Organochromium Chemistry With Formally Neutral Chelating Ancillary Ligands
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Author | : Kevin Allen Kreisel |
Publisher | : ProQuest |
Total Pages | : |
Release | : 2008 |
Genre | : Chelates |
ISBN | : 9780549388425 |
Download Organochromium Chemistry with Formally Neutral, Chelating Ancillary Ligands Book in PDF, Epub and Kindle
This dissertation describes research on chromium complexes with formally neutral, chelating ligands. The goal of this research is the fundamental study of organochromium chemistry with the hope of preparing Cr(II) complexes that are active for the polymerization or oligomerization of ethylene. This would provide evidence for Cr(II) to be active for these processes. Chapter 1 of this dissertation describes the synthesis and characterization of a series of chromium complexes supported by a chelating N-heterocyclic carbene ligand. The second chapter details the preparation and structural characterization of several complexes of chromium supported by several diimine ligands. The third chapter examines the organochromium chemistry derived from the complexes described in chapter 2. The final chapter entails the synthesis of the shortest metal-metal distance ever reported.
Author | : R Sneeden |
Publisher | : Elsevier |
Total Pages | : 337 |
Release | : 2012-12-02 |
Genre | : Science |
ISBN | : 0323155375 |
Download Organochromium compounds Book in PDF, Epub and Kindle
Organochromium Compounds is a three-chapter text that covers the major developments in the preparation, characterization, and reaction of the five main classes of organochromium compounds. These classes include the chromium p and solvated sodium and lithium poly(organo)chromate(III) and (II) complexes, carbenoid-chromium, solvated s-bonded organochromium(III) and (II), solvated sodium and lithium poly(organo)chromate(III) and (II) complexes, and unsolvated s-bonded tetra(organo)chromium(IV) compounds. This book will be of value to organic chemists and researchers who are interested in organotransition metal chemistry.
Author | : Jonathan G. Rudick |
Publisher | : Frontiers Media SA |
Total Pages | : 100 |
Release | : 2020-02-20 |
Genre | : |
ISBN | : 2889634841 |
Download Isocyanide-based Multicomponent Reactions Book in PDF, Epub and Kindle
This eBook is a collection of articles from a Frontiers Research Topic. Frontiers Research Topics are very popular trademarks of the Frontiers Journals Series: they are collections of at least ten articles, all centered on a particular subject. With their unique mix of varied contributions from Original Research to Review Articles, Frontiers Research Topics unify the most influential researchers, the latest key findings and historical advances in a hot research area! Find out more on how to host your own Frontiers Research Topic or contribute to one as an author by contacting the Frontiers Editorial Office: frontiersin.org/about/contact.
Author | : Zvi Rappoport |
Publisher | : |
Total Pages | : 832 |
Release | : 1987 |
Genre | : Science |
ISBN | : |
Download The Chemistry of the Cyclopropyl Group (NY Handling Set Only) Book in PDF, Epub and Kindle
The latest in a series of advanced treatises under the general editorship of Professor Saul Patai providing a comprehensive review of the chemistry of the cyclopropyl group including physical properties, analysis, reaction mechanisms and synthetic uses.
Author | : Lutz H. Gade |
Publisher | : John Wiley & Sons |
Total Pages | : 632 |
Release | : 2014-06-30 |
Genre | : Technology & Engineering |
ISBN | : 3527673296 |
Download Molecular Catalysts Book in PDF, Epub and Kindle
Highlighting the key aspects and latest advances in the rapidly developing field of molecular catalysis, this book covers new strategies to investigate reaction mechanisms, the enhancement of the catalysts' selectivity and efficiency, as well as the rational design of well-defined molecular catalysts. The interdisciplinary author team with an excellent reputation within the community discusses experimental and theoretical studies, along with examples of improved catalysts, and their application in organic synthesis, biocatalysis, and supported organometallic catalysis. As a result, readers will gain a deeper understanding of the catalytic transformations, allowing them to adapt the knowledge to their own investigations. With its ideal combination of fundamental and applied research, this is an essential reference for researchers and graduate students both in academic institutions and in the chemical industry. With a foreword by Nobel laureate Roald Hoffmann.
Author | : Jon Paul Janet |
Publisher | : American Chemical Society |
Total Pages | : 189 |
Release | : 2020-05-28 |
Genre | : Science |
ISBN | : 0841299005 |
Download Machine Learning in Chemistry Book in PDF, Epub and Kindle
Recent advances in machine learning or artificial intelligence for vision and natural language processing that have enabled the development of new technologies such as personal assistants or self-driving cars have brought machine learning and artificial intelligence to the forefront of popular culture. The accumulation of these algorithmic advances along with the increasing availability of large data sets and readily available high performance computing has played an important role in bringing machine learning applications to such a wide range of disciplines. Given the emphasis in the chemical sciences on the relationship between structure and function, whether in biochemistry or in materials chemistry, adoption of machine learning by chemistsderivations where they are important
Author | : John C. Chadwick |
Publisher | : John Wiley & Sons |
Total Pages | : 592 |
Release | : 2011-06-09 |
Genre | : Science |
ISBN | : 3527636005 |
Download Homogeneous Catalysts Book in PDF, Epub and Kindle
This first book to illuminate this important aspect of chemical synthesis improves the lifetime of catalysts, thus reducing material and saving energy, costs and waste. The international panel of expert authors describes the studies that have been conducted concerning the way homogeneous catalysts decompose, and the differences between homogeneous and heterogeneous catalysts. The result is a ready reference for organic, catalytic, polymer and complex chemists, as well as those working in industry and with/on organometallics.
Author | : Stefan Bräse |
Publisher | : Springer Science & Business Media |
Total Pages | : 304 |
Release | : 2013-02-14 |
Genre | : Science |
ISBN | : 3709113121 |
Download The Chemistry of Mycotoxins Book in PDF, Epub and Kindle
The biological activity of mycotoxins ranges from weak and/or sometimes positive effects, such as antibacterial activity (see penicillin derivatives derived from Penicillium strains) to strong mutagenic (e. g. aflatoxins, patulin), carcinogenic (e. g. aflatoxins), teratogenic, neurotoxic (e. g. ochratoxins), nephrotoxic (e. g. fumonisins, citrinin), hepatotoxic, and immunotoxic (e. g. ochratoxins, diketopiperazines) activity. Nowadays, many laboratories around the world are specialized in the detection of mycotoxins in food products and contaminated material found in housing. In this volume, a focus on the most important classes of mycotoxins is provided and their chemistry of the last ten years is discussed. In each Section, the individual biological impact is outlined. Sections are arranged according to mycotoxin classes (e. g. aflatoxins) and/or structural classes (e. g. resorcinyl lactones, diketopiperazines). The biology of mycotoxins is also described.
Author | : Giuliano Giambastiani |
Publisher | : Springer Science & Business Media |
Total Pages | : 296 |
Release | : 2011-04-29 |
Genre | : Science |
ISBN | : 9048138159 |
Download Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes I Book in PDF, Epub and Kindle
This book highlights key advances that have occurred in the field of olefin conversion in recent years. The role of homogenous transition metal catalysts which contain an imine functionality is emphasized; their potential applications in the processing and upgrade of olefins to a wide variety of commodity products of very high industrial value is also explored. On the threshold of the fiftieth anniversary of the Noble Prize to Ziegler and Natta, this book gives a critical summary of the state of the art developments in the fascinating and rapidly developing field of the olefin polymerization, oligomerization, and co-polymerization catalysis.
Author | : Gregory L. Geoffroy |
Publisher | : John Wiley & Sons |
Total Pages | : 366 |
Release | : 2009-09-17 |
Genre | : Science |
ISBN | : 0470147431 |
Download Topics in Inorganic and Organometallic Stereochemistry Book in PDF, Epub and Kindle
This volume is devoted entirely to inorganic and organometallic stereochemical subjects. Discusses the systematic notations that have been developed to satisfy the needs for a rational and systematic stereochemical nomenclature. Reviews the stereochemical aspects of the changes of bonding at carbon centers induced by metals, either catalytically or stoiciometrically. Also reviews the major achievements in current stereochemical research—the synthesis of asymmetric compounds mediated by transition metals. Discusses the structures of transition metal carbonyl clusters, summarizing recent progress in this expanding area and providing a semiquantitative rationalization of the structures for these clusters.