Molten Salt Techniques

Molten Salt Techniques
Author: D.G. Lovering
Publisher: Springer
Total Pages: 304
Release: 1991-01-31
Genre: Science
ISBN:

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This fourth volume in the series opens some new arenas in the realm of molten salts technology, with research reports on amides, amide mixtures, and their electrochemical properties; chromatography in liquid organic salts; thermal conductivity; magnetic, calorimetric, and ultra-high-pressure measure

Molten Salt Techniques

Molten Salt Techniques
Author: Robert J. Gale
Publisher: Springer Science & Business Media
Total Pages: 270
Release: 2013-11-27
Genre: Science
ISBN: 1461575028

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This second volume carries on the excellent work of its predecessor, ex tending its scope to other melts and to other techniques. It continues to present first-hand understanding and experience of this difficult and demanding field. There is ever present the trade-off or reconciliation between the novel chemistry of systems not dominated by the mediating influence of a supposedly indifferent solvent and the high temperatures required to effect the fluidity of the system. At the limit, the very high temperatures so increase the rates of all reactions as to dissolve the temporal difference between the thermodynamic and the kinetic view of chemistry. What can happen will happen and invariably does happen. Vessels corrode, the apparatus becomes a reactant, and the number of tolerant materials able to withstand the attack shrinks to graphite, boron carbide or, if all else fails, to frozen parts of the molten salt itself. It is probably true that there is no limit to man's ingenuity but I believe that God gave us molten salts just to test that thesis. If there is ever a Molten Salt Club, and Englishmen love clubs, its membership will be exclusive. It would certainly include the authors of this series. Graham Hills University of Strathclyde ix Preface In the first volume of this series, we expressed our contention that a real need existed for practical guidance in the field of molten salt experimentation.

Molten Salt Technology

Molten Salt Technology
Author: David G. Lovering
Publisher: Springer
Total Pages: 536
Release: 2014-11-14
Genre: Education
ISBN: 1475717245

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Molten Salt Techniques -

Molten Salt Techniques -
Author: Gale RJ Ed
Publisher:
Total Pages:
Release: 1984
Genre:
ISBN:

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Molten Salt Techniques

Molten Salt Techniques
Author: D.G. Lovering
Publisher: Springer
Total Pages: 378
Release: 1987-06-30
Genre: Science
ISBN:

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The physicist Kamerlingh Onnes, who was the first to liquify helium (1908), had written on the walls of his laboratory in Leiden: "From measur ing to knowing." As true as this is at very low temperatures, it is just as applicable at the high temperatures of molten salts. Only on the basis of exact measurements by a plethora of experimental methods can any real understanding be reached of both classes of liquids. In both temperature ranges experimental difficulties are much greater than those encountered around ambient temperature. Molten salts often present a formidable challenge to the experimen talist, for example, because of corrosion and other materials problems. Applications of molten salts were for a long time based on empirical knowledge alone. This was true for the first application of molten salts in 1807, when Davy obtained sodium and potassium by electrolysis of the molten hydroxides. For 100 years the winning of aluminum has been based on the very nearly simultaneous invention by Hall and Heroult (1886) of the electrolysis of molten cryolite. The process, though essentially unchanged, has since been perfected owing to an improvement in our understanding of what actually happens, based on difficult measurements ofthe many variables. However, even now there are gaps in our knowledge.

Molten Salt Techniques

Molten Salt Techniques
Author: D.G. Lovering
Publisher: Springer
Total Pages: 304
Release: 1983-09-30
Genre: Science
ISBN:

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This second volume carries on the excellent work of its predecessor, ex- tending its scope to other melts and to other techniques. It continues to present first-hand understanding and experience of this difficult and demanding field. There is ever present the trade-off or reconciliation between the novel chemistry of systems not dominated by the mediating influence of a supposedly indifferent solvent and the high temperatures required to effect the fluidity of the system. At the limit, the very high temperatures so increase the rates of all reactions as to dissolve the temporal difference between the thermodynamic and the kinetic view of chemistry. What can happen will happen and invariably does happen. Vessels corrode, the apparatus becomes a reactant, and the number of tolerant materials able to withstand the attack shrinks to graphite, boron carbide or, if all else fails, to frozen parts of the molten salt itself. It is probably true that there is no limit to man's ingenuity but I believe that God gave us molten salts just to test that thesis. If there is ever a Molten Salt Club, and Englishmen love clubs, its membership will be exclusive.It would certainly include the authors of this series. Graham Hills University of Strathclyde ix Preface In the first volume of this series, we expressed our contention that a real need existed for practical guidance in the field of molten salt experimentation.

Molten Salts Chemistry and Technology

Molten Salts Chemistry and Technology
Author: Marcelle Gaune-Escard
Publisher: John Wiley & Sons
Total Pages: 902
Release: 2014-05-12
Genre: Science
ISBN: 1118448820

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Written to record and report on recent research progresses in the field of molten salts, Molten Salts Chemistry and Technology focuses on molten salts and ionic liquids for sustainable supply and application of materials. Including coverage of molten salt reactors, electrodeposition, aluminium electrolysis, electrochemistry, and electrowinning, the text provides researchers and postgraduate students with applications include energy conversion (solar cells and fuel cells), heat storage, green solvents, metallurgy, nuclear industry, pharmaceutics and biotechnology.

Molten Salts

Molten Salts
Author: Marcelle Gaune-Escard
Publisher: Springer Science & Business Media
Total Pages: 408
Release: 2012-12-06
Genre: Science
ISBN: 9401004587

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Several state-of-the-art applications of molten salts are presented, such as metal-molten salt systems, room temperature glass formation, and room temperature melts. Several recent examples of applications highlight the importance of molten salts in various industries (batteries, pyrochemical reprocessing of nuclear fuel, synthesis and catalysis). The basic concepts of the structure, dynamics, electrochemistry, interfacial and thermodynamic properties are detailed and relevant experimental methods described. Such fundamental concepts are essential for an in-depth understanding of the physicochemical properties of molten salts in general, including metal-molten salts, glass forming and low temperature melts. Experimental methods for investigating structural, dynamical, electrochemical thermodynamical and interfacial properties are detailed, as also are techniques for data collection and analysis. Scientists, engineers and technologists will find the volume a valuable reference source covering a wide spectrum of fundamental concepts and modern technologies.

Molten Salts Chemistry

Molten Salts Chemistry
Author: FREDERIC Lantelme
Publisher: Elsevier
Total Pages: 0
Release: 2013-08-30
Genre: Science
ISBN: 9780123985385

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Molten salts and fused media provide the key properties and the theory of molten salts, as well as aspects of fused salts chemistry, helping you generate new ideas and applications for fused salts. Molten Salts Chemistry: From Lab to Applications examines how the electrical and thermal properties of molten salts, and generally low vapour pressure are well adapted to high temperature chemistry, enabling fast reaction rates. It also explains how their ability to dissolve many inorganic compounds such as oxides, nitrides, carbides and other salts make molten salts ideal as solvents in electrometallurgy, metal coating, treatment of by-products and energy conversion. This book also reviews newer applications of molten salts including materials for energy storage such as carbon nano-particles for efficient super capacitors, high capacity molten salt batteries and for heat transport and storage in solar plants. In addition, owing to their high thermal stability, they are considered as ideal candidates for the development of safer nuclear reactors and for the treatment of nuclear waste, especially to separate actinides from lanthanides by electrorefining.

Advances in Molten Salt Chemistry

Advances in Molten Salt Chemistry
Author: J. Braunstein
Publisher: Springer Science & Business Media
Total Pages: 290
Release: 2012-12-06
Genre: Science
ISBN: 1475705042

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Molten salts are investigated by very diverse techniques and for differ ing purposes, and the results are reported in widely scattered journals. There is a need to keep investigators aware of progress in other specialties and to provide students with source and background material. Advances in Molten Salt Chemistry hopes to fill these needs by providing reviews of recent progress presented, insofar as is reasonable, with enough background material and commentary to be comprehensible to a nonspecialist. We prefer a discussion of underlying principles, to the extent that they are known, and we encourage authors to comment critically on the reliability of data, the utility of models, and the cogency of ideas and theories. We take a broad vie~ of the suitability of topics for inclusion in this series. Both fundamental and technological advances have a place here, as do studies on materials related to molten salts (like liquid silicates, very concentrated aqueous solutions, solutions of salts in liquid metals, and solid electrolytes). We intend this series to serve the needs of those who investigate or use molten salts. We welcome suggestions of topics and suitable authors, as well as comments on the strengths and shortcomings of what is published.