Stereochemistry Of Organometallic And Inorganic Compounds Stereochemical And Stereophysical Behaviour Of Macrocycles
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Author | : Ivan Bernal |
Publisher | : |
Total Pages | : |
Release | : 1986 |
Genre | : Inorganic compounds |
ISBN | : |
Download Stereochemistry of Organometallic and Inorganic Compounds: Stereochemcal and stereophysical behaviour of macrocycles Book in PDF, Epub and Kindle
Author | : Bozzano G Luisa |
Publisher | : Elsevier |
Total Pages | : 257 |
Release | : 2012-12-02 |
Genre | : Science |
ISBN | : 044459700X |
Download Stereochemical and Stereophysical Behaviour of Macrocycles Book in PDF, Epub and Kindle
Stereochemical and Stereophysical Behavior of Macrocycles deals with the stereochemical and stereophysical properties of macrocyclic ligands and their coordination compounds. More specifically, the stereochemistry of metallic macrocyclics is discussed, along with the relationship between the thermodynamics and stereochemistry of macrocyclics and cryptates. The stereochemical aspects of the macrocycles of second and third row transition elements are also examined. Comprised of three chapters, this volume begins with an introduction to the stereochemistry of metallic macrocyclics as well as their structure, together with the conformation of their chemical rings and the steric effects of their coordination geometry. The next chapter considers the relationship between the thermodynamics and stereochemistry of macrocyclics and cryptates, with particular reference to the macrocyclic and cryptate effect. Cation-ligand interactions and solvent effects upon complex formation are described, along with macrocyclic and macrobicyclic ligands having different donor atoms. The final chapter is devoted to the stereochemical aspects of the macrocycles of transition metal ions, with additional comments on the stereochemistry of copper and nickel in unusual oxidation states. This book will be of interest to inorganic chemists.
Author | : Ivan Bernal |
Publisher | : Elsevier Science & Technology |
Total Pages | : 246 |
Release | : 1987 |
Genre | : Science |
ISBN | : 9780444428158 |
Download Stereochemical and Stereophysical Behaviour of Macrocycles Book in PDF, Epub and Kindle
Stereochemical and Stereophysical Behaviour of Macrocycles...
Author | : Ivan Bernal |
Publisher | : |
Total Pages | : |
Release | : 1986 |
Genre | : Chemistry, Inorganic |
ISBN | : |
Download Stereochemistry of Organometallic and Inorganic Compounds: Steriochemical and stereophysical behaviour of macrocycles Book in PDF, Epub and Kindle
Author | : Bozzano G Luisa |
Publisher | : Elsevier |
Total Pages | : 395 |
Release | : 2012-12-02 |
Genre | : Science |
ISBN | : 0444597328 |
Download Stereochemistry of Organometallic and Inorganic Compounds Book in PDF, Epub and Kindle
The authors of this fourth volume in the series have reviewed the making and breaking of chemical bonds in a sophisticated manner. In particular, new pressures brought about by environmental concerns, larger demands for the medical and pharmaceutical sectors and economics of the market place are forcing us into demanding greater stereochemical control and better product yields for chemical reactions capable of producing useful products. The chapters are written by leading experts in this area and give excellent overviews of the strengths and weaknesses of the various methodologies.In Chapter 1 newer discoveries in such tried and true methods of C-C bond formation as alkylations and aldol reactions of metal enolates are reviewed. The author of Chapter 2 discusses the ability of ab-initio methods to justify the results of empirical observations in the field of transition metal derivatives of small molecules such as N2, CO2 and similar small molecules. Having established the strengths and weaknesses of the various approaches to such theoretical calculations, a more interesting approach to these methods is pursued, namely, their ability to predict, in those areas in which they are particularly strong and reliable, chemical and stereochemical events and/or results in advance of experiments, later carried out in the laboratory. Finally, Chapter 3 reviews the stereochemical results of electron transfer reactions in mononuclear copper compounds.
Author | : Alexander von Zelewsky |
Publisher | : John Wiley & Sons |
Total Pages | : 272 |
Release | : 1996-06-03 |
Genre | : Science |
ISBN | : 9780471955993 |
Download Stereochemistry of Coordination Compounds Book in PDF, Epub and Kindle
This well-illustrated and well-referenced book provides a systematic introduction to the modern aspects of the topographical stereochemistry of coordination compounds, which are made up of metal ions surrounded by other non-metal atoms, ions and molecules.
Author | : Gregory L. Geoffroy |
Publisher | : John Wiley & Sons |
Total Pages | : 366 |
Release | : 2009-09-17 |
Genre | : Science |
ISBN | : 0470147431 |
Download Topics in Inorganic and Organometallic Stereochemistry Book in PDF, Epub and Kindle
This volume is devoted entirely to inorganic and organometallic stereochemical subjects. Discusses the systematic notations that have been developed to satisfy the needs for a rational and systematic stereochemical nomenclature. Reviews the stereochemical aspects of the changes of bonding at carbon centers induced by metals, either catalytically or stoiciometrically. Also reviews the major achievements in current stereochemical research—the synthesis of asymmetric compounds mediated by transition metals. Discusses the structures of transition metal carbonyl clusters, summarizing recent progress in this expanding area and providing a semiquantitative rationalization of the structures for these clusters.
Author | : Ivan Bernal |
Publisher | : |
Total Pages | : 404 |
Release | : 1990 |
Genre | : Chemical bonds |
ISBN | : |
Download Stereochemical Control, Bonding, and Steric Rearrangements Book in PDF, Epub and Kindle
The authors of this fourth volume in the series have reviewed the making and breaking of chemical bonds in a sophisticated manner. In particular, new pressures brought about by environmental concerns, larger demands for the medical and pharmaceutical sectors and economics of the market place are forcing us into demanding greater stereochemical control and better product yields for chemical reactions capable of producing useful products. The chapters are written by leading experts in this area and give excellent overviews of the strengths and weaknesses of the various methodologies. In Chapter 1 newer discoveries in such tried and true methods of C-C bond formation as alkylations and aldol reactions of metal enolates are reviewed. The author of Chapter 2 discusses the ability of ab-initio methods to justify the results of empirical observations in the field of transition metal derivatives of small molecules such as N2, CO2 and similar small molecules. Having established the strengths and weaknesses of the various approaches to such theoretical calculations, a more interesting approach to these methods is pursued, namely, their ability to predict, in those areas in which they are particularly strong and reliable, chemical and stereochemical events and/or results in advance of experiments, later carried out in the laboratory. Finally, Chapter 3 reviews the stereochemical results of electron transfer reactions in mononuclear copper compounds.
Author | : M.-Z. Asfari |
Publisher | : Springer Science & Business Media |
Total Pages | : 692 |
Release | : 2007-05-08 |
Genre | : Science |
ISBN | : 0306475227 |
Download Calixarenes 2001 Book in PDF, Epub and Kindle
Calixarene chemistry, at the turn of the millennium, is a field approaching true maturity. In many areas, applications are real and important, and the arsenal of structures based on calixarenes provides tools effective in numerous areas of supramolecular chemistry. In this book, chapters contributed by a broad spectrum of international authors provide a variety of perspectives upon the progress and future of calixarene chemistry. Issues covered in depth include: Calixarene synthesis, with all its subtleties and sophistication. Forces at play in the inclusion of neutral and charged molecules by calixarenes. Theoretical analyses of calixarene properties. Dynamics and thermodynamics of calixarenes and their complexes. Nanocomposite construction based on calixarene aggregates. Calixarenes on surfaces. Analytical applications of calixarenes. Catalysis by calixarenes and their complexes. Resource recovery and waste treatment with calixarenes. New directions in calixarene chemistry. Hetero- and homo-calixarenes. Bioactive calixarenes. Coordination chemistry of calixarenes. Calixarenes in the solid state.
Author | : |
Publisher | : Elsevier |
Total Pages | : 321 |
Release | : 2001-07-31 |
Genre | : Science |
ISBN | : 0080548253 |
Download Advances in Organometallic Chemistry Book in PDF, Epub and Kindle
Almost all branches of chemistry and material science now interface with organometallic chemistry-the study of compounds containing carbon-metal bonds. Organometallic compounds range from species which are so reactive that they only have a transient existence at ambient temperatures to species which are thermally very stable. This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964.