Recent advances in shape selectivity of MFI zeolite and its effect on the catalytic performance

Recent advances in shape selectivity of MFI zeolite and its effect on the catalytic performance
Author: Lan Zhang
Publisher: OAE Publishing Inc.
Total Pages: 26
Release: 2023-01-01
Genre: Science
ISBN:

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MFI zeolite characterized by uniform pore size, adjustable acidity, and high-temperature resistance has a broad application prospect in catalytic reactions. However, controlling the product distribution of zeolite as a catalyst is still confronting great challenges and applications. It is considered as an effective way to control the product distribution by developing and improving new zeolites to modulate their shape selective effect. In recent years, researchers have achieved remarkable successes in investigating the shape selective modulation of zeolites on catalytic reaction and molecular diffusion. The microporous channels of MFI zeolite are the main places for the entry and exit of reactants or product molecules. This review provides the research progress of the shape-selective modulation of MFI zeolite channels and its influence on a series of catalytic performances in recent years. The shape-selective modulation of microporous channels of zeolite, encapsulation of micropores to metals, catalysis of mesoporous zeolite, and the distribution of framework Al were all systematically discussed. The development of advanced catalysts still faces great challenges and potential applications. Finally, we discussed the problems to be addressed urgently in the field of zeolite catalysts in the future.

Mesoporous Zeolites

Mesoporous Zeolites
Author: Javier García-Martínez
Publisher: John Wiley & Sons
Total Pages: 608
Release: 2015-05-26
Genre: Technology & Engineering
ISBN: 3527335749

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Authored by a top-level team of both academic and industrial researchers in the field, this is an up-to-date review of mesoporous zeolites. The leading experts cover novel preparation methods that allow for a purpose-oriented fine-tuning of zeolite properties, as well as the related materials, discussing the specific characterization methods and the applications in close relation to each individual preparation approach. The result is a self-contained treatment of the different classes of mesoporous zeolites. With its academic insights and practical relevance this is a comprehensive handbook for researchers in the field and related areas, as well as for developers from the chemical industry.

Characterization and Design of Zeolite Catalysts

Characterization and Design of Zeolite Catalysts
Author: Miki Niwa
Publisher: Springer Science & Business Media
Total Pages: 189
Release: 2010-08-17
Genre: Science
ISBN: 3642126200

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Catalysis and catalyst is a key technology to solve the problems in energy and environment issues to sustain our human society. We believe that comprehensive understanding of the catalysis and catalyst provides us a chance to develop a new catalyst and contributes greatly to our society. However, the ?eld of heterogeneous catalyst is dif?cultto study andstill stays behindmoredeveloped?elds ofchemistry such as organic and physical chemistries. This is a dilemma to the chemists who study the catalysis and catalyst. While we can accomplish the progress in the - dustrial application, the scienti?c understandingis not complete yet. A gap between the useful application and incomplete scienti?c understanding, however, becomes smaller and smaller in recent years. Because zeolites are ?ne crystals, and the structure is clearly known, the study on the catalysis using the zeolites is easier than those encountered in other catalysts such as metals and metal oxides. Very fortunately, zeolites provide us the strong acidity with the ?ne distribution which enables various useful catalytic reactions. When some metals and cations are loaded in close to the acid sites, these loadede- ments show extraordinarycharacters, and many catalytic reactions proceed thereon.

Zeolites For Cleaner Technologies

Zeolites For Cleaner Technologies
Author: Jean-pierre Gilson
Publisher: World Scientific
Total Pages: 390
Release: 2002-09-19
Genre: Science
ISBN: 178326117X

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This book, written and edited by leading authorities from academia and industrial groups, covers both preventive- and curative-zeolite-based technologies in the field of chemical processing.The opening chapter presents the state of the art in zeolite science. The two subsequent chapters summarize the chemistries involved in the processes and the constraints imposed on the catalyst/adsorbent. Three major areas are covered: oil refining, petrochemicals and fine chemicals. A chapter on the (curative) use of zeolites in pollution abatement completes this overview.In the area of oil refining, a general lecture sets the scene for present and future challenges. It is followed by in-depth case studies involving FCC, hydrocracking and light naphtha isomerization. Also, an entire chapter is devoted to the often-overlooked subject of base oils.In the area of petrochemicals, the processing of aromatics and olefins is described and special attention is paid to the synergy between catalysis and separation on molecular sieves.

Zeolites in Sustainable Chemistry

Zeolites in Sustainable Chemistry
Author: Feng-Shou Xiao
Publisher: Springer
Total Pages: 490
Release: 2015-09-28
Genre: Science
ISBN: 366247395X

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This book is devoted to the new development of zeolitic catalysts with an emphasis on new strategies for the preparation of zeolites, novel techniques for their characterization and emerging applications of zeolites as catalysts for sustainable chemistry, especially in the fields of energy, biomass conversion and environmental protection. Over the years, energy and the environment have become the most important global issues, while zeolitic catalysts play important roles in addressing them. With individual chapters written by leading experts, this book offers an essential reference work for researchers and professionals in both academia and industry. Feng-Shou Xiao is a Professor at the Department of Chemistry, Zhejiang University, China. Xiangju Meng is an Associate Professor at the Department of Chemistry, Zhejiang University, China.

Heterogeneous Catalytic Materials

Heterogeneous Catalytic Materials
Author: Guido Busca
Publisher: Newnes
Total Pages: 479
Release: 2014-05-23
Genre: Technology & Engineering
ISBN: 044459521X

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Heterogeneous Catalytic Materials discusses experimental methods and the latest developments in three areas of research: heterogeneous catalysis; surface chemistry; and the chemistry of catalysts. Catalytic materials are those solids that allow the chemical reaction to occur efficiently and cost-effectively. This book provides you with all necessary information to synthesize, characterize, and relate the properties of a catalyst to its behavior, enabling you to select the appropriate catalyst for the process and reactor system. Oxides (used both as catalysts and as supports for catalysts), mixed and complex oxides and salts, halides, sulfides, carbides, and unsupported and supported metals are all considered. The book encompasses applications in industrial chemistry, refinery, petrochemistry, biomass conversion, energy production, and environmental protection technologies. Provides a systematic and clear approach of the synthesis, solid state chemistry and surface chemistry of all solid state catalysts Covers widely used instrumental techniques for catalyst characterization, such as x-ray photoelectron spectroscopy, scanning electron microscopy, and more Includes characterization methods and lists all catalytic behavior of the solid state catalysts Discusses new developments in nanocatalysts and their advantages over conventional catalysts

Comprehensive Inorganic Chemistry II

Comprehensive Inorganic Chemistry II
Author:
Publisher: Newnes
Total Pages: 7694
Release: 2013-07-23
Genre: Science
ISBN: 0080965296

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Comprehensive Inorganic Chemistry II, Nine Volume Set reviews and examines topics of relevance to today’s inorganic chemists. Covering more interdisciplinary and high impact areas, Comprehensive Inorganic Chemistry II includes biological inorganic chemistry, solid state chemistry, materials chemistry, and nanoscience. The work is designed to follow on, with a different viewpoint and format, from our 1973 work, Comprehensive Inorganic Chemistry, edited by Bailar, Emeléus, Nyholm, and Trotman-Dickenson, which has received over 2,000 citations. The new work will also complement other recent Elsevier works in this area, Comprehensive Coordination Chemistry and Comprehensive Organometallic Chemistry, to form a trio of works covering the whole of modern inorganic chemistry. Chapters are designed to provide a valuable, long-standing scientific resource for both advanced students new to an area and researchers who need further background or answers to a particular problem on the elements, their compounds, or applications. Chapters are written by teams of leading experts, under the guidance of the Volume Editors and the Editors-in-Chief. The articles are written at a level that allows undergraduate students to understand the material, while providing active researchers with a ready reference resource for information in the field. The chapters will not provide basic data on the elements, which is available from many sources (and the original work), but instead concentrate on applications of the elements and their compounds. Provides a comprehensive review which serves to put many advances in perspective and allows the reader to make connections to related fields, such as: biological inorganic chemistry, materials chemistry, solid state chemistry and nanoscience Inorganic chemistry is rapidly developing, which brings about the need for a reference resource such as this that summarise recent developments and simultaneously provide background information Forms the new definitive source for researchers interested in elements and their applications; completely replacing the highly cited first edition, which published in 1973

Zeolites: A Refined Tool for Designing Catalytic Sites

Zeolites: A Refined Tool for Designing Catalytic Sites
Author: L. Bonneviot
Publisher: Elsevier
Total Pages: 585
Release: 1995-09-08
Genre: Technology & Engineering
ISBN: 008054469X

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Formerly, the catalytic use of zeolites was exclusive to the field of acid catalysis. Nowadays, zeolites also find applications as catalysts in a wide array of chemical reactions such as; base catalyzed reactions, Redox reactions and catalytic reactions on transition metals and their complexes in confined environments. The concepts of Brønsted or Lewis acid-base pairs are adequately illustrated in the literature and well-understood in terms of structural and electronic properties of zeolites. By contrast, properties of chemically modified silicates, aluminosilicates and aluminophosphates have not yet been fully explored. The list of oxydo-reduction reactions performed in the presence of these new materials is growing as demonstrated by the selective catalytic reduction of nitrogen oxides or the numerous oxidations employing hydrogen peroxide. Much effort is currently being made to get a better insight into the nature of the sites involved. The zeolite lattice may also be used as a host for encapsulated complexes or metallic clusters allowing the control of nuclearity of these active species and the steric constraints imposed on the reactants. Molecular sieve and shape selectivity effects have also constituted fascinating aspects of zeolite properties. Recent developments leading to increasingly large pore sizes with VPI-5, cloverite and more recently mesoporous molecular sieves have broadened the spectrum of these applications. Indeed, larger and larger reactant and product molecules can be accommodated in these lattices. These new adsorbant/adsorbate systems create additional needs for experimental data and theoretical descriptions of transport properties, in particular of mono- and multi-components diffusion coefficients in the zeolite pore lattice. All these themes, representing the forefront and current trends in zeolite research, were discussed in the submitted papers to the symposium and are widely represented in the selected papers contained in this volume. A feature common to most of these contributions is the combined use of a variety of analytical techniques. Some of these techniques are at the frontier of the latest analytical developments such as multiple scattering EXAFS and bidimensional MAS-NMR.

Zeolite Catalysts

Zeolite Catalysts
Author: Subhash Bhatia
Publisher: CRC Press
Total Pages: 302
Release: 2020-07-24
Genre: Science
ISBN: 100009863X

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Presented in an easy-to-read form, this book on zeolite catalysis cover all aspects of the subject. It focuses on synthesis, structure, diffusion, deactivation, and industrial applications. This book is an ideal text for courses on catalysis or as a supplementary text for those studying applied or industrial chemistry. It is also a useful resource for anyone who works with zeolites as catalysts in the laboratory, pilot plants, or commercial installations.

Atlas of Zeolite Framework Types

Atlas of Zeolite Framework Types
Author: Ch. Baerlocher
Publisher: Elsevier
Total Pages: 405
Release: 2007-09-12
Genre: Technology & Engineering
ISBN: 0080554342

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Zeolite scientists, whether they are working in synthesis, catalysis, characterization or application development, use the Atlas of Zeolite Framework Types as a reference. It describes the main features of all of the confirmed zeolite framework structures, and gives references to the relevant primary structural literature. Since the last edition 34 more framwork types have been approved and are described in this new edition. A further new feature will be that characteristic building units will be listed for each of the framework types.Zeolites and their analogs are used as desiccants, as water softeners, as shape-selective acid catalysts, as molecular sieves, as concentrators of radioactive isotopes, as blood clotting agents, and even as additives to animal feeds. Recently, their suitability as hosts for nanometer spacing of atomic clusters has also been demonstrated. These diverse applications are a reflection of the fascinating structures of these microporous materials. Each time a new zeolite framework structure is reported, it is examined by the Structure Commission of the International Zeolite Association (IZA-SC), and if it is found to be unique and to conform to the IZA-SC's definition of a zeolite, it is assigned a 3-letter framework type code. This code is part of the official IUPAC nomenclature for microporous materials. The Atlas of Zeolite Framework Types is essentially a compilation of data for each of these confirmed framework types. These data include a stereo drawing showing the framework connectivity, features that characterize the idealized framework structure, a list of materials with this framework type, information on the type material that was used to establish the framework type, and stereo drawings of the pore openings of the type material. Clear stereo drawings of each of the framework types Description of the features of the framework type, allowing readers to quickly see if the framework type is suitable to their needs References to isotypic materials, readers can quickly identify related materials and consult the appropriate reference