Synthesis, Characterization, and Reactivity Studies of Iridium Complexes Bearing the Ligand Diphenylphosphidoboratabenzene
Author | : Luis Alfredo Arizpe |
Publisher | : |
Total Pages | : 60 |
Release | : 2011 |
Genre | : |
ISBN | : |
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The synthesis, structure, and reactivity properties of three iridium square planar complexes bearing the anionic phosphine ligand diphenylphosphidoboratabenzene (DPB) are described. Reactivity studies show a rate enhancement for the oxidative addition of a substituted benzyl bromide and Me3SnBr with DPB as a ligand in place of triphenylphosphine. Two products from the oxidative addition of p-chlorobenzyl bromide have been isolated and structurally characterized.