Surface Modification of Titanium Using Anodization to Enhance Antimicrobial Properties and Osseointegration

Surface Modification of Titanium Using Anodization to Enhance Antimicrobial Properties and Osseointegration
Author: Sakshi Jain
Publisher:
Total Pages: 175
Release: 2017
Genre:
ISBN:

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Titanium and its alloys are frequently used in dental and orthopedic implants because they have good mechanical strength, chemical stability and biocompatibility. These properties can be further improved by surface treatments such as anodization that are able to grow thicker and produce crystalline oxide layers with controlled morphological and physico-chemical properties. Both anatase (A) and rutile (R) crystalline phases of titanium oxide have been shown to promote bioactivity and antimicrobial effects. In a previous study in our laboratories, four electrolyte mixtures were optimized to produce anodized layers on commercially pure titanium consisting of specific anatase and rutile oxide ratios at an endpoint forming voltage of 180 V. In the present study, changes that occurred in the anodized layers with increasing forming voltage including crystallinity, thickness, surface morphology, surface roughness, surface chemistry, fractal dimension, shear strength, and corrosion resistance were determined for each of these electrolytes. The results showed the crystallinity, thickness, surface pore sizes, and surface roughness increased with increasing forming voltage. Incorporation of phosphorus into the anodized layers was shown in phosphoric acid containing electrolytes at higher forming voltages. Decreases in corrosion resistance were also shown at higher forming voltages in each electrolyte due to increased pore interconnectivity within the anodized layers. In addition, the apatite inducing ability of anodized layers in SBF was examined for selected forming voltages in each electrolyte. Anodization in phosphoric acid containing electrolytes was shown to be more favorable for apatite formation. The streptococcal and MRSA bacterial attachment before and after UV treatments was determined for selected forming voltages in each electrolyte. Additionally, the killing efficacy after 10-minute pre-irradiation with UVA or UVC treatments was determined. UVA treatments showed trends of at least a 20% reduction in bacterial attachment regardless of the crystallinity within the oxide for S. sanguinis. The anodized layer with an approximately equal distribution of anatase and rutile phases showed bacterial killing efficacy over 50% for S. sanguinis and over 80% for MRSA after UVA or UVC treatments. Finally, two forming voltage sample groups in two of the electrolytes were examined for MC3T3E-1 cell attachment, proliferation, and differentiation. Total intracellular protein content, alkaline phosphatase (ALP) activity, osteocalcin (OCN) activity, and cellular mineralization were investigated for different time periods up to 21 days. All sample groups showed suitable cellular proliferation, differentiation, and maturation but those anodized in the phosphoric acid containing electrolyte showed delayed proliferation and early differentiation and maturation. Also, anodized samples containing at least 50% anatase were shown to produce higher osteoblast mineralization compared to majority rutile phase anodized layers.

Advanced Surface Engineering Materials

Advanced Surface Engineering Materials
Author: Ashutosh Tiwari
Publisher: John Wiley & Sons
Total Pages: 705
Release: 2016-09-06
Genre: Technology & Engineering
ISBN: 1119314186

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Advanced surfaces enriches the high-throughput engineering of physical and chemical phenomenon in relatin to electrical, magnetic, electronics, thermal and optical controls, as well as large surface areas, protective coatings against water loss and excessive gas exchange. A more sophisticated example could be a highly selective surface permeability allowing passive diffusion and selective transport of molecules in the water or gases. The smart surface technology provides an interlayer model which prevents the entry of substances without affecting the properties of neighboring layers. A number of methods have been developed for coatings, which are essential building blocks for the top-down and/or bottom-up design of numerous functional materials. Advanced Surface Engineering Materials offers a detailed up-to-date review chapters on the functional coatings and adhesives, engineering of nanosurfaces, high-tech surface, characterization and new applications. The 13 chapters in this book are divided into 3 parts (Functional coatings and adhesives; Engineering of nanosurfaces; High-tech surface, characterization and new applications) and are all written by worldwide subject matter specialists. The book is written for readers from diverse backgrounds across chemistry, physics, materials science and engineering, medical science, environmental, bio- and nano- technologies and biomedical engineering. It offers a comprehensive view of cutting-edge research on surface engineering materials and their technological importance.

Titanium Dioxide

Titanium Dioxide
Author: Dongfang Yang
Publisher: BoD – Books on Demand
Total Pages: 520
Release: 2018-06-27
Genre: Technology & Engineering
ISBN: 1789233267

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Titanium dioxide is currently being used in many industrial products. It provides unique photocatalytic properties for water splitting and purification, bacterial inactivation, and organics degradation. It has also been widely used as the photoanode for dye-sensitized solar cells and coatings for self-cleaning surfaces, biomedical implants, and nanomedicine. This book covers various aspects of titanium dioxide nanomaterials including their unique one-dimensional, two-dimensional, mesoporous, and hierarchical nanostructures and their synthetic methods such as sol-gel, hydrothermal, anodic oxidation, and electrophoretic deposition, as well as its key applications in environmental and energy sectors. Through these 24 chapters written by experts from the international scientific community, readers will have access to a comprehensive overview of the recent research and development findings on the titanium dioxide nanomaterials.

Application of Titanium Dioxide

Application of Titanium Dioxide
Author: Magdalena Janus
Publisher: BoD – Books on Demand
Total Pages: 242
Release: 2017-07-26
Genre: Science
ISBN: 9535134299

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Titanium dioxide is mainly used as a pigment and photocatalyst. It is possible to find it in food, cosmetics, building materials, electric devices, and others. This book contains chapters about application of titanium dioxide in different branches of economy such as the agriculture, the food industry, the medicine, the cosmetics, the water treatment technologies, and the semiconductors.

Corrosion of Titanium

Corrosion of Titanium
Author: J. D. Jackson
Publisher:
Total Pages: 54
Release: 1966
Genre: Titanium
ISBN:

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TiO2 Nanotube Arrays

TiO2 Nanotube Arrays
Author: Craig A. Grimes
Publisher: Springer Science & Business Media
Total Pages: 380
Release: 2009-08-11
Genre: Technology & Engineering
ISBN: 1441900683

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TiO2 Nanotube Arrays: Synthesis, Properties, and Applications is the first book to provide an overview of this rapidly growing field. Vertically oriented, highly ordered TiO2 nanotube arrays are unique and easily fabricated materials with an architecture that demonstrates remarkable charge transfer as well as photocatalytic properties. This volume includes an introduction to TiO2 nanotube arrays, as well as a description of the material properties and distillation of the current research. Applications considered include gas sensing, heterojunction solar cells, water photoelectrolysis, photocatalytic CO2 reduction, as well as several biomedical applications. Written by leading researchers in the field, TiO2 Nanotube Arrays: Synthesis, Properties, and Applications is a valuable reference for chemists, materials scientists and engineers involved with renewable energy sources, biomedical engineering, and catalysis, to cite but a few examples.

Plasma Electrolytic Oxidation (PEO) Coatings

Plasma Electrolytic Oxidation (PEO) Coatings
Author: Marta Mohedano
Publisher: MDPI
Total Pages: 172
Release: 2021-06-02
Genre: Science
ISBN: 3036505520

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Plasma electrolytic oxidation (PEO), also known as micro-arc oxidation (MAO), functionalizes surfaces, improving the mechanical, thermal, and corrosion performance of metallic substrates, along with other tailored properties (e.g., biocompatibility, catalysis, antibacterial response, self-lubrication, etc.). The extensive field of applications of this technique ranges from structural components, in particular, in the transport sector, to more advanced fields, such as bioengineering. The present Special Issue covers the latest advances in PEO‐coated light alloys for structural (Al, Mg) and biomedical applications (Ti, Mg), with 10 research papers and 1 review from leading research groups around the world.

Noncarboxylic Acids: Advances in Research and Application: 2011 Edition

Noncarboxylic Acids: Advances in Research and Application: 2011 Edition
Author:
Publisher: ScholarlyEditions
Total Pages: 201
Release: 2012-01-09
Genre: Science
ISBN: 1464924538

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Noncarboxylic Acids: Advances in Research and Application: 2011 Edition is a ScholarlyEditions™ eBook that delivers timely, authoritative, and comprehensive information about Noncarboxylic Acids. The editors have built Noncarboxylic Acids: Advances in Research and Application: 2011 Edition on the vast information databases of ScholarlyNews.™ You can expect the information about Noncarboxylic Acids in this eBook to be deeper than what you can access anywhere else, as well as consistently reliable, authoritative, informed, and relevant. The content of Noncarboxylic Acids: Advances in Research and Application: 2011 Edition has been produced by the world’s leading scientists, engineers, analysts, research institutions, and companies. All of the content is from peer-reviewed sources, and all of it is written, assembled, and edited by the editors at ScholarlyEditions™ and available exclusively from us. You now have a source you can cite with authority, confidence, and credibility. More information is available at http://www.ScholarlyEditions.com/.

Bionanomaterials for Dental Applications

Bionanomaterials for Dental Applications
Author: Mieczyslaw Jurczyk
Publisher: CRC Press
Total Pages: 430
Release: 2012-10-26
Genre: Medical
ISBN: 9814303836

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This book introduces readers to the structure and characteristics of nanomaterials and their applications in dentistry. With currently available implant materials, the clinical failure rate varies from a few percent to over 10 percent and new materials are clearly needed. Nanomaterials offer the promise of higher strength, better bonding, less toxicity, and enhanced cytocompatibility, leading to increased tissue regeneration. Mieczyslaw Jurczyk, director of the Institute of Materials Science and Engineering at the Poznan University of Technology in Poland, has drawn from work in his laboratory and elsewhere in Poland to show that nanomaterials have important biological applications including in the stomatognathic system consisting of mouth, jaws, and associated structures. The book is written from a materials science and medical point of view and has 13 chapters and about 400 pages. The book can be divided approximately into three sections: the first five chapters introduce nanobiomaterials, the next five chapters describe their dental applications, and the last chapters describe their biocompatibility. Chapter 3 is a compendium on metallic biomaterials such as stainless steel, cobalt alloys, and titanium alloys; bioactive, bioresorbable polymers; and composites and ceramic biomaterials. The "top-down" approach to producing nanomaterials such as high-energy ballmilling and severe plastic deformation, as well as Feynman’s "bottom-up technique" of building atom by atom, are discussed in the next chapter. Subsequent chapters discuss each material in depth and point out how new architectures and properties emerge at the nanoscale. Chapter 8 is devoted to shape-memory materials, which now include not only NiTi but also polymers and magnetic materials. In order to improve bonding, nanomaterials can be used to synthesize implants with surface roughness similar to that of natural tissues. Chapter 9 is devoted to different surface treatments for Ti-based nanomaterials, such as anodic oxidation to improve the bioactivity of titanium and improve the corrosion resistance of porous titanium and its alloys. The use of carbon in various forms—nanoparticles, nanofibers, nanotubes, and thin films—is discussed next with emphasis on the microstructure and properties of these materials, their implant applications, and their interaction with subcutaneous tissues. Nanomaterials can be used in preventive dentistry and therefore can reduce the amount of dental treatment that is necessary to maintain a healthy mouth as argued in chapter 11. In a subsequent chapter, the author explains osseointegration (direct bone-to-metal interface) from a biological point of view and early tissue response. The mechanism of the interaction between the implanted materials with the cellular protein in the tissues is described. The last chapter discusses the application of new nanostructured materials in permanent and bioresorbable implants, nanosurface dental implants, and nanostructured dental composite restorative materials. This book not only focuses on nanomaterials but also on nanoengineering to achieve the best results in dentistry. It is recommended to anyone interested in nanomaterials and their applications in dental science. People with a background in materials, chemistry, physics, and biology will benefit from it.