Laser Spectroscopy and Dynamics of Transient Species Formed in Pyrolysis Reactions. Three Year Progress Report, June 1, 1989--May 31, 1992

Laser Spectroscopy and Dynamics of Transient Species Formed in Pyrolysis Reactions. Three Year Progress Report, June 1, 1989--May 31, 1992
Author:
Publisher:
Total Pages: 15
Release: 1991
Genre:
ISBN:

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This research concerns the study of the spectroscopy and excited state dynamics of a number of transient molecules containing either sulfur or oxygen. The identification and study of sulfur species which are analogs of important oxygen-containing combustion intermediates is important to our understanding of reactive intermediates. The oxygen-containing species chosen for study are new systems whose electronic spectra have not previously been identified. The major experimental technique used in this work was pyrolysis jet spectroscopy. Since many of the species have not been previously studied by laser techniques, much effort was devoted to determining methods for producing and observing them. We have been very successful in a number of cases and have developed some further experimental techniques.

Laser Spectroscopy and Dynamics of Transient Species Formed in Pyrolysis Reactions

Laser Spectroscopy and Dynamics of Transient Species Formed in Pyrolysis Reactions
Author:
Publisher:
Total Pages: 15
Release: 1991
Genre:
ISBN:

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This research concerns the study of the spectroscopy and excited state dynamics of a number of transient molecules containing either sulfur or oxygen. The identification and study of sulfur species which are analogs of important oxygen-containing combustion intermediates is important to our understanding of reactive intermediates. The oxygen-containing species chosen for study are new systems whose electronic spectra have not previously been identified. The major experimental technique used in this work was pyrolysis jet spectroscopy. Since many of the species have not been previously studied by laser techniques, much effort was devoted to determining methods for producing and observing them. We have been very successful in a number of cases and have developed some further experimental techniques.

Energy Research Abstracts

Energy Research Abstracts
Author:
Publisher:
Total Pages: 754
Release: 1993
Genre: Power resources
ISBN:

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Laser Spectroscopy and Dynamics of Transient Species. Progress Report, June 1, 1993--May 31, 1994

Laser Spectroscopy and Dynamics of Transient Species. Progress Report, June 1, 1993--May 31, 1994
Author:
Publisher:
Total Pages: 5
Release: 1994
Genre:
ISBN:

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Work was done on sub-Doppler spectroscopy of thioformaldehyde, electronic spectrum of FS2 radical, FTIR spectra of the transient molecule formyl chloride (HCOCl and DCOCl), and high-resolution FTIR spectra of the?9 (CH2 wag) and?5 (CSO symm. stretch) bands of sulfine (H2CSO), a transient species formed in pyrolysis of dimethyl sulfoxide and oxidation of thioformaldehyde.

Laser Spectroscopy and Dynamic of Transient Species. Progress Report, June 1, 1992--May 31, 1993

Laser Spectroscopy and Dynamic of Transient Species. Progress Report, June 1, 1992--May 31, 1993
Author:
Publisher:
Total Pages: 4
Release: 1993
Genre:
ISBN:

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Work on sub-Doppler spectroscopy of thioformaldehyde is nearing completion; the sub-Doppler structure in the H2CS spectrum correlates with previous observations of anomalously long fluorescence lifetimes and reduced quantum yields of fluorescence under collision-free conditions. Singlet-triplet perturbations are large and occur haphazardly when levels in the two states are near- coincidence. High-resolution FTIR spectra of many bands of HCOCl and DCOCl have been recorded. Laser fluorescence on formic acid is being studied. Reactive jet spectroscopy is being used to produce new reactive intermediates in F2/Ar gas streams. Preliminary experiments are underway in S3 and S4 systems.

Government Reports Annual Index

Government Reports Annual Index
Author:
Publisher:
Total Pages: 1190
Release: 1994
Genre: Research
ISBN:

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Sections 1-2. Keyword Index.--Section 3. Personal author index.--Section 4. Corporate author index.-- Section 5. Contract/grant number index, NTIS order/report number index 1-E.--Section 6. NTIS order/report number index F-Z.

March's Advanced Organic Chemistry

March's Advanced Organic Chemistry
Author: Michael B. Smith
Publisher: John Wiley & Sons
Total Pages: 2379
Release: 2007-01-29
Genre: Science
ISBN: 0470084944

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The Sixth Edition of a classic in organic chemistry continues its tradition of excellence Now in its sixth edition, March's Advanced Organic Chemistry remains the gold standard in organic chemistry. Throughout its six editions, students and chemists from around the world have relied on it as an essential resource for planning and executing synthetic reactions. The Sixth Edition brings the text completely current with the most recent organic reactions. In addition, the references have been updated to enable readers to find the latest primary and review literature with ease. New features include: More than 25,000 references to the literature to facilitate further research Revised mechanisms, where required, that explain concepts in clear modern terms Revisions and updates to each chapter to bring them all fully up to date with the latest reactions and discoveries A revised Appendix B to facilitate correlating chapter sections with synthetic transformations

Biochar for Environmental Management

Biochar for Environmental Management
Author: Johannes Lehmann
Publisher: Routledge
Total Pages: 450
Release: 2012-05-16
Genre: Business & Economics
ISBN: 1136571205

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Biochar is the carbon-rich product when biomass (such as wood, manure or crop residues) is heated in a closed container with little or no available air. It can be used to improve agriculture and the environment in several ways, and its stability in soil and superior nutrient-retention properties make it an ideal soil amendment to increase crop yields. In addition to this, biochar sequestration, in combination with sustainable biomass production, can be carbon-negative and therefore used to actively remove carbon dioxide from the atmosphere, with major implications for mitigation of climate change. Biochar production can also be combined with bioenergy production through the use of the gases that are given off in the pyrolysis process. This book is the first to synthesize the expanding research literature on this topic. The book's interdisciplinary approach, which covers engineering, environmental sciences, agricultural sciences, economics and policy, is a vital tool at this stage of biochar technology development. This comprehensive overview of current knowledge will be of interest to advanced students, researchers and professionals in a wide range of disciplines.