Performance Evaluation of Corrosion Inhibitors and Galvanized Steel in Concrete Exposure Specimens

Performance Evaluation of Corrosion Inhibitors and Galvanized Steel in Concrete Exposure Specimens
Author: Jerzy Zemajtis
Publisher:
Total Pages: 80
Release: 1999
Genre: Concrete bridges
ISBN:

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Corrosion inhibitor admixtures (CIA) and galvanized reinforcing steel (GS) are used for the corrosion protection for reinforced concrete bridges. The results of a 3.5-year evaluation of exposure specimens containing CIA from three different manufacturers and GS are presented. The specimens were built to simulate four exposure conditions typical for concrete bridges located in the coastal region or inland where deicing salts are used. The exposure conditions were Horizontal, Vertical, Tidal, and Immersed Zones. The specimens were kept inside the laboratory and were exposed to weekly ponding cycles of 6% sodium chloride solution by weight. The methods used to assess the condition of the specimens included chloride concentration measurements, corrosion potentials, and corrosion rates. Additionally, visual observations were performed for identification of rust stains and cracking on concrete surfaces. The results of chloride testing indicate that the amount of chlorides present at the bar level is more than sufficient to initiate corrosion. Chloride and rapid permeability data indicate no significant difference either in a rate of chloride ingress or in the diffusion coefficients for concretes with and without CIA. Corrosion potentials were the most negative for the Bare Steel (BS) specimen prepared with the Armatec 2000 corrosion inhibitor and generally indicated a 90% probability of active corrosion. Corrosion potentials were similar for the two BS control specimens and the BS specimen prepared with Rheocrete 222 and generally indicated an uncertain probability of corrosion. Corrosion potentials were the least negative for the BS specimen prepared with DCI-S corrosion inhibitor and generally indicated a 90% probability of no corrosion. Rate of corrosion measurements were the highest for the BS control specimens and the one prepared with A2000 and the most recent data suggest corrosion damage in 2 to 10 years. Although early rate of corrosion measurements were higher or about the same as for BS control specimens, recent measurements were slightly lower for the specimen prepared with Rheocrete 222 and suggest corrosion damage in 10 to 15 years. Rate of corrosion measurements were consistently the lowest for the BS specimens prepared with DCI-S and indicate corrosion damage is expected in 10 to 15 years. The corrosion potential and rate of corrosion data indicate that DCI-S is the only CIA evaluated that clearly provides some level of corrosion protection. A direct comparison of the GS specimens to the BS specimens is not possible because the measured potential refers to the zinc oxide and not to the steel. Nevertheless, the potential data agree with the chloride and permeability data, as well as with the visual observations, and indicate the damaging effect of a high concentration of chloride ions on the GS. At low and moderate chloride exposures, however, GS does provide corrosion protection. Recommendations are to continue monitoring until sufficient cracking has occurred in all specimens to provide for making a better estimate of the service lives of CIA and GS used in the construction of concrete bridge components in Virginia. The specimens with CIA and one control (continuous reinforcement in the legs) should be taken to the Hampton Road North Tunnel Island and placed in the brackish water to a depth of the Immersed Zone at low tide for further exposure to chloride. The specimens with GS and the other control (non-continuous reinforcement in the legs) should remain in an outdoor exposure in Southwest Virginia like the Civil Engineering Materials Research Laboratory in Blacksburg, Virginia.

Performance Evaluation of Various Corrosion Protection Systems of Bridges in Colorado

Performance Evaluation of Various Corrosion Protection Systems of Bridges in Colorado
Author: Yunping Xi
Publisher:
Total Pages: 166
Release: 2004
Genre: Concrete bridges
ISBN:

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Corrosion of reinforced concrete structures has been a significant problem for many state and transportation agencies since the application of deicing salts was introduced. Much research has been conducted to develop corrosion protection systems that can prolong the life span of reinforced concrete structures. The Colorado Department of Transportation (CDOT) has several routine and experimental measures to prevent corrosion of the rebar including epoxy-coated rebar, calcium nitrite admixture, organic corrosion inhibitors, a thick cover of quality concrete, and a waterproofing membrane covered by an asphalt overlay. An extensive literature review was performed to collect information on various corrosion protection systems that have been used in the U.S. and around the world. Current CDOT practices in terms of corrosion protection measures were reviewed. A draft inspection plan for Colorado's bridge structures was proposed.

Evaluation of Corrosion Protection Methods for Reinforced Concrete Highway Structures

Evaluation of Corrosion Protection Methods for Reinforced Concrete Highway Structures
Author: Jennifer L. Kepler
Publisher:
Total Pages: 244
Release: 2000
Genre: Concrete bridges
ISBN:

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Since the 1970s, research projects and field studies have been conducted on different methods for protecting reinforced concrete bridges from corrosion damage. The methods include alternative reinforcement and slab design, barrier methods, electrochemical methods, and corrosion inhibitors. Each method and its underlying principles are described, performance results of laboratory and/or field trials are reviewed, and systems are evaluated based on the results of the trials. Using performance results from the studies and costs obtained from transportation agencies, an economic analysis is used to estimate the cost of each system over a 75-year economic life using discount rates of 2%, 4% and 6%.

Evaluation of Corrosion Inhibitors in Chloride-contaminated Reinforced Concrete

Evaluation of Corrosion Inhibitors in Chloride-contaminated Reinforced Concrete
Author: Roumiana Hristova
Publisher:
Total Pages: 0
Release: 1996
Genre:
ISBN:

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The report describes research to determine the effectiveness of commercial corrosion-inhibiting admixtures on the corrosion of reinforcing steel in chloride contaminated concrete. Domestic and foreign publications were reviewed to locate performance data and current practices related to the use, testing and evaluation of corrosion inhibiting admixtures. The study consisted of identification and evaluation of the currently used corrosion-inhibiting admixtures in the United States and other countries. A list of available corrosion-inhibiting admixtures were appraised. Consideration was given to performance predictability, practicality, cost, and other pertinent factors. Five-year old "lollipop" concrete speciments containing sodium nitrite and dinitrobenzoic acid as corrosion inhibitors, and comparison with control specimens were studied using linear polarization and impedance spectroscopy. All mixes had different amounts of calcium chloride added. An equivalent circuit model considering the physical characteristics of the rebar/concrete interface was used to simulate the impedance spectra. The RC parameters obtained from the impedance simulation, including maximum phase angle shift, surface impedance and capacitive responses, were utilized to characterize the surface corrosion of embedded steel and to evaluate the effect of inhibitors with chloride content. The corrosion current densities determined by impedance measurement were compared with those determined using linear polarization and good agreement between the two methods was obtained.

Corrosion of Steel in Concrete Structures

Corrosion of Steel in Concrete Structures
Author: Amir Poursaee
Publisher: Woodhead Publishing
Total Pages: 314
Release: 2016-02-17
Genre: Technology & Engineering
ISBN: 1782424024

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Corrosion of reinforcing steel is now recognized as the major cause of degradation of concrete structures in many parts of the world. Despite this, infrastructure expenditure is being unreasonably decreased by sequestration and the incredible shrinking discretionary budget. All components of our infrastructure including highways, airports, water supply, waste treatment, energy supply, and power generation require significant investment and are subjected to degradation by corrosion, which significantly reduces the service life, reliability, functionality of structures and equipment, and safety. Corrosion of Steel in Concrete Structures provides a comprehensive review of the subject, in addition to recent advances in research and technological developments, from reinforcing materials to measurement techniques and modelling. This book contains not only all the important aspects in the field of corrosion of steel reinforced concrete but also discusses new topics and future trends. Part One of the book tackles theoretical concepts of corrosion of steel in concrete structures. The second part moves on to analyse the variety of reinforcing materials and concrete, including stainless steel and galvanized steel. Part Three covers measurements and evaluations, such as electrochemical techniques and acoustic emission. Part Four reviews protection and maintenance methods, whilst the final section analyses modelling, latest developments and future trends in the field. The book is essential reading for researchers, practitioners and engineers who are involved in materials characterisation and corrosion of steel in concrete structures. Provides comprehensive coverage on a broad range of topics related to the corrosion of steel bars in concrete Discusses the latest measuring methods and advanced modeling techniques Reviews the range of reinforcing materials and types of concrete

Corrosion Protection Performance of Corrosion Inhibitors and Epoxy-coated Reinforcing Steel in a Simulated Concrete Pore Water Solution

Corrosion Protection Performance of Corrosion Inhibitors and Epoxy-coated Reinforcing Steel in a Simulated Concrete Pore Water Solution
Author: Wioleta A. Pyć
Publisher:
Total Pages: 58
Release: 1998
Genre: Epoxy coatings
ISBN:

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We used a simulated concrete pore water solution to evaluate the corrosion protection performance of concrete corrosion-inhibiting admixtures and epoxy-coated reinforcing bars (ECR). We evaluated three commercial corrosion inhibitors, ECR from three coaters removed from job sites, one ECR shipped directly from the coater's plant, and one ECR removed from a job site plus a corrosion inhibitor. The corrosion inhibitors were calcium nitrite, an aqueous mixture of esters and amines, and a mixture of alcohol and amine. Corrosion protection performance was based on the amount of visually observed corroded surface area. For bare steel tested with and without corrosion inhibitors, corrosion increased with increasing chloride concentration, and specimens saturated with oxygen were more corroded than specimens saturated with breathing air. The amount of corrosion over the 90-day test period was controlled by the amount of oxygen in solution at the higher chloride concentrations. The ester-amine and alcohol-amine did not inhibit corrosion. Calcium nitrite inhibited corrosion at all levels of chloride concentration. For ECR, corrosion occurred both at sites where the coating was damaged and underneath the coating. Coating debondment was greatest in pore water solutions containing chloride. The least coating debondment and corrosion occurred in the solution containing calcium nitrite and the ECR shipped directly from the manufacturer. Coating debondment and corrosion of ECR are directly related to the amount of damage as holes; mashed, dented, and cracked areas; and holidays. The researchers recommend that the developed test method be adopted as a standard test for concrete corrosion inhibitors and that calcium nitrite remain the only concrete corrosion inhibitor approved for use in Virginia.

Galvanized Steel Reinforcement in Concrete

Galvanized Steel Reinforcement in Concrete
Author: Stephen Yeomans
Publisher: Elsevier
Total Pages: 316
Release: 2004-11-26
Genre: Technology & Engineering
ISBN: 0080472834

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Reinforced concrete is one of the most widely used modern materials of construction. It is comparatively cheap, readily available, and suitable for a variety of building and construction applications. Galvanized Steel Reinforcement in Concrete provides a detailed resource covering all aspects of this important material. Both servicability and durability aspects are well covered, with all the information needed maximise the life of buildings constructed from it. Containing an up-to-date and comprehensive collection of technical information and data from world renound authors, it will be a valuable source of reference for academics, researchers, students and professionals alike. Provides information vital to prolong the life of buildings constructed from this versatile material Brings together a disparate body of knowledge from many parts of the world into a concise and authoritative text Containing an up-to-date and comprehensive collection of technical information