Recent Advances in Anionic Polymerization

Recent Advances in Anionic Polymerization
Author: T.E. Hogen-Esch
Publisher: Springer Science & Business Media
Total Pages: 453
Release: 2012-12-06
Genre: Technology & Engineering
ISBN: 9400931751

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Over the years the field of anionic polymerization has attracted numerous outstanding scientists, and today it still is being pursued by many researchers all over the world. The exciting discovery of termination-less polymerization processes and living polymers culminating in the development of narrow molecular weight polymers, star polymers, and tailor-made block and graft copolymers, contributed immensely to the rapid expansion of polymer science. Areas of active research in anionic polymerization presently include the structure of ion pairs and their role in regulating polymer structure, ring opening polymerization of heterocyclic monomers, synthesis of well-defined block and graft copolymers including the application of macromers in such systems, telechelic polymers with functional end groups, and other topics. New developments in the organic chemistry of carbanions such as dipolar carbanions impinge on the field of anionic polymerization. More sophisticated characterization techniques have been instrumental in obtaining better correlations between the structure of polymers and that of intermediates leading to their formation. This book contains the proceedings of the international symposium on "Recent Advances in Anionic Polymerization and Related Processes" which was held at the 1986 spring meeting of the American Chemical Society. It was the first Polymer Division-sponsored meeting exclusively devoted to anionic polymerization since the Houston ACS meeting in the spring of 1980. The proceedings of that meeting were published in the book "Anionic Polymerization", ACS Symposium Series No. 166, edited by Dr. J. E. McGrath.

Recent Advances in Mechanistic and Synthetic Aspects of Polymerization

Recent Advances in Mechanistic and Synthetic Aspects of Polymerization
Author: M. Fontanille
Publisher: Springer Science & Business Media
Total Pages: 555
Release: 2012-12-06
Genre: Science
ISBN: 9400939892

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Due to their specific properties, polymers with well-defined structures have been receiving increasing attention over the last several years. Owing to the wide variability of their properties, these specialty polymers have been used in various areas from biomedical engineering to electronics or energy applications. The synthesis of such polymers necessi tates the use of new methods of polymerization which derived from an insight into the mechanism of polymerization reactions. A NATO Advanced Research Workshop on "Frontiers in Polymerization Catalysis and Polymer Synthesis" was held in BANDOl (FRANCE) in February 1987. Its aim was to assess the new polymerization methods, as well as the latest advances in the mechanisms of conventional polymerization reactions together with their applications to the synthesis of new macromolecular structures. The financial support from the NATO Scientific Affairs Division which covered the "lecturers' accomodation and travel expenses as well as the organization charges of this event gave it international scope. Several industrial companies participate at the meeting and contributed to it success. The organizors who are also editors of these proceedings, want to express their thanks to both NATO Scientific Affairs Division and the companies present at the meeting.

Ionic Polymerizations and Related Processes

Ionic Polymerizations and Related Processes
Author: Judit E. Puskas
Publisher: Springer Science & Business Media
Total Pages: 386
Release: 2012-12-06
Genre: Technology & Engineering
ISBN: 9401146276

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In Ionic Polymerization and Related Processes, internationally recognised academic and industrial researchers discuss and debate the latest developments in the field. The major focus is on cationic polymerizations, but related anionic and controlled radical processes are also discussed.

New Methods Polymer Synthesis

New Methods Polymer Synthesis
Author: J. R. Ebdon
Publisher: Springer Science & Business Media
Total Pages: 209
Release: 2012-12-06
Genre: Science
ISBN: 1468415301

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Most practitioners and students of polymer chemistry are familiar, in general terms at least, with the established methods of polymer synthesis - radical, anionic, cationic and coordination addition polymerization, and stepwise con densation and rearrangement polymerization. These methods are used to synthesize the majority of polymers used in the manufacture of commercially important plastics, fibres, resins and rubbers, and are covered in most introduc tory polymer chemistry textbooks and in most undergraduate and graduate courses on polymer science. Fewer polymer chemists, however, have much familiarity with more recent developments in methods of polymer synthesis, unless they have been specifically involved for some time in the synthesis of speciality polymers. These developments include not only refinements to established methods but also new mechanisms of polymerization, such as group transfer and metathesis polymerization and novel non-polymerization routes to speciality polymers involving, for example, the chemical modification of preformed polymers or the linking together of short terminally functionalized blocks.

New Methods of Polymer Synthesis

New Methods of Polymer Synthesis
Author: J.R. Ebdon
Publisher: Springer Science & Business Media
Total Pages: 209
Release: 2012-12-06
Genre: Technology & Engineering
ISBN: 9401095523

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Most practitioners and students of polymer chemistry are familiar, in general terms at least, with the established methods of polymer synthesis - radical, anionic, cationic and coordination addition polymerization, and stepwise con densation and rearrangement polymerization. These methods are used to synthesize the majority of polymers used in the manufacture of commercially important plastics, fibres, resins and rubbers, and are covered in most introduc tory polymer chemistry textbooks and in most undergraduate and graduate courses on polymer science. Fewer polymer chemists, however, have much familiarity with more recent developments in methods of polymer synthesis, unless they have been specifically involved for some time in the synthesis of speciality polymers. These developments include not only refinements to established methods but also new mechanisms of polymerization, such as group transfer and metathesis polymerization and novel non-polymerization routes to speciality polymers involving, for example, the chemical modification of preformed polymers or the linking together of short terminally functionalized blocks.

Proceedings of the 2003 International Symposium on Ionic Polymerization and Related Processes, Boston, USA, June 30-July 4, 2003

Proceedings of the 2003 International Symposium on Ionic Polymerization and Related Processes, Boston, USA, June 30-July 4, 2003
Author: Jimmy W. Mays
Publisher: John Wiley & Sons
Total Pages: 412
Release: 2004
Genre: Science
ISBN: 9783527310487

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Proceedings of the 2003 International symposium on Ionic Polymerization and Related Processes contains papers by world leaders in this important area of polymer science, Edited by world-known experts in ionic polymerization, Professors Jimmy Mays and Robson Storey, these peer reviewed papers are presented in three sub-categories: 1. anionic polymerization; 2. cationic polymerization; 3. related processes. Aspects covered include synthesis, mechanic Studies, and applications. This volume will be useful to both academic and industrial scientists and engineers seeking to keep up with current advances in these important areas of science and technology.

Fundamentals of Polymerization

Fundamentals of Polymerization
Author: Broja Mohan Mandal
Publisher: World Scientific
Total Pages: 468
Release: 2013
Genre: Science
ISBN: 9814322466

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Over the last twenty years, the field of the chemistry of polymerization witnessed enormous growth through the development of new concepts, catalysts, processes etc. Examples are: non classical living polymerizations (group transfer polymerization, living carbocationic polymerization, living radical polymerization and living ring-opening metathesis polymerization (ROMP)); new catalysts (metallocenes and late transition metal catalysts for stereospecific polymerization, Schrock and Grubbs catalyst for ROMP among others) and new processes such as miniemulsion, microemulsion polymerization and dispersion polymerization (in polar solvents). Apart from the developments in the chemistry of polymerization, methods have been developed for the evaluation of highly reliable rate constants of propagation in radical as well as cationic polymerization. All these have revolutionized the field of synthetic polymer chemistry. In the book, fundamentals of both the new and old polymerization chemistry have been dealt with. The new chemistry has been given nearly equal space along with the old.

Advances in Polymer Synthesis

Advances in Polymer Synthesis
Author: Bill M. Culbertson
Publisher: Springer Science & Business Media
Total Pages: 553
Release: 2012-12-06
Genre: Science
ISBN: 1461321212

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"Polymer Science and Engineering: Challenges, Needs, and Opportunities," a report issued in 1981 by the National Research Council's ad hoc Panel on Polymer Science and Engineering gives ample support for the urgent need of increased commitment to basic studies on polymers. Needs and opportunities, mentioned in the Panel's list, included polymerization methods, specialty polymers, high performance materials, and in situ (reaction injection molding) polymerization for direct conversion of monomers/oligomers to useful shapes. Clearly, in all these and several other areas, advances in polymer synthesis are needed. Whether one takes a look at the commodity or specialty polymers area or considers areas of growing needs, such as polymers for the automotive, aerospace, electronics, communications, separations, packaging, biomedical, etc., advances in polymer synthesis are needed. Polymeric materials, as they are constantly being modified and improved, fine-tuned for current and additional needs, and more readily adopted by industry and the public, will have a vastly expanding influence on everyday life. However, lack of long-term support of meaningful size for basic research on all facets of polymer chemistry and engineering, with particular emphasis on making needed advances in polymer synthesis, could well stunt the growth of high techn.ology in our country. Expanding this thought, lack of attention to basic research on polymer synthesis could help foster or insure that we won't have materials with performance profiles to meet requirements of emerging technologies and national needs, in a reasonably economic and timely fashion.