NMR Studies of Boron Hydrides and Related Compounds
Author | : Gareth R. Eaton |
Publisher | : |
Total Pages | : 680 |
Release | : 1969 |
Genre | : Science |
ISBN | : |
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Author | : Gareth R. Eaton |
Publisher | : |
Total Pages | : 680 |
Release | : 1969 |
Genre | : Science |
ISBN | : |
Author | : Heinrich Nöth |
Publisher | : Springer Science & Business Media |
Total Pages | : 474 |
Release | : 2012-12-06 |
Genre | : Science |
ISBN | : 3642667570 |
The revolutionary impetus of the NMR methods in organic chemistry has parallels in the field of boron chemistry. lIB NMR spectroscopy provided a basis for the elucida tion of structures and reactions of the boron hydrides. However, although many studies have been carried out with the higher boranes, carboranes, metalloboranes, etc. , and although certain patterns have emerged, the correlation between the observed chemical shift and the assigned structural unit is still not fully understood. Therefore, predictions in this area are still rather limited, and semiquantitative interpretations are not yet pos sible. Several years ago Eaton and Lipscomb sUpImarized the status in this field in their book "NMR Studies of Boron Hydrides and Related Compounds" and a plethora of new data has accumulated since then. The book also contained material on simple bo rane derivatives, but they were not discussed in any detail. On the other hand many systematic studies, both synthetic and spectroscopic, have been conducted on these simple boron materials in the last decade. Thus a large amount of NMR information is available, not only on lIB but also on 1 H, 1 3 C, and 14 N. However, this information is widely scattered in the literature, and often the data are not discussed at all. It see med appropriate, therefore, to collect these data and to present them in one volume.
Author | : Gareth R. Eaton |
Publisher | : |
Total Pages | : 617 |
Release | : 1969 |
Genre | : |
ISBN | : |
Author | : William N. Lipscomb |
Publisher | : Courier Corporation |
Total Pages | : 347 |
Release | : 2013-05-13 |
Genre | : Science |
ISBN | : 0486271986 |
In this classic monograph, Nobel Prize–winning chemist William N. Lipscomb elucidates his area of expertise: the general structural principles and reactions of boron hydrides and related compounds. Lipscomb's work appeared only a decade after the structures of boron hydrides were first elucidated and their chemistry formulated into a widely applicable framework. His observations led to a major reconsideration of how atoms bond to form stable molecules. A concise treatment of the many separate parts of the structural theory and its relation to chemistry, this volume begins with an overview of boron hydrides and related structures, progressing to three-center bonds and their applications, molecular orbitals, nuclear magnetic resonance studies of boron hydrides and related compounds, and reactions of the boron hydrides. More than 120 diagrams and figures illustrate a variety of structures.
Author | : H. Steinberg |
Publisher | : Elsevier |
Total Pages | : 499 |
Release | : 2013-09-03 |
Genre | : Science |
ISBN | : 1483224899 |
Progress in Boron Chemistry, Volume I is a 10-chapter text that covers the advances in the chemistry of various boron compounds and their applications. The opening chapter deals with the chemistry of compounds containing boron-boron bonds, followed by a brief overview of some aspects of the coordination chemistry of boron. The subsequent chapters discuss the molecular structures of boron hydrides and the chemotherapeutic potential of boron compounds. Other chapters explore the chemistry of other boron compounds, including heteroaromatic boron compounds, organoperoxyboranes, organoboron heterocycles, and boronic acids. The concluding chapter describes the NMR studies of boron compounds. This book is of value to organic, inorganic, and analytical chemists.
Author | : Gareth R. Eaton |
Publisher | : |
Total Pages | : 617 |
Release | : 1969 |
Genre | : |
ISBN | : |
Author | : Edward John Stampf |
Publisher | : |
Total Pages | : 222 |
Release | : 1976 |
Genre | : Boron |
ISBN | : |
Author | : H. Nöth |
Publisher | : Elsevier |
Total Pages | : 128 |
Release | : 2013-10-22 |
Genre | : Science |
ISBN | : 1483157903 |
Boron Chemistry contains the selected lectures presented at the Third International Meeting on Boron Chemistry held at Munich & Ettal, FRG on July 5-9, 1976. Separating nine papers as chapters, this book discusses effects of orbital vacancies in boron compounds, the aminoboronation reaction, and the cyclic coordination of boron compounds. This text also explores the organoboranes in synthesis and analysis; the synthesis, structure, and chemical reactions of metalloboranes; and studies of the smaller boron hydrides and their derivatives.
Author | : R. J. Brotherton |
Publisher | : Elsevier |
Total Pages | : 314 |
Release | : 2016-10-12 |
Genre | : Science |
ISBN | : 1483146618 |
Progress in Boron Chemistry, Volume 2 presents the chemistry and applications of boron and its compounds. This book provides a critical treatment of six areas of boron chemistry, including polyhedral borane ions, carboranes, polymers, hydrogen, metal borides, and elemental boron. Organized into six chapters, this volume begins with an overview of the structures as well as the synthesis of polyhedral borane anions. This text then examines the various types of classes and series of the carboranes. Other chapters consider the relatively intramolecular rearrangements and intramolecular exchange reactions concerning the various closo-carboranes and nido-carboranes. This book discusses as well the formation and the historical significance of a higher boron hydride polymer. The final chapter deals with the structural utilization of boron filaments, which promises to be the first large-scale use for comparatively high purity elemental boron. This book is intended to be suitable for boron chemists, chemical engineers, scientists, and research workers.
Author | : Earl Muetterties |
Publisher | : Elsevier |
Total Pages | : 545 |
Release | : 2012-12-02 |
Genre | : Science |
ISBN | : 032314649X |
Boron Hydride Chemistry covers the significant contributions of boron hydride research in the subjects of bonding, structure, and stereochemistry. This book contains 12 chapters that illustrate the merging of certain areas of boron hydride chemistry with other disciplines, such as organic, organometallic, and transition metal chemistry. After providing an overview of the general geometric, stereochemical, and dynamic stereochemical features of boron hydrides, this book goes on exploring the bonding theory and theoretical research on boron hydrides, with an emphasis on boron hydrides that have open polyhedral structures. These topics are followed by discussions on gas phase and solution reactions of borane and substituted boranes. A chapter focuses on the chemistry of cations containing boron atoms bonded to hydrogen. The remaining chapters examine the syntheses, structures, bonding, spectral properties, and chemistry of specific boron hydrides, including borazines, closo-boron hydrides, carboranes, icosahedral carboranes, and close- and nido-heteroboranes. Inorganic chemists and researchers, teachers, and undergraduate inorganic chemistry students will find this book invaluable.