Enhanced Heavy Oil Recovery by Hybrid Thermal-chemical Processes

Enhanced Heavy Oil Recovery by Hybrid Thermal-chemical Processes
Author: Moslem Taghavifar
Publisher:
Total Pages: 0
Release: 2014
Genre:
ISBN:

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Developing hybrid processes for heavy oil recovery is a major area of interest in recent years. The need for such processes originates from the challenges of heavy oil recovery relating to fluid injectivity, reservoir heating, and oil displacement and production. These challenges are particularly profound in shaley thin oil deposits where steam injection is not feasible and other recovery methods should be employed. In this work, we aim to develop and optimize a hybrid process that involves moderate reservoir heating and chemical enhanced oil recovery (EOR). This process, in its basic form, is a three-stage scheme. The first stage is a short electrical heating, in which the reservoir temperature is raised just enough to create fluid injectivity. After electrical heating has created sufficient fluid injectivity, high-rate high-pressure hot water injection accelerates the raise in temperature of the reservoir and assists oil production. At the end of hot waterflooding the oil viscosities are low enough for an Alkali-Co-solvent-Polymer (ACP) chemical flood to be performed where oil can efficiently be mobilized and displaced at low pressure gradients. A key aspect of ultra-low IFT chemical flood, such as ACP, is the rheology of the microemulsions that form in the reservoir. Undesirable rheology impedes the displacement of the chemical slug in the reservoir and results in poor process performance or even failure. The viscosity of microemulsions can be altered by the addition of co-solvents and branched or twin-tailed co-surfactants and by an increase in temperature. To reveal the underlying mechanisms, a consistent theoretical framework was developed. Employing the membrane theory and electrostatics, the significance of charge and/or composition heterogeneity in the interface membrane and the relevance of each to the above-mentioned alteration methods was demonstrated. It was observed that branched co-surfactants (in mixed surfactant formulations) and temperature only modify the saddle-splay modulus (k̄) and bending modulus (k) respectively, whereas co-solvent changes both moduli. The observed rheological behavior agrees with our findings. To describe the behavior of microemulsions in flow simulations, a rheological model was developed. A key feature of this model is the treatment of the microemulsion as a bi-network. This provides accuracy and consistency in the calculation of the zero-shear viscosity of a microemulsion regardless of its type and microstructure. Once model parameters are set, the model can be used at any concentration and shear rate. A link between the microemulsion rheological behavior and its microstructure was demonstrated. The bending modulus determines the magnitude of the viscous dissipations and the steady-shear behavior. The new model, additionally, includes components describing the effects of rheology alteration methods. Experimental viscosity data were used to validate the new microemulsion viscosity model. Several ACP corefloods showing the large impact of microemulsion viscosity on process performance were matched using the UTCHEM simulator with the new microemulsion rheology model added to the code. Finally, numerical simulations based on Peace River field data were performed to investigate the performance of the proposed hybrid thermal-chemical process. Key design parameters were identified to be the method of heating, duration of the heating, ACP slug size and composition, polymer drive size, and polymer concentration in the polymer drive. An optimization study was done to demonstrate the economic feasibility of the process. The optimization revealed that short electrical heating and high-rate high-pressure waterflooding are necessary to minimize the energy use and operational expenses. The optimum slug and polymer drive sizes were found to be ~0.25 PV and ~1 PV, respectively. It was shown that the well costs dominate the expenditure and the overall cost of the optimized process is in the range of 20-30 $/bbl of incremental oil production.

Hybrid Enhanced Oil Recovery Processes for Heavy Oil Reservoirs

Hybrid Enhanced Oil Recovery Processes for Heavy Oil Reservoirs
Author: Xiaohu Dong
Publisher: Elsevier
Total Pages: 330
Release: 2021-10-27
Genre: Business & Economics
ISBN: 0128242272

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Hybrid Enhanced Oil Recovery Processes for Heavy Oil Reservoirs, Volume 73 systematically introduces these technologies. As the development of heavy oil reservoirs is emphasized, the petroleum industry is faced with the challenges of selecting cost-effective and environmentally friendly recovery processes. This book tackles these challenges with the introduction and investigation of a variety of hybrid EOR processes. In addition, it addresses the application of these hybrid EOR processes in onshore and offshore heavy oil reservoirs, including theoretical, experimental and simulation approaches. This book will be very useful for petroleum engineers, technicians, academics and students who need to study the hybrid EOR processes, In addition, it will provide an excellent reference for field operations by the petroleum industry. Introduces emerging hybrid EOR processes and their technical details Includes case studies to help readers understand the application potential of hybrid EOR processes from different points-of-view Features theoretical, experimental and simulation studies to help readers understand the advantages and challenges of each process

Thermal Methods

Thermal Methods
Author: Abdolhossein Hemmati-Sarapardeh
Publisher: Gulf Professional Publishing
Total Pages: 462
Release: 2023-04-18
Genre: Science
ISBN: 0128219343

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Thermal Methods, Volume Two, the latest release in the Enhanced Oil Recovery series, helps engineers focus on the latest developments in this fast-growing area. In the book, different techniques are described in addition to the latest technologies in data mining and hybrid processes. Supported field case studies are included to illustrate a bridge between research and practical applications, making it useful for both academics and practicing engineers. Structured to start with thermal concepts and steam flooding, the book's editors then advance to more complex content, guiding engineers into areas such as hybrid thermal methods and edgier technologies that bridge solar and nuclear energy. Supported by a full spectrum of contributors, this book gives petroleum engineers and researchers the latest research developments and field applications to drive innovation for the future of energy. Presents the latest understanding surrounding the updated research and practical applications specific to thermal enhanced oil recovery methods Provides an analysis of editors’ research on available technology, including hybrid thermal-solvent processes and dual pipe configurations Teaches about additional methods, such as data mining applications, and economic and environmental considerations

Hybrid Enhanced Oil Recovery Using Smart Waterflooding

Hybrid Enhanced Oil Recovery Using Smart Waterflooding
Author: Kun Sang Lee
Publisher: Gulf Professional Publishing
Total Pages: 152
Release: 2019-04-03
Genre: Business & Economics
ISBN: 0128172983

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Hybrid Enhanced Oil Recovery Using Smart Waterflooding explains the latest technologies used in the integration of low-salinity and smart waterflooding in other EOR processes to reduce risks attributed to numerous difficulties in existing technologies, also introducing the synergetic effects. Covering both lab and field work and the challenges ahead, the book delivers a cutting-edge product for today’s reservoir engineers. Explains how smart waterflooding is beneficial to each EOR process, such as miscible, chemical and thermal technologies Discusses the mechanics and modeling involved using geochemistry Provides extensive tools, such as reservoir simulations through experiments and field tests, establishing a bridge between theory and practice

Heavy Oil Recovery and Upgrading

Heavy Oil Recovery and Upgrading
Author: James G. Speight
Publisher: Gulf Professional Publishing
Total Pages: 839
Release: 2019-02-28
Genre: Technology & Engineering
ISBN: 0128130261

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Heavy Oil Recovery and Upgrading covers properties, factors, methods and all current and upcoming processes, giving engineers, new and experienced, the full spectrum of recovery choices, including SAGD, horizontal well technology, and hybrid approaches. Moving on to the upgrading and refining of the product, the book also includes information on in situ upgrading, refining options, and hydrogen production. Rounding out with environmental effects, management methods on refinery waste, and the possible future configurations within the refinery, this book provides engineers with a single source to make decisions and manage the full range of challenges. Presents the properties, mechanisms, screening criteria and field applications for heavy oil enhanced recovery projects Includes current upgrading options and future methods for refining heavy oil development Fills in the gaps between literature and practical application for everyday industry reference

Chemical Enhanced Oil Recovery

Chemical Enhanced Oil Recovery
Author: Patrizio Raffa
Publisher: Walter de Gruyter GmbH & Co KG
Total Pages: 277
Release: 2019-07-22
Genre: Technology & Engineering
ISBN: 3110640430

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This book aims at presenting, describing, and summarizing the latest advances in polymer flooding regarding the chemical synthesis of the EOR agents and the numerical simulation of compositional models in porous media, including a description of the possible applications of nanotechnology acting as a booster of traditional chemical EOR processes. A large part of the world economy depends nowadays on non-renewable energy sources, most of them of fossil origin. Though the search for and the development of newer, greener, and more sustainable sources have been going on for the last decades, humanity is still fossil-fuel dependent. Primary and secondary oil recovery techniques merely produce up to a half of the Original Oil In Place. Enhanced Oil Recovery (EOR) processes are aimed at further increasing this value. Among these, chemical EOR techniques (including polymer flooding) present a great potential in low- and medium-viscosity oilfields. • Describes recent advances in chemical enhanced oil recovery. • Contains detailed description of polymer flooding and nanotechnology as promising boosting tools for EOR. • Includes both experimental and theoretical studies. About the Authors Patrizio Raffa is Assistant Professor at the University of Groningen. He focuses on design and synthesis of new polymeric materials optimized for industrial applications such as EOR, coatings and smart materials. He (co)authored about 40 articles in peer reviewed journals. Pablo Druetta works as lecturer at the University of Groningen (RUG) and as engineering consultant. He received his Ph.D. from RUG in 2018 and has been teaching at a graduate level for 15 years. His research focus lies on computational fluid dynamics (CFD).

Efficient Simulation of Thermal Enhanced Oil Recovery Processes

Efficient Simulation of Thermal Enhanced Oil Recovery Processes
Author: Zhouyuan Zhu
Publisher: Stanford University
Total Pages: 237
Release: 2011
Genre:
ISBN:

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Simulating thermal processes is usually computationally expensive because of the complexity of the problem and strong nonlinearities encountered. In this work, we explore novel and efficient simulation techniques to solve thermal enhanced oil recovery problems. We focus on two major topics: the extension of streamline simulation for thermal enhanced oil recovery and the efficient simulation of chemical reaction kinetics as applied to the in-situ combustion process. For thermal streamline simulation, we first study the extension to hot water flood processes, in which we have temperature induced viscosity changes and thermal volume changes. We first compute the pressure field on an Eulerian grid. We then solve for the advective parts of the mass balance and energy equations along the individual streamlines, accounting for the compressibility effects. At the end of each global time step, we account for the nonadvective terms on the Eulerian grid along with gravity using operator splitting. We test our streamline simulator and compare the results with a commercial thermal simulator. Sensitivity studies for compressibility, gravity and thermal conduction effects are presented. We further extended our thermal streamline simulation to steam flooding. Steam flooding exhibits large volume changes and compressibility associated with the phase behavior of steam, strong gravity segregation and override, and highly coupled energy and mass transport. To overcome these challenges we implement a novel pressure update along the streamlines, a Glowinski scheme operator splitting and a preliminary streamline/finite volume hybrid approach. We tested our streamline simulator on a series of test cases. We compared our thermal streamline results with those computed by a commercial thermal simulator for both accuracy and efficiency. For the cases investigated, we are able to retain solution accuracy, while reducing computational cost and gaining connectivity information from the streamlines. These aspects are useful for reservoir engineering purposes. In traditional thermal reactive reservoir simulation, mass and energy balance equations are solved numerically on discretized reservoir grid blocks. The reaction terms are calculated through Arrhenius kinetics using cell-averaged properties, such as averaged temperature and reactant concentrations. For the in-situ combustion process, the chemical reaction front is physically very narrow, typically a few inches thick. To capture accurately this front, centimeter-sized grids are required that are orders of magnitude smaller than the affordable grid block sizes for full field reservoir models. To solve this grid size effect problem, we propose a new method based on a non-Arrhenius reaction upscaling approach. We do not resolve the combustion front on the grid, but instead use a subgrid-scale model that captures the overall effects of the combustion reactions on flow and transport, i.e. the amount of heat released, the amount of oil burned and the reaction products generated. The subgrid-scale model is calibrated using fine-scale highly accurate numerical simulation and laboratory experiments. This approach significantly improves the computational speed of in-situ combustion simulation as compared to traditional methods. We propose the detailed procedures to implement this methodology in a field-scale simulator. Test cases illustrate the solution consistency when scaling up the grid sizes in multidimensional heterogeneous problems. The methodology is also applicable to other subsurface reactive flow modeling problems with fast chemical reactions and sharp fronts. Displacement front stability is a major concern in the design of all the enhanced oil recovery processes. Historically, premature combustion front break through has been an issue for field operations of in-situ combustion. In this work, we perform detailed analysis based on both analytical methods and numerical simulation. We identify the different flow regimes and several driving fronts in a typical 1D ISC process. For the ISC process in a conventional mobile heavy oil reservoir, we identify the most critical front as the front of steam plateau driving the cold oil bank. We discuss the five main contributors for this front stability/instability: viscous force, condensation, heat conduction, coke plugging and gravity. Detailed numerical tests are performed to test and rank the relative importance of all these different effects.

Advancements in Chemical Enhanced Oil Recovery

Advancements in Chemical Enhanced Oil Recovery
Author: Tushar Sharma
Publisher: CRC Press
Total Pages: 404
Release: 2024-09-06
Genre: Technology & Engineering
ISBN: 1000986675

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This comprehensive book presents the latest advances in chemical EOR, considered to be an efficient technique to recover bypassed oil and residual oil trapped in reservoirs. The volume first provides an introduction to chemical EOR and discusses its viability. From there, it delves in the various EOR methods, including low-salinity water flooding, polymer and surfactant flooding, foam flooding, nanofluid flooding, hybrid methods, ionic liquid applications, and others. The book covers chemical synthesis of EOR agents and numerical simulation of compositional models in porous media, including a description of possible application of nanotechnology acting as a booster of traditional chemical EOR processes.

Fundamentals of Enhanced Oil and Gas Recovery from Conventional and Unconventional Reservoirs

Fundamentals of Enhanced Oil and Gas Recovery from Conventional and Unconventional Reservoirs
Author: Alireza Bahadori
Publisher: Gulf Professional Publishing
Total Pages: 536
Release: 2018-08-18
Genre: Technology & Engineering
ISBN: 0128130288

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Fundamentals of Enhanced Oil and Gas Recovery from Conventional and Unconventional Reservoirs delivers the proper foundation on all types of currently utilized and upcoming enhanced oil recovery, including methods used in emerging unconventional reservoirs. Going beyond traditional secondary methods, this reference includes advanced water-based EOR methods which are becoming more popular due to CO2 injection methods used in EOR and methods specific to target shale oil and gas activity. Rounding out with a chapter devoted to optimizing the application and economy of EOR methods, the book brings reservoir and petroleum engineers up-to-speed on the latest studies to apply. Enhanced oil recovery continues to grow in technology, and with ongoing unconventional reservoir activity underway, enhanced oil recovery methods of many kinds will continue to gain in studies and scientific advancements. Reservoir engineers currently have multiple outlets to gain knowledge and are in need of one product go-to reference. Explains enhanced oil recovery methods, focusing specifically on those used for unconventional reservoirs Includes real-world case studies and examples to further illustrate points Creates a practical and theoretical foundation with multiple contributors from various backgrounds Includes a full range of the latest and future methods for enhanced oil recovery, including chemical, waterflooding, CO2 injection and thermal

Enhanced Oil Recovery of Heavy Oils by Non-thermal Chemical Methods

Enhanced Oil Recovery of Heavy Oils by Non-thermal Chemical Methods
Author: Rahul Kumar
Publisher:
Total Pages: 358
Release: 2013
Genre:
ISBN:

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It is estimated that the shallow reservoirs of Ugnu, West Sak and Shraeder Bluff in the North Slope of Alaska hold about 20 billion barrels of heavy oil. The proximity of these reservoirs to the permafrost makes the application of thermal methods for the oil recovery very unattractive. It is feared that the heat from the thermal methods may melt this permafrost leading to subsidence of the unconsolidated sand (Marques 2009; Peyton 1970; Wilson 1972). Thus it is necessary to consider the development of cheap non-thermal methods for the recovery of these heavy oils. This study investigates non-thermal techniques for the recovery of heavy oils. Chemicals such as alkali, surfactant and polymer are used to demonstrate improved recovery over waterflooding for two oils (A:10,000cp and B:330 cp). Chemical screening studies showed that appropriate concentrations of chemicals, such as alkali and surfactant, could generate emulsions with oil A. At low brine salinity oil-in-water (O/W) emulsions were generated whereas water-in-oil (W/O) emulsions were generated at higher salinities. 1D and 2D sand pack floods conducted with alkali surfactant (AS) at different salinities demonstrated an improvement of oil recovery over waterflooding. Low salinity AS flood generated lower pressure drop, but also resulted in lower oil recovery rates. High salinity AS flood generated higher pressure drop, high viscosity emulsions in the system, but resulted in a greater improvement in oil recovery over waterfloods. Polymers can also be used to improve the sweep efficiency over waterflooding. A 100 cp polymer flood improved the oil recovery over waterflood both in 1D and 2D geometry. In 1D geometry 1PV of polymer injection increased the oil recovery from 30% after waterflood to 50% OOIP. The tertiary polymer injection was found to be equally beneficial as the secondary polymer injection. It was also found that the combined application of AS and polymer did not give any major advantage over polymer flood or AS flood alone. Chemical EOR technique was considered for the 330cp oil B. Chemical screening studies showed that microemulsions could be generated in the system when appropriate concentrations of alkali and surfactant were added. Solubilization ratio measurement indicted that the interfacial tension in the system approached ultra-low values of about 10-3 dynes/cm. The selected alkali surfactant system was tested in a sand pack flood. Additionally a partially hydrolyzed polymer was used to provide mobility control to the process. The tertiary injection of ASP (Alkali-Surfactant-Polymer) was able to improve the oil recovery from 60% OOIP after the waterflood to almost 98% OOIP. A simple mathematical model was built around viscous fingering phenomenon to match the experimental oil recoveries and pressure drops during the waterflood. Pseudo oil and water relative permeabilities were calculated from the model, which were then used directly in a reservoir simulator in place of the intrinsic oil-water relative permeabilities. Good agreement with the experimental values was obtained. For history matching the polymer flood of heavy oil, intrinsic oil-water relative permeabilities were found to be adequate. Laboratory data showed that polymer viscosity is dependent on the polymer concentration and the effective brine salinity. Both these effects were taken into account when simulating the polymer flood or the ASP flood. The filtration theory developed by Soo and Radke (1984) was used to simulate the dilute oil-in-water emulsion flow in the porous media when alkali-surfactant flood of the heavy oil was conducted. The generation of emulsion in the porous media is simulated via a reaction between alkali, surfactant, water and heavy oil. The theory developed by Soo and Radke (1984) states that the flowing emulsified oil droplets clog in pore constrictions and on the pore walls, thereby restricting flow. Once captured, there is a negligible particle re-entrainment. The simulator modeled the capture of the emulsion droplets via chemical reaction. Next, the local water relative permeability was reduced as the trapping of the oil droplets will reduce the mobility of the water phase. This entrapment mechanism is responsible for the increase in the pressure drop and improvement in oil recovery. The model is very sensitive to the reaction rate constants and the oil-water relative permeabilities. ASP process for lower viscosity 330 cp oil was modeled using the UTCHEM multiphase-multicomponent simulator developed at the University of Texas at Austin. The simulator can handle the flow of three liquid phases; oil, water and microemulsion. The generation of microemulsion is modeled by the reaction of the crude oil with the chemical species present in the aqueous phase. The experimental phase behavior of alkali and surfactant with the crude oil was modeled using the phase behavior mixing model of the simulator. Oil and water relative permeabilities were enhanced where microemulsion is generated and interfacial tension gets reduced. Experimental oil recovery and pressure drop data were successfully history matched using UTCHEM simulator.