Control of Polymerization Reactors

Control of Polymerization Reactors
Author: Joseph Schork
Publisher: Routledge
Total Pages: 378
Release: 2017-09-20
Genre: Science
ISBN: 1351457934

Download Control of Polymerization Reactors Book in PDF, Epub and Kindle

This reference and text provides an in-depth description of developments in control techniques and their application to polymerization reactors and offers important introductory background information on polymerization reaction engineering.;Discussing modelling, identification, linear, nonlinear and multivariable schemes, Control of Polymerization Reactors: presents all available techniques that can be used to control reactors properly for optimal performance; shows how to manipulate pivotal variables that affect reactor control; examines methods for deriving dynamic process models to improve reactor efficiency; reviews reactor control problems and points out end-use properties; supplies methods for measuring process variables, and ways to estimate variables that can't be measured; and explains how single-input, single-output (SISO) strategies can be effectively used for control.;Filled with illustrative examples to clarify concepts, including more than 730 figures, tables and equations, Control of Polymerization Reactors is intended for use as a reference for chemical, process development, process design, research and development, control systems, and polymer engineers; and polymer chemists and physicists; as well as a text for upper-level undergraduate and graduate students in polymerization reactor control courses.

Modeling, Simulation, Dynamic Optimization and Control of a Semibatch Emulsion Polymerization Process

Modeling, Simulation, Dynamic Optimization and Control of a Semibatch Emulsion Polymerization Process
Author: Iván-Dario Gil
Publisher:
Total Pages: 0
Release: 2014
Genre:
ISBN:

Download Modeling, Simulation, Dynamic Optimization and Control of a Semibatch Emulsion Polymerization Process Book in PDF, Epub and Kindle

In this work, modeling, simulation, dynamic optimization and nonlinear control of an industrial emulsion polymerization process to produce poly-vinyl acetate (PVAc) are proposed. The reaction is modeled as a two-phase system composed of an aqueous phase and a particle phase. A detailed model is used to calculate the weight average molecular weight, the number average molecular weight and the dispersity. The moments of the growing and dead chains are used to represent the state of the polymer and to calculate the molecular weight distribution (MWD). The case study corresponds to an industrial reactor operated at a chemical company in Bogotá. An industrial scale reactor (11 m3 of capacity) is simulated where a semi-batch emulsion polymerization reaction of vinyl acetate is performed. Dynamic optimization problem is solved directly using a Nonlinear Programming solver. Integration of differential equations is made using Runge-Kutta method. Three different optimization problems are solved from the more simplistic (only one control variable: reactor temperature) to the more complex (three control variables : reactor temperature, initiator flow rate and monomer flow rate) in order to minimize the reaction time. A reduction of 25% of the batch time is achieved with respect to the normal operating conditions applied at the company. The results show that is possible to minimize the reaction time while some polymer desired qualities (conversion, molecular weight and solids content) satisfy the defined constraints. A nonlinear geometric control technique by using input/output linearization is adapted to the reactor temperature control. An extended Kalman filter (EKF) is implemented to estimate unmeasured states and it is tested in different cases including a robustness study where model errors are introduced to verify its good performance. After verification of controller performance, some process changes were proposed in order to improve process productivity and polymer quality. Finally, the optimal temperature profile and optimal feed policies of the monomer and initiator, obtained in a dynamic optimization step, are used to provide the optimal set points for the nonlinear control. The results show that the nonlinear controller designed here is appropriate to follow the optimal temperature trajectories calculated previously.

Advances in Polymer Reaction Engineering

Advances in Polymer Reaction Engineering
Author:
Publisher: Academic Press
Total Pages: 350
Release: 2020-10-31
Genre: Technology & Engineering
ISBN: 0128215224

Download Advances in Polymer Reaction Engineering Book in PDF, Epub and Kindle

Advances in Polymer Reaction Engineering, Volume 56 in the Advances in Chemical Engineering series is aimed at reporting the latest advances in the field of polymer synthesis. Chapters in this new release include Polymer reaction engineering and composition control in free radical copolymers, Reactor control and on-line process monitoring in free radical emulsion polymerization, Exploiting pulsed laser polymerization to retrieve intrinsic kinetic parameters in radical polymerization, 3D printing in chemical engineering, Renewable source monomers in waterborne polymer dispersions, Importance of models and digitalization in Polymer Reaction Engineering, Recent Advances in Modelling of Radical Polymerization, and more. Covers recent advances in the control and monitoring of polymerization processes and in reactor configurations Provides modelling of polymerization reactions and up-to-date approaches to estimate reaction rate constants Includes authoritative opinions from experts in academia and industry

Emulsion Polymerization and Its Applications in Industry

Emulsion Polymerization and Its Applications in Industry
Author: V. I. Eliseeva
Publisher: Springer Science & Business Media
Total Pages: 231
Release: 2012-12-06
Genre: Technology & Engineering
ISBN: 1468416413

Download Emulsion Polymerization and Its Applications in Industry Book in PDF, Epub and Kindle

There is a large body of Soviet work on emulsion polymerization, spanning a period of over three decades, that has been published primarily in the Russian language. Most of this has remained untranslated into English and hence un available to most other scientists. The value of this book lies primarily in the fact that it brings together the most important of these Soviet contributions, along with comment and analysis by the authors, who may be considered among the foremost authorities in this field in the Soviet Union. But the hundreds of literature citations go far beyond the borders of the Soviet Union and serve as an excellent bibliography of the world literature on emulsion polymerization up to the time this book was written. The book covers both fundamental and applied aspects. In the former are included discussions of particle formation mechanisms, a comprehensive theory of emulsion polymerization, copolymerization of polar monomers, and particle morphology and its implications with regard to derived film properties. Among the applied aspects are discussions of continuous emulsion polymerization, both tubular reactors and continuous stirred tank cascades, and various aspects con cerning the manufacture of some of the most important monomers, such as styrene, butadiene, vinyl acetate, methyl methacrylate, acrylonitrile, and chloroprene. This book will be an indispensable reference source for scientists who are entering the field as well as those who are experienced and who have wanted a ready access to this large body of literature.

Chemistry and Technology of Emulsion Polymerisation

Chemistry and Technology of Emulsion Polymerisation
Author: A. M. van Herk
Publisher: John Wiley & Sons
Total Pages: 332
Release: 2013-05-13
Genre: Technology & Engineering
ISBN: 1118638360

Download Chemistry and Technology of Emulsion Polymerisation Book in PDF, Epub and Kindle

Chemistry and Technology of Emulsion Polymerisation 2e provides a practical and intuitive explanation of emulsion polymerization, in combination with both conventional and controlled radical polymerization. For those working in industry, coupling theory with everyday practice can be difficult. By carefully explaining the principles of the reaction, based on well-designed experimental investigation, the book explains how the principles relate to practical application. The second edition of this book includes a new chapter on morphology of latex particles, a rapidly progressing area where modelling the thermodynamic and kinetic aspects of phase separation and morphology has developed into a mature and powerful tool to predict and control morphology of latex particles. Another area that is rapidly progressing is the application of controlled radical polymerisation in emulsion polymerization. Controlled radical polymerisation is used in aiding encapsulation of inorganic particles like pigment particles and clay platelets. These latest developments are included in the second edition.

Principles and Applications of Emulsion Polymerization

Principles and Applications of Emulsion Polymerization
Author: Chorng-Shyan Chern
Publisher: John Wiley & Sons
Total Pages: 268
Release: 2008-10-06
Genre: Science
ISBN: 0470377933

Download Principles and Applications of Emulsion Polymerization Book in PDF, Epub and Kindle

Up-to-date coverage of methods of emulsion polymerization This book provides a comprehensive reference on emulsion polymerization methods,focusing on the fundamental mechanisms and kinetics of each process, as well as howthey can be applied to the manufacture of environmentally friendly polymeric materials. Topics covered include: Conventional emulsion polymerization Miniemulsion polymerization Microemulsion polymerization Industrial emulsion polymerization processes (primarily the semibatch and continuous reactions systems) The role of various colloidal phenomena in emulsion polymerization Important end-use properties of emulsion polymer (latex) products Information on industrial applications in paints, coatings, adhesives, paper and board, and more This is a hands-on reference for graduate students and professionals in polymerchemistry, chemical engineering, and materials science who are involved in researchon coatings, adhesives, rubber, latex, paints, finishes, and other materials that can becreated using various methods of emulsion polymerization.