous financial support for the workshop and for the preparation of this book was provided by the Scientific Affairs Division of NATO and some companies. The organizers also acknowledge the efforts of the staff of the Bildungs zentrum der Hans-Seidel-Stiftung in Wild bad Kreuth for creating a pleasant and stimulating atmosphere during the conference.

Metal Carbenes in Organic Synthesis

Metal Carbenes in Organic Synthesis
Author: K H Dtz
Publisher: Springer Science & Business Media
Total Pages: 396
Release: 2004-09-21
Genre: Science
ISBN: 9783540218333

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With contributions by numerous experts

N-Heterocyclic Carbenes in Transition Metal Catalysis

N-Heterocyclic Carbenes in Transition Metal Catalysis
Author: Frank Glorius
Publisher: Springer
Total Pages: 240
Release: 2007-02-05
Genre: Science
ISBN: 3540369309

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In this book leading experts have surveyed major areas of application of NHC metal complexes in catalysis. The authors have placed a special focus on nickel- and palladium-catalyzed reactions, on applications in metathesis reactions, on oxidation reactions and on the use of chiral NHC-based catalysts. This compilation is rounded out by an introductory chapter and a chapter dealing with synthetic routes to NHC metal complexes.

Transition Metal-Catalyzed Carbene Transformations

Transition Metal-Catalyzed Carbene Transformations
Author: Jianbo Wang
Publisher: John Wiley & Sons
Total Pages: 450
Release: 2022-05-16
Genre: Science
ISBN: 3527347992

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Presents an up-to-date overview of the rapidly growing field of carbene transformations Carbene transformations have had an enormous impact on catalysis and organometallic chemistry. With the growth of transition metal-catalyzed carbene transformations in recent decades, carbene transformations are today an important compound class in organic synthesis as well as in the pharmaceutical and agrochemical industries. Edited by leading experts in the field, Transition Metal-Catalyzed Carbene Transformations is a thorough summary of the most recent advances in the rapidly expanding research area. This authoritative volume covers different reaction types such as ring forming reactions and rearrangement reactions, details their conditions and properties, and provides readers with accurate information on a wide range of carbene reactions. Twelve in-depth chapters address topics including carbene C-H bond insertion in alkane functionalization, the application of engineered enzymes in asymmetric carbene transfer, progress in transition-metal-catalyzed cross-coupling using carbene precursors, and more. Throughout the text, the authors highlight novel catalytic systems, transformations, and applications of transition-metal-catalyzed carbene transfer. Highlights the dynamic nature of the field of transition-metal-catalyzed carbene transformations Summarizes the catalytic radical approach for selective carbene cyclopropanation, high enantioselectivity in X-H insertions, and bio-inspired carbene transformations Introduces chiral N,N'-dioxide and chiral guanidine-based catalysts and different transformations with gold catalysis Discusses approaches in cycloaddition reactions with metal carbenes and polymerization with carbene transformations Outlines multicomponent reactions through gem-difunctionalization and transition-metal-catalyzed cross-coupling using carbene precursors Transition Metal-Catalyzed Carbene Transformations is essential reading for all chemists involved in organometallics, including organic and inorganic chemists, catalytic chemists, and chemists working in industry.

N-Heterocyclic Carbenes in Transition Metal Catalysis

N-Heterocyclic Carbenes in Transition Metal Catalysis
Author: Frank Glorius
Publisher: Springer Science & Business Media
Total Pages: 241
Release: 2007
Genre: Science
ISBN: 3540369295

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In this book leading experts have surveyed major areas of application of NHC metal complexes in catalysis. The authors have placed a special focus on nickel- and palladium-catalyzed reactions, on applications in metathesis reactions, on oxidation reactions and on the use of chiral NHC-based catalysts. This compilation is rounded out by an introductory chapter and a chapter dealing with synthetic routes to NHC metal complexes.

Transition Metal Complexes of Neutral Eta1-Carbon Ligands

Transition Metal Complexes of Neutral Eta1-Carbon Ligands
Author: Remi Chauvin
Publisher: Springer Science & Business Media
Total Pages: 260
Release: 2010-01-12
Genre: Science
ISBN: 3642047211

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This book is part of a series that gives the broad scientific readership a comprehensive summary and critical overview of specific topics in the field of organometallic chemistry. This text focuses on transition metal complexes of neutral eta1-carbon ligands.

Transition Metals in the Synthesis of Complex Organic Molecules

Transition Metals in the Synthesis of Complex Organic Molecules
Author: Louis S. Hegedus
Publisher: University Science Books
Total Pages: 358
Release: 1999
Genre: Science
ISBN: 9781891389047

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This second edition offers easy access to the field of organotransition metal chemistry. The book covers the basics of transition metal chemistry, giving a practical introduction to organotransition reaction mechanisms.

Metal Carbenes in Organic Synthesis

Metal Carbenes in Organic Synthesis
Author: Florencio Zaragoza Dörwald
Publisher: John Wiley & Sons
Total Pages: 290
Release: 2008-09-26
Genre: Science
ISBN: 3527614079

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There are hardly more versatile compounds in organic synthesis than carbene complexes. The rapid development of new synthetic methods involving carbene complexes - stereoselective cyclopropanation, carbonyl olefination, olefin metathesis, etc. - reveals the value and high potential of these compounds. Their application ranges from the synthesis of fine chemicals to polymer production. This comprehensive, well structured handbook presents the fundamental principles and the recent advances in carbene complex chemistry. Arranged according to structure and reactivity, all relevant classes of carbene complexes, their generation, and application in organic synthesis are discussed in detail. Critically selected, up-to-date references and valuable experimental procedures await the reader. Every chemist searching for a concise introduction and reference work for carbene complex chemistry will welcome this practical guide. "...this concise presentation of all the aspects of the use of carbene complexes in synthesis will help provide the impetus for even more rapid developments in this field of research." R. H. Grubbs (Caltech)