High-Resolution Spectroscopy of Transient Molecules

High-Resolution Spectroscopy of Transient Molecules
Author: Eizi Hirota
Publisher: Springer Science & Business Media
Total Pages: 245
Release: 2012-12-06
Genre: Science
ISBN: 3642824773

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It is a great challenge in chemistry to clarify every detail of reaction processes. In older days chemists mixed starting materials in a flask and took the resul tants out of it after a while, leaving all the intermediate steps uncleared as a sort of black box. One had to be content with only changing temperature and pressure to accelerate or decelerate chemical reactions, and there was almost no hope of initiating new reactions. However, a number of new techniques and new methods have been introduced and have provided us with a clue to the examination of the black box of chemical reaction. Flash photolysis, which was invented in the 1950s, is such an example; this method has been combined with high-resolution electronic spectroscopy with photographic recording of the spectra to provide a large amount of precise and detailed data on transient molecules which occur as intermediates during the course of chemical reac tions. In 1960 a fundamentally new light source was devised, i. e. , the laser. When the present author and coworkers started high-resolution spectroscopic stud ies of transient molecules at a new research institute, the Institute for Molecu lar Science in Okazaki in 1975, the time was right to exploit this new light source and its microwave precursor in order to shed light on the black box.

Handbook of High-resolution Spectroscopy

Handbook of High-resolution Spectroscopy
Author: Martin Quack
Publisher: John Wiley & Sons
Total Pages: 2236
Release: 2011-09-26
Genre: Science
ISBN: 0470066539

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The field of High-Resolution Spectroscopy has been considerably extended and even redefined in some areas. Combining the knowledge of spectroscopy, laser technology, chemical computation, and experiments, Handbook of High-Resolution Spectroscopy provides a comprehensive survey of the whole field as it presents itself today, with emphasis on the recent developments. This essential handbook for advanced research students, graduate students, and researchers takes a systematic approach through the range of wavelengths and includes the latest advances in experiment and theory that will help and guide future applications. The first comprehensive survey in high-resolution molecular spectroscopy for over 15 years Brings together the knowledge of spectroscopy, laser technology, chemical computation and experiments Brings the reader up-to-date with the many advances that have been made in recent times Takes the reader through the range of wavelengths, covering all possible techniques such as Microwave Spectroscopy, Infrared Spectroscopy, Raman Spectroscopy, VIS, UV and VUV Combines theoretical, computational and experimental aspects Has numerous applications in a wide range of scientific domains Edited by two leaders in this field Provides an overview of rotational, vibration, electronic and photoelectron spectroscopy Volume 1 - Introduction: Fundamentals of Molecular Spectroscopy Volume 2 - High-Resolution Molecular Spectroscopy: Methods and Results Volume 3 - Special Methods & Applications

Very High Resolution Photoelectron Spectroscopy

Very High Resolution Photoelectron Spectroscopy
Author: Stephan Hüfner
Publisher: Springer Science & Business Media
Total Pages: 411
Release: 2007-02-09
Genre: Science
ISBN: 3540681302

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Photoemission spectroscopy is one of the most extensively used methods to study the electronic structure of atoms, molecules, and solids and their surfaces. This volume introduces and surveys the field at highest energy and momentum resolutions allowing for a new range of applications, in particular for studies of high temperature superconductors.

High-Resolution Laser Spectroscopy

High-Resolution Laser Spectroscopy
Author: K. Shimoda
Publisher: Springer
Total Pages: 380
Release: 2014-03-12
Genre: Technology & Engineering
ISBN: 9783662312483

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With contributions by numerous experts

High Resolution Spectroscopy

High Resolution Spectroscopy
Author: Samuel Tolansky
Publisher:
Total Pages: 318
Release: 1947
Genre: Science
ISBN:

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High-resolution NMR Techniques in Organic Chemistry

High-resolution NMR Techniques in Organic Chemistry
Author: T. Claridge
Publisher: Elsevier
Total Pages: 408
Release: 1999-12-24
Genre: Science
ISBN: 9780080427997

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From the initial observation of proton magnetic resonance in water and in paraffin, the discipline of nuclear magnetic resonance has seen unparalleled growth as an analytical method. Modern NMR spectroscopy is a highly developed, yet still evolving, subject which finds application in chemistry, biology, medicine, materials science and geology. In this book, emphasis is on the more recently developed methods of solution-state NMR applicable to chemical research, which are chosen for their wide applicability and robustness. These have, in many cases, already become established techniques in NMR laboratories, in both academic and industrial establishments. A considerable amount of information and guidance is given on the implementation and execution of the techniques described in this book.

High Resolution Spectroscopy

High Resolution Spectroscopy
Author: J. Michael Hollas
Publisher: Butterworth-Heinemann
Total Pages: 654
Release: 2013-10-22
Genre: Science
ISBN: 1483100901

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High Resolution Spectroscopy discusses the underlying concepts in the different branches of spectroscopy, especially in high resolution spectroscopy. The coverage of the book includes basic principles such as the quantization of energy, as well as the interaction of electromagnetic radiation with atoms and molecules; general experimental methods and features of instrumentation; and microwave, millimeter wave, and lamb dip spectroscopy. Also covered in the book are subjects such as the principles behind rotational spectroscopy; diatomic and polyatomic molecules in vibrational spectroscopy; and the electronic spectroscopy of atoms, as well as diatomic and polyatomic molecules. The text is recommended for engineers and physicists who would like to know more about the concepts, theories, methods, and instrumentation related to spectroscopy, particularly in the field of high resolution spectroscopy.

High Resolution Spectroscopy

High Resolution Spectroscopy
Author: J. Michael Hollas
Publisher: John Wiley & Sons
Total Pages: 772
Release: 1998-10-15
Genre: Science
ISBN:

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Encompassing a wide range of techniques, spectroscopy is used to analyze chemicals, biological and pharmaceutical compounds, food and beverages, and high-tech materials. Covering the whole range of spectroscopic techniques, this book provides a thorough overview of underlying principles, techniques and applications. Dr. Hollas is a well-known author and authority in the field, and this book is an expanded version of his well-received lower-level book, Modern Spectroscopy, now in its third edition (0-471-96523-5). "The first edition of High Resolution Spectroscopy (the big book version of Modern Spectroscopy) was undoubtedly the best textbook on spectroscopy written at an undergraduate / beginning graduate level, and the second edition is an improvement... ...The coverage is broad, deep and even. The first chapters give a concise and clear introduction to spectroscopy, covering much that is accessible elsewhere only in more complicated discussions... ...The production values of High Resolution Spectroscopy are high, diagrams are well reproduced and the whole text is lavishly illustrated with many spectra and diagrams of apparatus.... ... it contains a great deal of material and is beautifully written; every library should contain a copy; every student of spectroscopy (no-matter what age!) should have a copy on their shelves." Extracts from a Review in Spectroscopy Europe, 11/3 (1999)

Principles of High Resolution NMR in Solids

Principles of High Resolution NMR in Solids
Author: M. Mehring
Publisher: Springer Science & Business Media
Total Pages: 352
Release: 2012-12-06
Genre: Science
ISBN: 3642687563

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The field of Nuclear Magnetic Resonance (NMR) has developed at a fascinating pace during the last decade. It always has been an extremely valuable tool to the organic chemist by supplying molecular "finger print" spectra at the atomic level. Unfortunately the high resolution achievable in liquid solutions could not be obtained in solids and physicists and physical chemists had to live with unresolved lines open to a wealth of curve fitting procedures and a vast amount of speculations. High resolution NMR in solids seemed to be a paradoxon. Broad structure less lines are usually encountered when dealing with NMR in solids. Only with the recent advent of mUltiple pulse, magic angle, cross-polarization, two-dimen sional and multiple-quantum spectroscopy and other techniques during the last decade it became possible to resolve finer details of nuclear spin interactions in solids. I have felt that graduate students, researchers and others beginning to get involved with these techniques needed a book which treats the principles, theo retical foundations and applications of these rather sophisticated experimental techniques. Therefore I wrote a monograph on the subject in 1976. Very soon new ideas led to the developement of "two-dimensional spectroscopy" and "multiple-quantum spectroscopy", topics which were not covered in the first edition of my book. Moreover an exponential growth of literature appeared in this area of research leaving the beginner in an awkward situation of tracing back from a current article to the roots of the experiment.