Electrochemical Impedance Spectroscopy in PEM Fuel Cells

Electrochemical Impedance Spectroscopy in PEM Fuel Cells
Author: Xiao-Zi (Riny) Yuan
Publisher: Springer Science & Business Media
Total Pages: 428
Release: 2009-11-25
Genre: Science
ISBN: 1848828462

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"Electrochemical Impedance Spectroscopy in PEM Fuel Cells" discusses one of the most powerful and useful diagnostic tools for various aspects of the study of fuel cells: electrochemical impedance spectroscopy (EIS). This comprehensive reference on EIS fundamentals and applications in fuel cells contains information about basic principles, measurements, and fuel cell applications of the EIS technique. Many illustrated examples are provided to ensure maximum clarity and observability of the spectra. "Electrochemical Impedance Spectroscopy in PEM Fuel Cells" will enable readers to explore the frontiers of EIS technology in PEM fuel cell research and other electrochemical systems. As well as being a useful text for electrochemists, it can also help researchers who are unfamiliar with EIS to learn the technique quickly and to use it correctly in their fuel cell research. Managers or entrepreneurs may also find this book a useful guide to accessing the challenges and opportunities in fuel cell technology.

PEM Fuel Cell Testing and Diagnosis

PEM Fuel Cell Testing and Diagnosis
Author: Jiujun Zhang
Publisher: Newnes
Total Pages: 391
Release: 2013-01-22
Genre: Technology & Engineering
ISBN: 0444536892

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PEM Fuel Cell Testing and Diagnosis covers the recent advances in PEM (proton exchange membrane) fuel cell systems, focusing on instruments and techniques for testing and diagnosis, and the application of diagnostic techniques in practical tests and operation. This book is a unique source of electrochemical techniques for researchers, scientists and engineers working in the area of fuel cells. Proton exchange membrane fuel cells are currently considered the most promising clean energy-converting devices for stationary, transportation, and micro-power applications due to their high energy density, high efficiency, and environmental friendliness. To advance research and development of this emerging technology, testing and diagnosis are an essential combined step. This book aids those efforts, addressing effects of humidity, temperature and pressure on fuel cells, degradation and failure analysis, and design and assembly of MEAs, single cells and stacks. Provides fundamental and theoretical principles for PEM fuel cell testing and diagnosis. Comprehensive source for selecting techniques, experimental designs and data analysis Analyzes PEM fuel cell degradation and failure mechanisms, and suggests failure mitigation strategies Provides principles for selecting PEM fuel cell key materials to improve durability

Electrochemical Impedance Spectroscopy

Electrochemical Impedance Spectroscopy
Author: Mark E. Orazem
Publisher: John Wiley & Sons
Total Pages: 510
Release: 2011-10-13
Genre: Science
ISBN: 111820994X

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Using electrochemical impedance spectroscopy in a broad range of applications This book provides the background and training suitable for application of impedance spectroscopy to varied applications, such as corrosion, biomedical devices, semiconductors and solid-state devices, sensors, batteries, fuel cells, electrochemical capacitors, dielectric measurements, coatings, electrochromic materials, analytical chemistry, and imaging. The emphasis is on generally applicable fundamentals rather than on detailed treatment of applications. With numerous illustrative examples showing how these principles are applied to common impedance problems, Electrochemical Impedance Spectroscopy is ideal either for course study or for independent self-study, covering: Essential background, including complex variables, differential equations, statistics, electrical circuits, electrochemistry, and instrumentation Experimental techniques, including methods used to measure impedance and other transfer functions Process models, demonstrating how deterministic models of impedance response can be developed from physical and kinetic descriptions Interpretation strategies, describing methods of interpretating of impedance data, ranging from graphical methods to complex nonlinear regression Error structure, providing a conceptual understanding of stochastic, bias, and fitting errors in frequency-domain measurements An overview that provides a philosophy for electrochemical impedance spectroscopy that integrates experimental observation, model development, and error analysis This is an excellent textbook for graduate students in electrochemistry, materials science, and chemical engineering. It's also a great self-study guide and reference for scientists and engineers who work with electrochemistry, corrosion, and electrochemical technology, including those in the biomedical field, and for users and vendors of impedance-measuring instrumentation.

Electrical Systems 2

Electrical Systems 2
Author: Abdenour Soualhi
Publisher: John Wiley & Sons
Total Pages: 188
Release: 2020-04-14
Genre: Technology & Engineering
ISBN: 1119720575

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Methods of diagnosis and prognosis play a key role in the reliability and safety of industrial systems. Failure diagnosis requires the use of suitable sensors, which provide signals that are processed to monitor features (health indicators) for defects. These features are required to distinguish between operating states, in order to inform the operator of the severity level, or even the type, of a failure. Prognosis is defined as the estimation of a systems lifespan, including how long remains and how long has passed. It also encompasses the prediction of impending failures. This is a challenge that many researchers are currently trying to address. Electrical Systems, a book in two volumes, informs readers of the theoretical solutions to this problem, and the results obtained in several laboratories in France, Spain and further afield. To this end, many researchers from the scientific community have contributed to this book to share their research results.

Polymer Electrolyte Fuel Cells

Polymer Electrolyte Fuel Cells
Author: Michael Eikerling
Publisher: CRC Press
Total Pages: 567
Release: 2014-09-23
Genre: Science
ISBN: 1439854068

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The book provides a systematic and profound account of scientific challenges in fuel cell research. The introductory chapters bring readers up to date on the urgency and implications of the global energy challenge, the prospects of electrochemical energy conversion technologies, and the thermodynamic and electrochemical principles underlying the op

High Temperature Polymer Electrolyte Membrane Fuel Cells

High Temperature Polymer Electrolyte Membrane Fuel Cells
Author: Qingfeng Li
Publisher: Springer
Total Pages: 545
Release: 2015-10-15
Genre: Technology & Engineering
ISBN: 3319170821

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This book is a comprehensive review of high-temperature polymer electrolyte membrane fuel cells (PEMFCs). PEMFCs are the preferred fuel cells for a variety of applications such as automobiles, cogeneration of heat and power units, emergency power and portable electronics. The first 5 chapters of the book describe rationalization and illustration of approaches to high temperature PEM systems. Chapters 6 - 13 are devoted to fabrication, optimization and characterization of phosphoric acid-doped polybenzimidazole membranes, the very first electrolyte system that has demonstrated the concept of and motivated extensive research activity in the field. The last 11 chapters summarize the state-of-the-art of technological development of high temperature-PEMFCs based on acid doped PBI membranes including catalysts, electrodes, MEAs, bipolar plates, modelling, stacking, diagnostics and applications.

Polymer Electrolyte Fuel Cell Degradation

Polymer Electrolyte Fuel Cell Degradation
Author: Matthew M. Mench
Publisher: Academic Press
Total Pages: 474
Release: 2012
Genre: Technology & Engineering
ISBN: 0123869366

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For full market implementation of PEM fuel cells to become a reality, two main limiting technical issues must be overcome- cost and durability. This cutting-edge volume directly addresses the state-of-the-art advances in durability within every fuel cell stack component. [...] chapters on durability in the individual fuel cell components -- membranes, electrodes, diffusion media, and bipolar plates -- highlight specific degradation modes and mitigation strategies. The book also includes chapters which synthesize the component-related failure modes to examine experimental diagnostics, computational modeling, and laboratory protocol"--Back cover.

Electrochemical Impedance Spectroscopy and its Applications

Electrochemical Impedance Spectroscopy and its Applications
Author: Andrzej Lasia
Publisher: Springer
Total Pages: 376
Release: 2014-06-17
Genre: Science
ISBN: 1461489334

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This book presents a complete overview of the powerful but often misused technique of Electrochemical Impedance Spectroscopy (EIS). The book presents a systematic and complete overview of EIS. The book carefully describes EIS and its application in studies of electrocatalytic reactions and other electrochemical processes of practical interest. This book is directed towards graduate students and researchers in Electrochemistry. Concepts are illustrated through detailed graphics and numerous examples. The book also includes practice problems. Additional materials and solutions are available online.

Electrochemical Phenomena in the Cathode Impedance Spectrum of PEM Fuel Cells

Electrochemical Phenomena in the Cathode Impedance Spectrum of PEM Fuel Cells
Author: Samuel Cruz-Manzo
Publisher: Elsevier
Total Pages: 388
Release: 2022-06-18
Genre: Technology & Engineering
ISBN: 0323914322

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Electrochemical Phenomena in the Cathode Impedance Spectrum of PEM Fuel Cells: Fundamentals, Modelling, and Applications establishes how the electrochemical and diffusion mechanisms of a polymer electrolyte membrane fuel cell (PEMFC) are related to electrochemical impedance spectroscopy (EIS) measurements using physics-based impedance models derived from fundamental electrode and diffusion theories. The contribution of the different phenomena occurring at the different layers comprising the cathode on the impedance response of the PEMFC is revealed through EIS-modelling analysis. The relation between EIS measurements and polarisation curves representing the performance of PEMFCs is established. Insight is gained into how the EIS response of the PEMFC changes at different operating conditions e.g. relative humidity, load demand, gas reactant stoichiometry and temperature using physics-based impedance models. The application of impedance models with EIS measurements carried out in the individual cells comprising a PEMFC stack is demonstrated, while recent modelling approaches and other impedance models reported in the literature to represent the EIS response of the PEMFC are also considered and discussed. Provides further understanding of ambiguities during the interpretation of the electrochemical impedance spectrum of the PEMFC Includes impedance models written in MATLAB® for replication or application to other PEMFC-EIS measurements Includes impedance spectra of the PEMFC at different operating conditions, electro/diffusion pathways for derivation of the impedance models and flowcharts for application of the impedance models with real-world measured EIS data

Fast Electrochemical Impedance Spectroscopy

Fast Electrochemical Impedance Spectroscopy
Author: Pavle Boškoski
Publisher: Springer
Total Pages: 83
Release: 2017-05-07
Genre: Technology & Engineering
ISBN: 3319533908

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This book offers a review of electrochemical impedance spectroscopy (EIS) and its application in online condition monitoring of electrochemical devices, focusing on the practicalities of performing fast and accurate EIS. The first part of the book addresses the theoretical aspects of the fast EIS technique, including stochastic excitation signals, time-frequency signal processing, and statistical analysis of impedance measurements. The second part presents an application of the fast EIS technique for condition monitoring and evaluates the performance of the proposed fast EIS methodology in three different types of electrochemical devices: a Li-ion battery, a Li-S cell, and a polymer electrolyte membrane (PEM) fuel cell. Uniquely, in addition to theoretical aspects the book provides practical guidelines for implementation, commissioning, and exploitation of EIS for condition monitoring of electrochemical devices, making it a valuable resource for practicing engineers as well as researchers.