Compounds and Alloys Under High Pressure

Compounds and Alloys Under High Pressure
Author: E. Yu Tonkov
Publisher: Taylor & Francis
Total Pages: 585
Release: 2022-11-30
Genre: Technology & Engineering
ISBN: 1351459112

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This is the first book to classify and systematize the available data on the behavior of binary alloys under high pressure. Despite the fact that there is a strong correlation between temperature-composition (T-C) phase diagrams at normal pressure and three- dimensional temperature-composition-pressure (T-C-P) diagrams, many material scientists seldom refer to the (T-C-P) diagrams, just as many high pressure researchers often ignore the data obtained at normal pressure. This book aims to bridge the gap between data obtained at high pressure and that obtained at normal pressure. The most recent research covers not only elements and stoichiometric compounds, but also binary, ternary, and multicomponent alloys, and so this book covers an extended range of substances. The properties of 890 binary systems and a further 1153 pseudobinary and ternary systems are summarized, and accompanied by an extensive bibliography. The data includes information on the solubility of components in solid solutions, melting, and first- and second-order phase transformations in alloys and stoichiometric compounds.

Pressure-Induced Phase Transformations (Volume II)

Pressure-Induced Phase Transformations (Volume II)
Author: Daniel Errandonea
Publisher: Mdpi AG
Total Pages: 0
Release: 2023-08-25
Genre: Science
ISBN: 9783036585642

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The study of phase transitions in materials under high pressure and high temperature is a very active research field. In the last few decades, many important discoveries have been made thanks to the development of experimental techniques and computer simulation methods. Many of these achievements affect various research fields ranging from solid-state physics, chemistry, and materials science to geophysics. They not only involve deepening knowledge on solid-solid phase transitions, but also a better understanding of melting under compression. These modern discoveries, as well as the impact of pressure on structural, chemical, and physical properties, are central to the current Special Issue. Amongst other topics, it places particular emphasis on phase transitions and their effects on different physical properties.

Phase Transitions in Solids Under High Pressure

Phase Transitions in Solids Under High Pressure
Author: Vladimir Davydovich Blank
Publisher: CRC Press
Total Pages: 455
Release: 2013-10-25
Genre: Science
ISBN: 1466594241

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The use of high-pressure techniques has become popular for studying the nature of substances and phenomena occurring in them, especially as a means of obtaining new materials (synthesis under high pressure) and processing known materials (hydroextrusion). A product of many years of research by the authors and their colleagues, Phase Transitions in Solids under High Pressure discusses the relationships of phase transformations in solids under high pressure, the mechanism of these transformations, crystal geometry, the effect of deformation, the conditions of formation, and preservation of the high-pressure phases under normal pressure. The book begins with an introduction that describes the relationship of the thermodynamics of phase transformations and the kinetics of the transformations. This is followed by a chapter explaining the equipment and mostly original procedures for investigating phase transformation in solids under high hydrostatic and quasi-hydrostatic pressures. The book covers phase transformations under high pressure in a wide temperature range in the elements carbon, silicon, germanium, titanium, zirconium, iron, gallium, and cerium as well as in titanium- and iron-based alloys and AIBVII, AIIBVI, and AIIIBV compounds. In addition, the book examines the kinetics of phase transformations in iron-based alloys in isobaric–isothermal conditions. The authors present results for phase transformations in deformation under high pressure, describe several non-trivial effects associated with phase transformations under high pressure, and analyze the kinetics and hysteresis of high-temperature and low-temperature phase transformations. They conclude by describing the role of investigations under high pressure for determining general relationships governing phase transformations in solids.

Phase Transformations of Elements Under High Pressure

Phase Transformations of Elements Under High Pressure
Author: E. Yu Tonkov
Publisher: CRC Press
Total Pages: 390
Release: 2018-10-08
Genre: Science
ISBN: 1420037609

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As laboratories replace heavy hydraulic presses and bulky high-pressure chambers with miniature diamond anvils, traditional heaters with laser heating, and continue to improve methods of shock compression, there has been considerable new data obtained from the high-pressure, high-temperature modification of pure elements. The dense metallic modification of elements shows the potential for achieving superconductivity akin to theoretical predictions. Phase Transformations of Elements Under High Pressure contains the latest theoretical and experimental information on nearly 100 elements, including first-and second-phase transitions, melting lines, crystal structures of stable and metastable phases, stability of polymorphic modifications, and other useful properties and data. It emphasizes features such as changes in the liquid state, amorphization, and metallization, and provides temperature-pressure diagrams for every element. The book also describes the transitions of polymeric forms of fullerene, crystal modifications of elements stable under high pressures, and provides data that confirms their superconducting and magnetic properties. This handbook will be a lasting reference for scientists in a broad range of disciplines, including solid-state physics, chemistry, crystallography, mineralogy, and materials science.

Compounds and Alloys Under High Pressure

Compounds and Alloys Under High Pressure
Author: E.Yu Tonkov
Publisher: Taylor & Francis
Total Pages: 588
Release: 2022
Genre: Technology & Engineering
ISBN: 1351459104

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This is the first book to classify and systematize the available data on the behavior of binary alloys under high pressure. Despite the fact that there is a strong correlation between temperature-composition (T-C) phase diagrams at normal pressure and three- dimensional temperature-composition-pressure (T-C-P) diagrams, many material scientists seldom refer to the (T-C-P) diagrams, just as many high pressure researchers often ignore the data obtained at normal pressure. This book aims to bridge the gap between data obtained at high pressure and that obtained at normal pressure. The most recent research covers not only elements and stoichiometric compounds, but also binary, ternary, and multicomponent alloys, and so this book covers an extended range of substances. The properties of 890 binary systems and a further 1153 pseudobinary and ternary systems are summarized, and accompanied by an extensive bibliography. The data includes information on the solubility of components in solid solutions, melting, and first- and second-order phase transformations in alloys and stoichiometric compounds.

Pressure-Induced Phase Transitions in AB2X4 Chalcogenide Compounds

Pressure-Induced Phase Transitions in AB2X4 Chalcogenide Compounds
Author: Francisco Javier Manjon
Publisher: Springer
Total Pages: 0
Release: 2016-08-23
Genre: Technology & Engineering
ISBN: 9783662521892

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This book on pressure-induced phase transitions in AB2X4 chalcogenide compounds deals with one important AmBnXp material. The interest in these materials is caused by their properties. The results are discussed for three main groups of structural families: cubic-spinel structures, defective tetragonal structures, and other structures like layered and wurtzite-type modifications. A systematic analysis of the behavior of cubic (spinel), tetragonal (defect chalcopyrites and stannites) and other crystal modifications of AB2X4 compounds under hydrostatic pressure is performed. The behavior of AIIAl2S4, AIIGa2S4, AIIAl2Se4 and AIIGa2Se4 compounds with defective tetragonal structures, compounds with layered and wurtzite structures under hydrostatic pressure and the pressure dependence of the band gap, lattice parameters, interatomic distances, vibrational modes and pressure-induced phase transitions is discussed. Many of these compounds, except oxide spinels, undergo a pressure-induced phase transition towards the rocksalt-type structure. The phase transition is preceded by disorder in the cation sublattice. The dependence of the transition pressure to the rocksalt-type structure as a function of the compound ionicity and the size criterion is analyzed. At high pressures, all ordered-vacancy compounds are found to exhibit a band anticrossing between several conduction bands that leads to a strong decrease of its pressure coefficient and consequently to a strong non-linear pressure dependence of the direct bandgap energy. Theoretical studies of phase transitions in several ordered-vacancy compounds reveal that the existence of ordered vacancies alter the cation-anion bond distances and their compressibilities. The book is written for students, Ph D. students and specialists in materials science, phase transitions and new materials.

Phase Transformations

Phase Transformations
Author: Srikumar Banerjee
Publisher: Elsevier
Total Pages: 837
Release: 2010-05-31
Genre: Technology & Engineering
ISBN: 0080548792

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The terms phase transitions and phase transformations are often used in an interchangeable manner in the metallurgical literature. In Phase Transformations, transformations driven by pressure changes, radiation and deformation and those occurring in nanoscale multilayers are brought to the fore. Order-disorder transformations, many of which constitute very good examples of continuous transformations, are dealt with in a comprehensive manner. Almost all types of phase transformations and reactions that are commonly encountered in inorganic materials are covered and the underlying thermodynamic, kinetic and crystallographic aspects elucidated. Shows readers the advancements in the field - due to enhanced computing power and superior experimental capability Drawing upon the background and the research experience of the authors, bringing together a wealth of experience Written essentially from a physical metallurgists view point