High Temperature Polymer Electrolyte Membrane Fuel Cells

High Temperature Polymer Electrolyte Membrane Fuel Cells
Author: Qingfeng Li
Publisher: Springer
Total Pages: 545
Release: 2015-10-15
Genre: Technology & Engineering
ISBN: 3319170821
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This book is a comprehensive review of high-temperature polymer electrolyte membrane fuel cells (PEMFCs). PEMFCs are the preferred fuel cells for a variety of applications such as automobiles, cogeneration of heat and power units, emergency power and portable electronics. The first 5 chapters of the book describe rationalization and illustration of approaches to high temperature PEM systems. Chapters 6 - 13 are devoted to fabrication, optimization and characterization of phosphoric acid-doped polybenzimidazole membranes, the very first electrolyte system that has demonstrated the concept of and motivated extensive research activity in the field. The last 11 chapters summarize the state-of-the-art of technological development of high temperature-PEMFCs based on acid doped PBI membranes including catalysts, electrodes, MEAs, bipolar plates, modelling, stacking, diagnostics and applications.

Polymer Membranes for Fuel Cells

Polymer Membranes for Fuel Cells
Author: Javaid Zaidi
Publisher: Springer Science & Business Media
Total Pages: 439
Release: 2010-07-15
Genre: Science
ISBN: 0387735321
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From the late-1960’s, perfluorosulfonic acid (PFSAs) ionomers have dominated the PEM fuel cell industry as the membrane material of choice. The “gold standard’ amongst the many variations that exist today has been, and to a great extent still is, DuPont’s Nafion® family of materials. However, there is significant concern in the industry that these materials will not meet the cost, performance, and durability requirementsnecessary to drive commercialization in key market segments – es- cially automotive. Indeed, Honda has already put fuel cell vehicles in the hands of real end users that have home-grown fuel cell stack technology incorporating hydrocarbon-based ionomers. “Polymer Membranes in Fuel Cells” takes an in-depth look at the new chem- tries and membrane technologies that have been developed over the years to address the concerns associated with the materials currently in use. Unlike the PFSAs, which were originally developed for the chlor-alkali industry, the more recent hydrocarbon and composite materials have been developed to meet the specific requirements of PEM Fuel Cells. Having said this, most of the work has been based on derivatives of known polymers, such as poly(ether-ether ketones), to ensure that the critical requirement of low cost is met. More aggressive operational requi- ments have also spurred the development on new materials; for example, the need for operation at higher temperature under low relative humidity has spawned the creation of a plethora of new polymers with potential application in PEM Fuel Cells.

High temperature polymer electrolyte membrane fuel cells

High temperature polymer electrolyte membrane fuel cells
Author: Christian Siegel
Publisher: Logos Verlag Berlin GmbH
Total Pages: 180
Release: 2015-03-20
Genre: Fuel cells
ISBN: 3832539174
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A three-dimensional computational fluid dynamics model of a high temperature polymer electrolyte membrane fuel cell, employing a high temperature stable polybenzimidazole membrane electrode assembly doped with phosphoric acid, was developed and implemented using a commercially available finite element software. Three types of flow-fields were modeled and simulated. Selected simulation results at reference operating conditions were compared to the performance curves and to segmented solid-phase temperature and current density measurements. For the segmented measurements, an inhouse developed prototype cell was designed and manufactured. The segmented cell was successfully operated and the solid-phase temperature and the current density distribution were recorded, evaluated, and discussed. Sequentially scanned segmented electrochemical impedance spectroscopy measurements were performed to qualitatively support the observed trends. These measurements were used to identify and determine the causes of the inhomogeneous current density distributions. An equivalent circuit model was developed, the obtained spectra were analyzed, and the model parameters discussed. This work helps to provide a better understanding of the internal behaviour of a running high temperature polymer electrolyte membrane fuel cell and presents valuable data for modeling and simulation. For large fuel cells and complete fuel cell stacks in particular, well designed anode and cathode inlet and outlet sections are expected to aid in achieving flatter quantities distributions and in preventing hot spots over the membrane electrode assembly area, and to develop proper start-up, shut-down, and tempering concepts.

PEM Fuel Cells

PEM Fuel Cells
Author: Gurbinder Kaur
Publisher: Elsevier
Total Pages: 584
Release: 2021-11-16
Genre: Science
ISBN: 0128237090
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PEM Fuel Cells: Fundamentals, Advanced Technologies, and Practical Application provides a comprehensive introduction to the principles of PEM fuel cell, their working condition and application, and the latest breakthroughs and challenges for fuel cell technology. Each chapter follows a systematic and consistent structure with clear illustrations and diagrams for easy understanding. The opening chapters address the basics of PEM technology; stacking and membrane electrode assembly for PEM, degradation mechanisms of electrocatalysts, platinum dissolution and redeposition, carbon-support corrosion, bipolar plates and carbon nanotubes for the PEM, and gas diffusion layers. Thermodynamics, operating conditions, and electrochemistry address fuel cell efficiency and the fundamental workings of the PEM. Instruments and techniques for testing and diagnosis are then presented alongside practical tests. Dedicated chapters explain how to use MATLAB and COMSOL to conduct simulation and modeling of catalysts, gas diffusion layers, assembly, and membrane. Degradation and failure modes are discussed in detail, providing strategies and protocols for mitigation. High-temperature PEMs are also examined, as are the fundamentals of EIS. Critically, the environmental impact and life cycle of the production and storage of hydrogen are addressed, as are the risk and durability issues of PEMFC technology. Dedicated chapters are presented on the economics and commercialization of PEMFCs, including discussion of installation costs, initial capital costs, and the regulatory frameworks; apart from this, there is a separate chapter on their application to the automotive industry. Finally, future challenges and applications are considered. PEM Fuel Cells: Fundamentals, Advanced Technologies, and Practical Application provides an in-depth and comprehensive reference on every aspect of PEM fuel cells fundamentals, ideal for researchers, graduates, and students. Presents the fundamentals of PEM fuel cell technology, electrolytes, membranes, modeling, conductivity, recent trends, and future applications Addresses commercialization, public policy, and the environmental impacts of PEMFC in dedicated chapters Presents state-of-the-art PEMFC research alongside the underlying concepts

Nanocarbons for Energy Conversion: Supramolecular Approaches

Nanocarbons for Energy Conversion: Supramolecular Approaches
Author: Naotoshi Nakashima
Publisher: Springer
Total Pages: 564
Release: 2018-08-13
Genre: Technology & Engineering
ISBN: 3319929178
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This book focuses on nanocarbons (carbon nanotubes, graphene, nanoporous carbon, and carbon black) and related materials for energy conversion, including fuel cells (predominately proton exchange membrane fuel cells [PEMFC]), Li-ion batteries, and supercapacitors. Written by a group of internationally recognized researchers, it offers an in-depth review of the structure, properties, and functions of nanocarbons, and summarizes recent advances in the design, fabrication and characterization of nanocarbon-based catalysts for energy applications. As such, it is an invaluable resource for graduate students, academics and industrial scientists interested in the areas of nanocarbons, energy materials for fuel cells, batteries and supercapacitors as well as materials design, and supramolecular science.

Polymer Electrolyte Fuel Cell Durability

Polymer Electrolyte Fuel Cell Durability
Author: Felix N. Büchi
Publisher: Springer Science & Business Media
Total Pages: 489
Release: 2009-02-08
Genre: Science
ISBN: 038785536X
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This book covers a significant number of R&D projects, performed mostly after 2000, devoted to the understanding and prevention of performance degradation processes in polymer electrolyte fuel cells (PEFCs). The extent and severity of performance degradation processes in PEFCs were recognized rather gradually. Indeed, the recognition overlapped with a significant number of industrial dem- strations of fuel cell powered vehicles, which would suggest a degree of technology maturity beyond the resaolution of fundamental failure mechanisms. An intriguing question, therefore, is why has there been this apparent delay in addressing fun- mental performance stability requirements. The apparent answer is that testing of the power system under fully realistic operation conditions was one prerequisite for revealing the nature and extent of some key modes of PEFC stack failure. Such modes of failure were not exposed to a similar degree, or not at all, in earlier tests of PEFC stacks which were not performed under fully relevant conditions, parti- larly such tests which did not include multiple on–off and/or high power–low power cycles typical for transportation and mobile power applications of PEFCs. Long-term testing of PEFCs reported in the early 1990s by both Los Alamos National Laboratory and Ballard Power was performed under conditions of c- stant cell voltage, typically near the maximum power point of the PEFC.

Fuel Cells and Hydrogen Production

Fuel Cells and Hydrogen Production
Author: Timothy E. Lipman
Publisher: Springer
Total Pages: 0
Release: 2018-10-05
Genre: Technology & Engineering
ISBN: 9781493977888
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The expected end of the “oil age” will lead to increasing focus and reliance on alternative energy conversion devices, among which fuel cells have the potential to play an important role. Not only can phosphoric acid and solid oxide fuel cells already efficiently convert today’s fossil fuels, including methane, into electricity, but other types of fuel cells, such as polymer electrolyte membrane fuel cells, have the potential to become the cornerstones of a possible future hydrogen economy. This handbook offers concise yet comprehensive coverage of the current state of fuel cell research and identifies key areas for future investigation. Internationally renowned specialists provide authoritative introductions to a wide variety of fuel cell types and hydrogen production technologies, and discuss materials and components for these systems. Sustainability and marketing considerations are also covered, including comparisons of fuel cells with alternative technologies.

High-temperature Solid Oxide Fuel Cells for the 21st Century

High-temperature Solid Oxide Fuel Cells for the 21st Century
Author: Kevin Kendall
Publisher: Elsevier
Total Pages: 520
Release: 2015-11-21
Genre: Technology & Engineering
ISBN: 0124104835
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High-temperature Solid Oxide Fuel Cells, Second Edition, explores the growing interest in fuel cells as a sustainable source of energy. The text brings the topic of green energy front and center, illustrating the need for new books that provide comprehensive and practical information on specific types of fuel cells and their applications. This landmark volume on solid oxide fuel cells contains contributions from experts of international repute, and provides a single source of the latest knowledge on this topic. A single source for all the latest information on solid oxide fuel cells and their applications Illustrates the need for new, more comprehensive books and study on the topic Explores the growing interest in fuel cells as viable, sustainable sources of energy

Proton Exchange Membrane Fuel Cells

Proton Exchange Membrane Fuel Cells
Author: David P. Wilkinson
Publisher: CRC Press
Total Pages: 462
Release: 2009-11-24
Genre: Science
ISBN: 1439806667
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A Detailed, Up-to-Date Treatment of Key Developments in PEMFC MaterialsThe potential to revolutionize the way we power our worldBecause of its lower temperature and special polymer electrolyte membrane, the proton exchange membrane fuel cell (PEMFC) is well-suited for transportation, portable, and micro fuel cell applications. But the performance o

Recent Advances in High-Temperature PEM Fuel Cells

Recent Advances in High-Temperature PEM Fuel Cells
Author: Sivakumar Pasupathi
Publisher: Academic Press
Total Pages: 86
Release: 2016-09-13
Genre: Technology & Engineering
ISBN: 0128103868
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Hydrogen and Fuel Cells Primers is a series focused on Energy applications. Its concise volumes present those coming into this broad and multidisciplinary field with the most recent advances in each of its particular topics. They bring together information that has thus far been scattered in many different sources under one single title, which makes them a useful reference for industry professionals, researchers and graduate students, especially those starting in a new topic of research. This volume, Recent Advances in High Temperature PEM Fuel Cells, provides an up-to-date progress of High Temperature Polymer Electrolyte Membrane Fuel Cells (HTPEMFCs), including three critical subjects for this type of fuel cells: Membrane Electrode Assembly (MEA) development, stack development and systems development. The MEA and stack development sections cover the recent advances in this area and highlight the areas in most need of improvement. The systems development section focuses on stationary systems, mainly Combined Heat and Power (CHP), based on HTPEMFCs. Finally the conclusions summarize the recent advances of HTPEMFCs in all these areas and provide some insights for future developments. Prof. Bruno G. Pollet, Series Editor Presents the most current knowledge in membrane electrode assembly, stack, and systems development for HTPEMFCs Highlights the areas that need improvement in electrode assembly and stack development Examines stationary high temperature PEMFC systems, including CHP