The Chemistry Of Macrocyclic Ligand Complexes
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Author | : Leonard F. Lindoy |
Publisher | : Cambridge University Press |
Total Pages | : 281 |
Release | : 1989-03-23 |
Genre | : Science |
ISBN | : 052125261X |
Download The Chemistry of Macrocyclic Ligand Complexes Book in PDF, Epub and Kindle
This book contains an overview of complex formation by macrocyclic ligand systems. The study of macrocyclic chemistry represents a major area of activity which impinges on a range of other areas in both chemistry and biochemistry. The field has characteristically yielded many interesting and unusual compounds. The text discusses the structures and properties of macrocyclic compounds; the synthesis of macrocycles; polyether crown and related systems; metal-ion and molecular recognition (host-guest chemistry); as well as kinetic, thermodynamic and electrochemical aspects of a range of macrocyclic systems. A discussion of the different categories of naturally occurring macrocycles is also included. Specialist and non-specialist alike will find this a useful text. Apart from serving as a convenient reference for established workers in the field, it should also prove useful to new graduate students as well as to researchers from other areas who seek a general introduction to the subject. The topics discussed also provide a suitable basis for a senior undergraduate or graduate course in macrocyclic chemistry and inorganic complexes.
Author | : Gordon Melson |
Publisher | : Springer Science & Business Media |
Total Pages | : 676 |
Release | : 2012-12-06 |
Genre | : Science |
ISBN | : 1461329280 |
Download Coordination Chemistry of Macrocyclic Compounds Book in PDF, Epub and Kindle
Chemists have been aware of the existence of coordination compounds con taining organic macrocyclic ligands since the first part of this century ; however, only during the past few years have they expanded research into the chemistry of these compounds. The expansion was initiated in the early 1960s by the synthesis and characterization of compounds containing some new macrocyclic ligands. The synthesis of compounds which may serve as model systems for some natural products containing large rings as ligands provided the main goal for the early expansion of research effort; indeed, a recurrent theme behind much of the reported chemistry has been the analogy between synthetic macrocyclic compounds and many natural-product systems. More recently, the emphases of reported research have ranged over the whole spectrum of chemistry, and the number of publications that discuss macrocyclic chemistry has increased at a dramatic rate. The completed research has been reported in a variety of journals throughout the world but there has been no previous attempt to bring the major developments together under one cover. This book, therefore, attempts to satisfy the need for a single source in which there is both a collection and a correlation of information concerning the coordination chemistry of macrocyclic compounds. The chapters in this book discuss various aspects of macrocyclic chemistry, and while these chapters as a whole constitute an in-depth survey of the state-of the-art of the field, each chapter is written as a complete unit.
Author | : Edwin C. Constable |
Publisher | : |
Total Pages | : 0 |
Release | : 2023 |
Genre | : Macrocyclic compounds |
ISBN | : 9780191992384 |
Download Coordination Chemistry of Macrocyclic Compounds Book in PDF, Epub and Kindle
'Coordination Chemistry of Macrocyclic Compounds' describes the coordination chemistry of macrocyclic ligands. Common types of ligands are introduced and strategies for the synthesis of the free ligands and their metal complexes are discussed. The unique thermodynamic and kinetic properties of macrocyclic complexes are discussed and applications of the ligands presented.
Author | : K. Gloe |
Publisher | : Springer Science & Business Media |
Total Pages | : 450 |
Release | : 2005-12-05 |
Genre | : Science |
ISBN | : 1402036876 |
Download Macrocyclic Chemistry Book in PDF, Epub and Kindle
Macrocyclic Chemistry: Current Trends and Future Perspectives illustrates essential concepts in this expanding research field covering both basic and applied studies. Written by well-known experts from around the world, the topics of the chapters range from new macrocyclic architectures with different functions and self-assembly processes through to the modeling and dynamics of such systems. The content also reflects on application possibilities in analytical chemistry, separation processes, material preparation and medicine. Thus this book serves as a creative source of research strategies and methodic tools. Providing an excellent overview of the field, this book will be a valuable resource for researchers in industry and academic institutions as well as for teachers of science and graduate students. This book is devoted to the long-standing tradition of the International Symposia on Macrocyclic Chemistry (ISMC) and published to coincide with the 30th meeting, Dresden, Germany.
Author | : Gordon Melson |
Publisher | : |
Total Pages | : 680 |
Release | : 1979-10-01 |
Genre | : |
ISBN | : 9781461329299 |
Download Coordination Chemistry of Macrocyclic Compounds Book in PDF, Epub and Kindle
Author | : J.H. Zagal |
Publisher | : Springer Science & Business Media |
Total Pages | : 828 |
Release | : 2007-07-16 |
Genre | : Science |
ISBN | : 0387284303 |
Download N4-Macrocyclic Metal Complexes Book in PDF, Epub and Kindle
In response to significant developments in sensor science and technology, this book offers insight into the various extended applications and developments of N4 macrocycle complexes in biomimetic electrocatalysis. Chapters are devoted to the chemistry, electronic and electrochemical properties of porphyrin- based polymetallated supramolecular redox catalysts and their applications in analytical and photoelectrochemical molecular devices; the use of porphyrins, phthalocyanines and related complexes as electrocatalysts for the detection of a wide variety of environmentally polluting and biologically relevant molecules; and the use of electropolymerized metalloporphyrin and metallophthalocyanine films as powerful materials for analytical tools, especially for sensing biologically relevant species.
Author | : Mohammad Mansoob Khan |
Publisher | : LAP Lambert Academic Publishing |
Total Pages | : 168 |
Release | : 2012-06 |
Genre | : |
ISBN | : 9783659142536 |
Download Chemistry of Dinucleating MacRocyclic Ligand and Their Complexes Book in PDF, Epub and Kindle
Macrocyclic ligands that can incorporate two or more metal ions giving homo- or hetero-dinuclear complexes are of considerable interest. Some of these hetero-dinuclear complexes are interesting as they mimic the active sites of metalloenzymes, such as cytochrome-c oxidase and bovine erythrocyte superoxide dismutase. Such systems are very helpful in investigating mutual influences of the two metal centers on electronic, magnetic, and electrochemical properties. Therefore, such types of system are very helpful in biological diagnostic applications. Research in inorganic chemistry has expanded in recent years by exploiting a variety of chelating ligands to modify and control the characteristics of metal ions in biological systems. Macrocyclic ligands offer the benefit of high stability complex formation and, through functionalization, the opportunity to modify the coordination environment. The pharmaceutical and bio-medical industry has yet to appreciate the impact coordination chemistry can have on the design of novel medicines. This may change the future as skilled multi-disciplinary experts may develop their investigation using a strategic approach to complex design.
Author | : Brian G. Cox |
Publisher | : Elsevier Publishing Company |
Total Pages | : 440 |
Release | : 1992 |
Genre | : Science |
ISBN | : |
Download Coordination and Transport Properties of Macrocyclic Compounds in Solution Book in PDF, Epub and Kindle
This book covers the fundamental physical principles of the selective complexation, extraction, and transport of ions and molecules by macrocyclic compounds - both natural and synthetic. It also treats the use of these compounds for the extraction and transport of substrates in chemical and biological systems. Included are solution kinetic and thermodynamic properties of the complexes, along with relevant experimental methods, complemented by solution and solid-state structures. General and specific methods for the synthesis of macro(poly)cyclic specialised ligands are described. The book is useful as additional reading for undergraduate courses in chemistry (e.g. inorganic complexation chemistry, analytical chemistry, solution kinetics, synthesis) and biochemistry (ion transport/membrane phenomena); for graduate students in chemistry and biochemistry; for research workers in macrocyclic chemistry and biophysical chemistry; and for industrial laboratories involved in metal ion extraction and recovery.
Author | : N. V. Gerbeleu |
Publisher | : John Wiley & Sons |
Total Pages | : 574 |
Release | : 2008-07-11 |
Genre | : Science |
ISBN | : 3527613811 |
Download Template Synthesis of Macrocyclic Compounds Book in PDF, Epub and Kindle
The synthesis of macrocycles is an art in itself. Template-controlled synthesis provides elegant access to fascinating macrocyclic structures. Polyazamacrocycles, crown ethers, cryptands, rotaxanes, knots -- the range of macrocyclic compounds is as broad as their potential application as molecular switches, in ion exchange, electron transfer or catalysis. This book provides authoritative information on all aspects of template-controlled macrocyclizations. It covers in depth the current state of research on template processes - novel synthetic techniques and mechanistic approaches. The critical discussion of the diverse synthetic routes includes the detailed characterization of the broad variety of macrocyclic products. References to applications of macrocyclic compounds and over 1,500 citations make this handbook an indispensable tool for chemists in academia and industry. Researchers in organic and supramolecular chemistry, biotechnology, and inorganic chemistry will find inspiration for the design, synthesis, and myriad uses of new synthetic macrocycles.
Author | : Reed Izatt |
Publisher | : Elsevier |
Total Pages | : 335 |
Release | : 2012-12-02 |
Genre | : Science |
ISBN | : 0323155480 |
Download Synthetic Multidentate Macrocyclic Compounds Book in PDF, Epub and Kindle
Synthetic Multidentate Macrocyclic Compounds attempts to bring together selected chapters in which the authors discuss in depth investigations in important areas of macrocycle research. The chapters deal mainly with macrocyclic compounds (saturated polyethers and their derivatives), and macrobicyclic compounds (cryptates). The book contains six chapters and opens with a first-hand account of the initial synthesis of the cyclic polyethers. This is followed by separate chapters on the synthesis of cyclic polyethers, polyether amines, and polyether sulfides; the synthesis of multidentate compounds; and the structure of synthetic macrocyclic compounds and their cation complexes. Subsequent chapters deal with the rates of reactions and the mechanism by which synthetic macrocyclic ligands complex substrates in solution; and commercial applications of the synthetic macrocyclic ligands. This book is primarily aimed at researchers and students in organic, physical, analytical, and inorganic chemistry, and in chemical engineering. However, it will also be of interest to many in the areas of biology, biochemistry, and physiology. Extensive literature references are found in each chapter.