Nonequilibrium Statistical Mechanics of Heterogeneous Fluid Systems

Nonequilibrium Statistical Mechanics of Heterogeneous Fluid Systems
Author: Andrei G. Bashkirov
Publisher: CRC Press
Total Pages: 176
Release: 2020-10-07
Genre: Science
ISBN: 1000102653

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There is a wide variety of heterogeneous fluid systems that possess interphase surfaces. This monograph is devoted to pioneering studies in nonequilibrium statistical mechanics of such systems. Starting from the Liouville equation, the equations of surface hydrodynamics are derived with allowance for discontinuities of thermodynamic parameters of interphase boundaries. Brownian motion of a large solid particle in a fluid and nucleation are treated as results of fluctuations of flows across particle surfaces. With the use of the Gibbs method, a shock wave in a gas is considered as a sort of an interphase surface, and the surface tension of a shock front is introduced for the first time.

Nonequilibrium Statistical Mechanics of Heterogeneous Fluid Systems

Nonequilibrium Statistical Mechanics of Heterogeneous Fluid Systems
Author: Andrei G. Bashkirov
Publisher: CRC Press
Total Pages: 180
Release: 2020-10-07
Genre: Science
ISBN: 1000141152

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There is a wide variety of heterogeneous fluid systems that possess interphase surfaces. This monograph is devoted to pioneering studies in nonequilibrium statistical mechanics of such systems. Starting from the Liouville equation, the equations of surface hydrodynamics are derived with allowance for discontinuities of thermodynamic parameters of interphase boundaries. Brownian motion of a large solid particle in a fluid and nucleation are treated as results of fluctuations of flows across particle surfaces. With the use of the Gibbs method, a shock wave in a gas is considered as a sort of an interphase surface, and the surface tension of a shock front is introduced for the first time.

Statistical Mechanics of Nonequilibrium Liquids

Statistical Mechanics of Nonequilibrium Liquids
Author: Denis J. Evans
Publisher: ANU E Press
Total Pages: 318
Release: 2007-08-01
Genre: Science
ISBN: 1921313234

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"There is a symbiotic relationship between theoretical nonequilibrium statistical mechanics on the one hand and the theory and practice of computer simulation on the other. Sometimes, the initiative for progress has been with the pragmatic requirements of computer simulation and at other times, the initiative has been with the fundamental theory of nonequilibrium processes. This book summarises progress in this field up to 1990"--Publisher's description.

Equilibrium and Nonequilibrium Statistical Mechanics: Principles and Concepts

Equilibrium and Nonequilibrium Statistical Mechanics: Principles and Concepts
Author: Avijit Lahiri
Publisher: Avijit Lahiri
Total Pages: 1623
Release: 2023-10-14
Genre: Science
ISBN:

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Equilibrium and Non-equilibrium Statistical Mechanics is a source-book of great value to college and university students embarking upon a serious reading of Statistical Mechanics, and is likely to be of interest to teachers of the subject as well. Written in a lucid style, the book builds up the subject from basics, and goes on to quite advanced and modern developments, giving an overview of the entire framework of statistical mechanics. The equilibrium ensembles of quantum and classical statistical mechanics are introduced at length, indicating their relation to equilibrium states of thermodynamic systems, and the applications of these ensembles in the case of the ideal gas are worked out, pointing out the relevance of the ideal gas in respect of a number of real-life systems. The application to interacting systems is then taken up by way of explaining the virial expansion of a dilute gas. The book then deals with a number of foundational questions relating to the existence of the thermodynamic limit and to the equivalence of the various equilibrium ensembles. The relevance of the thermodynamic limit in explaining phase transitions is indicated with reference to the Yang-Lee theory and the Kirkwood-Salsburg equations for correlation functions. The statistical mechanics of interacting systems is then taken up again, with reference to the 1D and 2D Ising model and to the spin glass model of disordered systems. Applications of the Mean field theory are worked out, explaining the Landau-Ginzburg theory, which is then followed by the renormalization group approach to phase transitions. Interacting systems in the quantum context are referred to, addressing separately the cases of interacting bosons and fermions. The case of the weakly interacting bosons is explained in details, while the Landau theory for fermi liquids is also explained in outline. The book then goes on to a modern but readable account of non-equilibrium statistical mechanics, explaining the link with irreversible thermodynamcs. After an exposition of the Boltzmann equations and the linear response theory illustrated with reference to the hydrodynamic model, it explains the statistical mechanics of reduced systems, in the context of a number of reduction schemes. This is followed by an account of the relevance of dynamical chaos in laying down the foundations of classical statistical mechanics, where the SRB distributon is introduced in the context of non-equilibrium steady states, with reference to which the principle of minimum entropy production is explaned. A number of basic fluctuation relations are then worked out, pointing out their relation to irreversible thermodynamics. Finally, the book explains the relevance of quantum chaos in addressing foundational issues in quantum statistical mechanics, beginning with Berry’s conjecture and then going on to an exposition of the eigenstate thermalization (ETH) hypothesis, indicating how the latter is relevant in explaining the processes of equilibriation and thermalization in thermodynamic systems and their sub-systems.

Nonequilibrium Statistical Mechanics

Nonequilibrium Statistical Mechanics
Author: Byung Chan Eu
Publisher: Springer Science & Business Media
Total Pages: 405
Release: 2013-11-11
Genre: Science
ISBN: 9401724385

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In this monograph, nonequilibrium statistical mechanics is developed by means of ensemble methods on the basis of the Boltzmann equation, the generic Boltzmann equations for classical and quantum dilute gases, and a generalised Boltzmann equation for dense simple fluids. The theories are developed in forms parallel with the equilibrium Gibbs ensemble theory in a way fully consistent with the laws of thermodynamics. The generalised hydrodynamics equations are the integral part of the theory and describe the evolution of macroscopic processes in accordance with the laws of thermodynamics of systems far removed from equilibrium. Audience: This book will be of interest to researchers in the fields of statistical mechanics, condensed matter physics, gas dynamics, fluid dynamics, rheology, irreversible thermodynamics and nonequilibrium phenomena.

Non-equilibrium Statistical Physics with Application to Disordered Systems

Non-equilibrium Statistical Physics with Application to Disordered Systems
Author: Manuel Osvaldo Cáceres
Publisher: Springer
Total Pages: 568
Release: 2017-03-07
Genre: Science
ISBN: 3319515535

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This textbook is the result of the enhancement of several courses on non-equilibrium statistics, stochastic processes, stochastic differential equations, anomalous diffusion and disorder. The target audience includes students of physics, mathematics, biology, chemistry, and engineering at undergraduate and graduate level with a grasp of the basic elements of mathematics and physics of the fourth year of a typical undergraduate course. The little-known physical and mathematical concepts are described in sections and specific exercises throughout the text, as well as in appendices. Physical-mathematical motivation is the main driving force for the development of this text. It presents the academic topics of probability theory and stochastic processes as well as new educational aspects in the presentation of non-equilibrium statistical theory and stochastic differential equations.. In particular it discusses the problem of irreversibility in that context and the dynamics of Fokker-Planck. An introduction on fluctuations around metastable and unstable points are given. It also describes relaxation theory of non-stationary Markov periodic in time systems. The theory of finite and infinite transport in disordered networks, with a discussion of the issue of anomalous diffusion is introduced. Further, it provides the basis for establishing the relationship between quantum aspects of the theory of linear response and the calculation of diffusion coefficients in amorphous systems.

Nonequilibrium Statistical Mechanics

Nonequilibrium Statistical Mechanics
Author: Gene F. Mazenko
Publisher: John Wiley & Sons
Total Pages: 492
Release: 2008-07-11
Genre: Science
ISBN: 3527618961

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The present text offers a graduate level treatment of time dependent phenomena in condensed matter physics. Conventional ideas of linear response theory and kinetic theory are treated in detail. The general emphasis, however, in on the development of generalized Langevin equations for treating nonlinear behaviour in a wide variety of systems. A full treatment is given for the underpinnings of hydrodynamics for fluids. This is the third volume of a four volume set of texts by the same author, two of which have already been published ("Fluctuations, Order, and Defects" 0-471-32840-5, "Equilibrium Statistical Mechanics" 0-471-32839-1). While the preceding volume contains material that is a prerequisite for fully understanding the material presented here, this volume is self-contained and can stand alone from the preceding volume.

Nonequilibrium Statistical Mechanics

Nonequilibrium Statistical Mechanics
Author: Robert Zwanzig
Publisher: Oxford University Press
Total Pages: 233
Release: 2001-04-19
Genre: Science
ISBN: 0198032153

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This is a presentation of the main ideas and methods of modern nonequilibrium statistical mechanics. It is the perfect introduction for anyone in chemistry or physics who needs an update or background in this time-dependent field. Topics covered include fluctuation-dissipation theorem; linear response theory; time correlation functions, and projection operators. Theoretical models are illustrated by real-world examples and numerous applications such as chemical reaction rates and spectral line shapes are covered. The mathematical treatments are detailed and easily understandable and the appendices include useful mathematical methods like the Laplace transforms, Gaussian random variables and phenomenological transport equations.

Non-equilibrium Thermodynamics of Heterogeneous Systems

Non-equilibrium Thermodynamics of Heterogeneous Systems
Author: Signe Kjelstrup
Publisher: World Scientific Publishing Company Incorporated
Total Pages: 434
Release: 2008
Genre: Science
ISBN: 9812779132

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"The purpose of this book is to encourage the use of non-equilibrium thermodynamics to describe transport in complex, heterogeneous media. With large coupling effects between the transport of heat, mass, charge and chemical reactions at surfaces, it is important to know how one should properly integrate across systems where different phases are in contact. No other book gives a prescription of how to set up flux equations for transports across heterogeneous systems." "The authors apply the thermodynamic description in terms of excess densities, developed by Gibbs for equilibrium, to non-equilibrium systems. The treatment is restricted to transport into and through the surface. Using local equilibrium together with the balance equations for the surface, expressions for the excess entropy production of the surface and of the contact line are derived. Many examples are given to illustrate how the theory can be applied to coupled transport of mass, heat, charge and chemical reactions; in phase transitions, at electrode surfaces and in fuel cells. Molecular simulations and analytical studies are used to add insight."--BOOK JACKET.

An Introduction to Chaos in Nonequilibrium Statistical Mechanics

An Introduction to Chaos in Nonequilibrium Statistical Mechanics
Author: J. R. Dorfman
Publisher: Cambridge University Press
Total Pages: 303
Release: 1999-08-28
Genre: Science
ISBN: 0521655897

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Introduction to applications and techniques in non-equilibrium statistical mechanics of chaotic dynamics.