The Organic Chemistry of Nickel

The Organic Chemistry of Nickel
Author: P.W. Jolly
Publisher: Elsevier
Total Pages: 533
Release: 2012-12-02
Genre: Science
ISBN: 0323146902

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The Organic Chemistry of Nickel, Volume I: Organonickel Complexes is devoted to a description of the organonickel complexes. The major goal is to provide a reference work, and for this reason a conventional layout has been adopted with separate chapters devoted to each type of organic ligand. In the interest of readability, known compounds have been assembled in tables at the end of each chapter, thereby allowing the text to be used for discussions of the general chemistry involved and to highlight the special reactions associated with nickel. Conscious of the needs of organometallic chemists, the authors included systems in which no nickel-carbon bond is involved. Among these is a chapter on the tetrakisligand nickel complexes and sections on dioxygen and azobenzene complexes. The nitrosyl complexes and complexes containing a metal-metal bond—topics frequently considered to be part of the domain of the organometallic chemist—have not received individual attention. Tables of the observed bond distances in organonickel complexes are provided as an Appendix; a short list of the more important review articles relevant to each organic ligand can be found at the end of each chapter.

The organic chemistry of nickel

The organic chemistry of nickel
Author: P. W. Jolly
Publisher:
Total Pages: 517
Release: 1974
Genre: Organonickel compounds
ISBN: 9780123334015

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Organic Synthesis

Organic Synthesis
Author: Peter W. Jolly
Publisher:
Total Pages: 400
Release: 1975
Genre: Organonickel compounds
ISBN: 9780123334022

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The Organic Chemistry of Nickel

The Organic Chemistry of Nickel
Author: P.W. Jolly
Publisher: Elsevier
Total Pages: 417
Release: 2012-12-02
Genre: Science
ISBN: 0323151302

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The Organic Chemistry of Nickel, Volume II: Organic Synthesis describes the chemistry of the organonickel complexes and the use of nickel in organic synthesis. Composed of six chapters, this volume starts with discussions on the oligomerization, co-oligomerization, and polymerization of olefins, followed by short accounts of the mechanistically related isomerization and hydrogenation of olefins, as well as the hydrosilylation and hydrocyanation reactions. Chapter II examines the oligomerization of acetylene and substituted alkynes, the co-oligomerization of alkynes with olefins, the related oligomerization of allene, including a number of telomerization reactions involving alkynes or allenes. Chapters III and IV describe the oligomerization, co-oligomerization, and polymerization of butadiene and substituted 1,3-dienes. Chapter V explores the coupling of organic halides in the presence of stoichiometric amounts of zerovalent nickel complexes, and the nickel-catalyzed cross-coupling reaction between organic halides and Grignard reagents. Lastly, Chapter VI emphasizes the carbonylation of alkynes, olefins, and organic halides using nickel complexes. This book will be of great value to organic chemists and researchers who are interested in the application of nickel complexes to organic synthesis.

Organic synthesis

Organic synthesis
Author: P. W. Jolly
Publisher:
Total Pages: 400
Release: 1975
Genre:
ISBN:

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