Synthesis and Structural Characterization of CCC-N-Heterocyclic Carbene (CCC-NHC) Pincer Complexes of Nickel
Author | : Paul Jerome Kelley |
Publisher | : |
Total Pages | : 148 |
Release | : 2010 |
Genre | : |
ISBN | : |
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Abstract: The recently reported methodology for concomitant triple C-H activation of a CCC-NHC pincer ligand precursor followed by transmetallation to late transition metals has been extended to include nickel. A very faint solid state fluorescence has been collected for the complexes reported. X-ray structural analysis of a representative compound exhibits a distorted square planar geometry. Issues with rapid halogen exchange have been found in some cases indicating increased liability of the halide ligand uncommon in comparable systems.