Orthogonal Supramolecular Interaction Motifs for Functional Monolayer Architectures

Orthogonal Supramolecular Interaction Motifs for Functional Monolayer Architectures
Author: Mahmut Deniz Yilmaz
Publisher: Springer Science & Business Media
Total Pages: 115
Release: 2012-05-30
Genre: Science
ISBN: 3642302572

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Deniz Yilmaz' thesis describes a combination of orthogonal supramolecular interactions for the design of functional monolayer architectures on surfaces, that can be used as chemical and biosensors in a wide range of applications. The term “orthogonal supramolecular interactions” refers to non-covalent interactions that do not influence each other's assembly properties. Orthogonal self-assembly thus allows extended control over the self-assembly process and promotes new materials properties. The first part of the thesis employs orthogonal host-guest and lanthanide-ligand coordination interaction motifs to create supramolecular luminescent monolayers. The second part of the thesis describes the fabrication of functional monolayers on silicon and gold substrates for applications in electronics. The results illustrate the power of weak supramolecular interactions to direct the immobilization of functional systems on surfaces. The combination of host-guest and lanthanide-ligand coordination interaction motifs on surfaces demonstrates that hybrid, multifunctional supramolecular monolayers can be fabricated by integrating different non-covalent interactions in the same system. This combination opens up new avenues for the fabrication of complex hybrid organic-inorganic materials and stimuli-responsive surfaces. Their utility is demonstrated through applications of the functional interfaces to biosensing and nanotechnology.

Functional Supramolecular Architectures

Functional Supramolecular Architectures
Author: Paolo Samorì
Publisher: John Wiley & Sons
Total Pages: 1332
Release: 2014-06-13
Genre: Technology & Engineering
ISBN: 3527689915

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A comprehensive overview of functional nanosystems based on organic and polymeric materials and their impact on current and future research and technology in the highly interdisciplinary field of materials science. As such, this handbook covers synthesis and fabrication methods, as well as properties and characterization of supramolecular architectures. Much of the contents are devoted to existing and emerging applications, such as organic solar cells, transistors, diodes, nanowires and molecular switches. The result is an indispensable resource for materials scientists, organic chemists, molecular physicists and electrochemists looking for a reliable reference on this hot topic.

Supramolecular Chemistry

Supramolecular Chemistry
Author: Stefan Kubik
Publisher: Walter de Gruyter GmbH & Co KG
Total Pages: 656
Release: 2024-07-22
Genre: Science
ISBN: 3111315177

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This introductory textbook on supramolecular chemistry is a thoroughly revised and expanded version of the 1st edition, originally published in 2020. All chapters have been brought up to date and now include "Further Reading" sections that highlight relevant developments. In addition, a new chapter on supramolecular polymers has been added. With these changes, this book provides an even more comprehensive introduction to the exciting field of supramolecular chemistry than before. Readers will learn what forces hold supramolecular architectures together, how supramolecular systems are created and characterized, how molecular switches, motors, transporters, catalysts, chemosensors, and other functional systems work, and where supramolecular chemistry can play or already plays a role in our lives. In 2022 the first edition of this book won the Literature Prize of the German Chemical Industry Association VCI. For the full press release (in German): https://www.vci.de/fonds/presse-und-infos/pressemitteilungen/preisgeld-fuer-supramolekuele.jsp

Functional Supramolecular Materials

Functional Supramolecular Materials
Author: Rahul Banerjee
Publisher: Royal Society of Chemistry
Total Pages: 476
Release: 2017-05-05
Genre: Science
ISBN: 1788010272

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Supramolecular materials have a great number of applications due to the reversibility of their non-covalent molecular interactions, such as reversible hydrogen bonding, host–guest interactions and electrostatic interactions. This book provides a comprehensive source of information on the structure and function of organic and metal–organic supramolecular materials. The chapters of this book provide an overview of supramolecular material assembly at various scales, including the formation of 2D polymers and molecular cages. The role of intermolecular interactions in solid and solution state self-assembly is discussed, as is the role of mechanochemistry on molecular and supramolecular architectures. Finally, novel applications of these materials in molecular recognition, catalysis, light harvesting and environmental remediation are covered. Functional Supramolecular Materials will be of interest to graduate students and researchers in academia and industry in the fields of supramolecular chemistry and functional materials science.

Supramolecular Chemistry in the 3rd Millennium

Supramolecular Chemistry in the 3rd Millennium
Author: Catherine E. Housecroft
Publisher: MDPI
Total Pages: 264
Release: 2021-08-18
Genre: Science
ISBN: 3036514635

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This Special Issue is one of the first for the new MDPI flagship journal Chemistry (ISSN 2624-8549) which has a broad remit for publishing original research in all areas of chemistry. The theme of this issue is Supramolecular Chemistry in the 3rd Millennium and I am sure that this topic will attract many exciting contributions. We chose this topic because it encompasses the unity of contemporary pluridisciplinary science, in which organic, inorganic, physical and theoretical chemists work together with molecular biologists and physicists to develop a systems-level understanding of molecular interactions. The description of supramolecular chemistry as 'chemistry beyond the molecule' (Jean-Marie Lehn, Nobel Lecture and Gautam R. Desiraju, Nature, 2001, 412, 397) addresses the wide variety of weak, non-covalent interactions that are the basis for the assembly of supramolecular architectures, molecular receptors and molecular recognition, programed molecular systems, dynamic combinatorial libraries, coordination networks and functional supramolecular materials. We welcome submissions from all disciplines involved in this exciting and evolving area of science.

Supramolecular Chemistry

Supramolecular Chemistry
Author: Stefan Kubik
Publisher: Walter de Gruyter GmbH & Co KG
Total Pages: 613
Release: 2020-12-16
Genre: Science
ISBN: 3110595613

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This book is an excellent introduction to supramolecular chemistry, explaining how molecules can be arranged to more complex chemical systems through non-covalent interactions and what makes supramolecular architectures stable. Starting with the principles of molecular recognition and supramolecular receptors, the author further gives an overview of different supramolecular systems and methods for their synthesis.

Supramolecular Nanotechnology

Supramolecular Nanotechnology
Author: Omar Azzaroni
Publisher: John Wiley & Sons
Total Pages: 1801
Release: 2023-04-25
Genre: Technology & Engineering
ISBN: 3527834052

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Supramolecular Nanotechnology Provides up-to-date coverage of both current knowledge and new developments in the dynamic and interdisciplinary field of supramolecular nanotechnology In recent years, supramolecular nanotechnology has revolutionized research in chemistry, physics, and materials science. These easily manipulated molecular units enable the synthesis of novel nanomaterials for use in a wide range of current and potential applications including electronics, sensors, drug delivery, and imaging. Supramolecular Nanotechnology presents a state-of-the-art overview of functional self-assembling nanomaterials based on organic and polymeric molecules. Featuring contributions by an international panel of experts in the field, this comprehensive volume covers the design of self-assembled materials, their synthesis and diverse fabrication methods, the characterization of supramolecular architectures, and current and emerging applications in chemistry, biology, and medicine. Detailed chapters discuss the synthesis of peptide-based supramolecular structures and polymeric self-assembling materials, their characterization, advanced microscopy techniques, nanostructures made of porphyrins, polyelectrolytes, silica, their application in catalysis and cancer, atomistic and coarse-grained simulations, and more. Presents cutting-edge research on rationally designed, self-assembled supramolecular structures Discusses the impact of supramolecular nanotechnology on current and future research and technology Highlights applications of self-assembled supramolecular systems in catalysis, biomedical imaging, cancer therapies, and regenerative medicine Provides synthetic strategies for preparing the molecular assemblies and various characterization techniques for assessing the supramolecular morphology Describes theoretical modeling and simulation techniques for analyzing supramolecular nanostructures Supramolecular Nanotechnology: Advanced Design of Self-Assembled Functional Materials is essential reading for materials scientists and engineers, polymer and organic chemists, pharmaceutical scientists, molecular physicists and biologists, and chemical engineers.

Supramolecular Protein Chemistry

Supramolecular Protein Chemistry
Author: Peter B. Crowley
Publisher: Royal Society of Chemistry
Total Pages: 329
Release: 2020-12-14
Genre: Science
ISBN: 1788017544

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Assembly, Architecture and Application

Porphyrin-based Supramolecular Architectures

Porphyrin-based Supramolecular Architectures
Author: Shengqian Ma
Publisher: Royal Society of Chemistry
Total Pages: 384
Release: 2021-12-03
Genre: Science
ISBN: 1839164948

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Porphyrin-based Supramolecular Architectures focuses on the most recent developments in the field, emphasizing the cutting-edge research in a diverse range of applications. Designed for readers considering the unprecedented prosperity of porous materials research, chapters will cover both strategies for structure design (such as MOFs and COFs) as well as emerging applications including CO2 fixation, catalysis and photodynamic therapy. With contributions from global experts, this title will be of interest to graduate students and researchers in supramolecular chemistry, organic chemistry, inorganic chemistry, physical chemistry, organometallic chemistry, solid-state chemistry, catalysis and (porous) materials science.