CW EC-QCL-based Sensor for Simultaneous Detection of H2O, HDO, N2O and CH4 Using Multi-pass Absorption Spectroscopy

CW EC-QCL-based Sensor for Simultaneous Detection of H2O, HDO, N2O and CH4 Using Multi-pass Absorption Spectroscopy
Author:
Publisher:
Total Pages: 11
Release: 2016
Genre:
ISBN:

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A sensor system based on a continuous wave, external-cavity quantum-cascade laser (CW EC-QCL) was demonstrated for simultaneous detection of atmospheric H2O, HDO, N2O and CH4 using a compact, dense pattern multi-pass gas cell with an effective path-length of 57.6 m. The EC-QCL with a mode-hop-free spectral range of 1225-1285 cm-1 operating at similar to 7.8 mu m was scanned covering four neighboring absorption lines, for H2O at 1281.161 cm-1, HDO at 1281.455 cm-1, N2O at 1281.53 cm-1 and CH4 at 1281.61 cm-1. A first-harmonic-normalized wavelength modulation spectroscopy with second-harmonic detection (WMS-2f/1f) strategy was employed for data processing. An Allan-Werle deviation analysis indicated that minimum detection limits of 1.77 ppmv for H2O, 3.92 ppbv for HDO, 1.43 ppbv for N2O, and 2.2 ppbv for CH4 were achieved with integration times of 50-s, 50-s, 100-s and 129-s, respectively. In conclusion, experimental measurements of ambient air are also reported.

State-of-the-art Laser Gas Sensing Technologies

State-of-the-art Laser Gas Sensing Technologies
Author: Yufei Ma
Publisher: MDPI
Total Pages: 278
Release: 2020-03-05
Genre: Technology & Engineering
ISBN: 3039283987

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Trace gas sensing technologies are widely used in many applications, such as environmental monitoring, life science, medical diagnostics, and planetary exploration. On the one hand, laser sources have developed greatly due to the rapid development of laser media and laser techniques in recent years. Some novel lasers such as solid-state, diode, and quantum cascade lasers have experienced significant progress. At present, laser wavelengths can cover the range from ultraviolet to terahertz, which could promote the development of laser gas sensing technologies significantly. On the other hand, some new gas sensing methods have appeared, such as photothermal spectroscopy and photoacoustic spectroscopy. Laser spectroscopy-based gas sensing techniques have the advantages of high sensitivity, non-invasiveness, and allowing in situ, real-time observation. Due to the rapid and recent developments in laser source as well as the great merits of laser spectroscopy-based gas sensing techniques, this book aims to provide an updated overview of the state-of-the-art laser gas sensing technologies.

Optical Sensing in Power Transformers

Optical Sensing in Power Transformers
Author: Jun Jiang
Publisher: John Wiley & Sons
Total Pages: 256
Release: 2020-12-14
Genre: Technology & Engineering
ISBN: 1119765285

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A cutting-edge, advanced level, exploration of optical sensing application in power transformers Optical Sensing in Power Transformers is filled with the critical information and knowledge on the optical techniques applied in power transformers, which are important and expensive components in the electric power system. Effective monitoring of systems has proven to decrease the transformer lifecycle cost and increase a high level of availability and reliability. It is commonly held that optical sensing techniques will play an increasingly significant role in online monitoring of power transformers. In this comprehensive text, the authors—noted experts on the topic—present a scholarly review of the various cutting-edge optical principles and methodologies adopted for online monitoring of power transformers. Grounded in the authors' extensive research, the book examines optical techniques and high-voltage equipment testing and provides the foundation for further application, prototype, and manufacturing. The book explores the principles, installation, operation, condition detection, monitoring, and fault diagnosis of power transformers. This important text: Provides a current exploration of optical sensing application in power transformers Examines the critical balance and pros and cons of cost and quality of various optical condition monitoring techniques Presents a wide selection of techniques with appropriate technical background Extends the vision of condition monitoring testing and analysis Treats condition monitoring testing and analysis tools together in a coherent framework Written for researchers, technical research and development personnel, manufacturers, and frontline engineers, Optical Sensing in Power Transformers offers an up-to-date review of the most recent developments of optical sensing application in power transformers.

Modern Techniques of Spectroscopy

Modern Techniques of Spectroscopy
Author: Dheeraj Kumar Singh
Publisher: Springer Nature
Total Pages: 663
Release: 2021-04-01
Genre: Technology & Engineering
ISBN: 9813360844

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The book highlights recent developments in the field of spectroscopy by providing the readers with an updated and high-level of overview. The focus of this book is on the introduction to concepts of modern spectroscopic techniques, recent technological innovations in this field, and current examples of applications to molecules and materials relevant for academia and industry. The book will be beneficial to researchers from various branches of science and technology, and is intended to point them to modern techniques, which might be useful for their specific problems. Spectroscopic techniques, that are discussed include, UV-Visible absorption spectroscopy, XPS, Raman spectroscopy, SERS, TERS, CARS, IR absorption spectroscopy, SFG, LIBS, Quantum cascade laser (QCL) spectroscopy, fluorescence spectroscopy, ellipsometry, cavity-enhanced absorption spectroscopy, such as cavity ring-down spectroscopy (CRDS) and evanescent wave-CRDS both in gas and condensed phases, time-resolved spectroscopy etc. Applications introduced in the different chapters demonstrates the usefulness of the spectroscopic techniques for the characterization of fundamental properties of molecules, e.g. in connection with environmental impact, bio-activity, or usefulness for pharmaceutical drugs, and materials important e.g. for nano-science, nuclear chemistry, or bio-applications. The book presents how spectroscopic techniques can help to better understand substances, which have also great impact on questions of social and economic relevance (environment, alternative energy, etc.).

Cavity-Enhanced Spectroscopy and Sensing

Cavity-Enhanced Spectroscopy and Sensing
Author: Gianluca Gagliardi
Publisher: Springer
Total Pages: 537
Release: 2013-10-19
Genre: Science
ISBN: 3642400035

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The book reviews the dramatic recent advances in the use of optical resonators for high sensitivity and high resolution molecular spectroscopy as well as for chemical, mechanical and physical sensing. It encompasses a variety of cavities including those made of two or more mirrors, optical fiber loops, fiber gratings and spherical cavities. The book focuses on novel techniques and their applications. Each chapter is written by an expert and/or pioneer in the field. These experts also provide the theoretical background in optics and molecular physics where needed. Examples of recent breakthroughs include the use of frequency combs (Nobel prize 2005) for cavity enhanced sensing and spectroscopy, the use of novel cavity materials and geometries, the development of optical heterodyne detection techniques combined to active frequency-locking schemes. These methods allow the use and interrogation of optical resonators with a variety of coherent light sources for trace gas detection and sensing of strain, temperature and pressure.

Methods for Measuring Greenhouse Gas Balances and Evaluating Mitigation Options in Smallholder Agriculture

Methods for Measuring Greenhouse Gas Balances and Evaluating Mitigation Options in Smallholder Agriculture
Author: Todd S. Rosenstock
Publisher: Springer
Total Pages: 217
Release: 2016-08-23
Genre: Technology & Engineering
ISBN: 3319297945

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​​This book provides standards and guidelines for quantifying greenhouse gas emissions and removals in smallholder agricultural systems and comparing options for climate change mitigation based on emission reductions and livelihood trade-offs. Globally, agriculture is directly responsible for about 11% of annual greenhouse gas (GHG) emissions and induces an additional 17% through land use change, mostly in developing countries. Farms in the developing countries of sub-Saharan Africa and Asia are predominately managed by smallholders, with 80% of land holdings smaller than ten hectares. However, little to no information exists on greenhouse gas emissions and mitigation potentials in smallholder agriculture. Greenhouse gas measurements in agriculture are expensive, time consuming, and error prone, challenges only exacerbated by the heterogeneity of smallholder systems and landscapes. Concerns over methodological rigor, measurement costs, and the diversity of approaches, coupled with the demand for robust information suggest it is germane for the scientific community to establish standards of measurements for quantifying GHG emissions from smallholder agriculture. Standard guidelines for use by scientists, development organizations will help generate reliable data on emissions baselines and allow rigorous comparisons of mitigation options. The guidelines described in this book, developed by the CGIAR Research Program on Climate Change, Agriculture, and Food Security (CCAFS) and partners, are intended to inform anyone conducting field measurements of agricultural greenhouse gas sources and sinks, especially to develop IPCC Tier 2 emission factors or to compare mitigation options in smallholder systems.

Cavity Ring-Down Spectroscopy

Cavity Ring-Down Spectroscopy
Author: Giel Berden
Publisher: John Wiley & Sons
Total Pages: 344
Release: 2009-08-11
Genre: Science
ISBN: 9781444308242

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Cavity Ring-Down Spectroscopy: Techniques and Applications provides a practical overview of this valuable analytical tool, explaining the fundamental concepts and experimental methods, and illustrating important applications. Designed as both an introductory text and a reference source, this book is relevant for scientists unfamiliar with CRDS who are interested in using the technique in their research, as well as experienced users.

Tunable Lasers Handbook

Tunable Lasers Handbook
Author: Frank J. Duarte
Publisher: Elsevier
Total Pages: 493
Release: 1996-01-08
Genre: Science
ISBN: 0080519768

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Many laser applications depend on the ability of a particular laser to be frequency tunable. Among the many different types of frequency tunable lasers are: dye lasers, excimer lasers, and semiconductor lasers. Thisbook gives active researchers and engineers the practical information they need to choose an appropriate tunable laser for their particular applications. Presents a unified and integrated perspective on tunable lasers Includes sources spanning the electromagnetic spectrum from the UV to the FIR Contains 182 figures and 68 tables Provides coverage of optical parametric oscillators and tunable gas, liquid, solid state, and semiconductor lasers

Mid-Infrared Coherent Sources and Applications

Mid-Infrared Coherent Sources and Applications
Author: Majid Ebrahim-Zadeh
Publisher: Springer Science & Business Media
Total Pages: 630
Release: 2008-01-02
Genre: Science
ISBN: 140206439X

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Covering fundamental principles and the state of the art, this is a collection of reviews from experts in mid-infrared (mid-IR) coherent sources. Among the sources covered are optical parametric oscillators, difference frequency generators, and the most recent broadband crystalline, quantum cascade, and fiber lasers. The authors show how advances in mid-IR science and technology make these sources indispensable for a variety of applications.

Advances in Spectroscopy: Molecules to Materials

Advances in Spectroscopy: Molecules to Materials
Author: Dheeraj Kumar Singh
Publisher: Springer
Total Pages: 454
Release: 2020-10-26
Genre: Science
ISBN: 9789811502040

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This book presents and discusses recent developments in the broad field of spectroscopy, providing the reader with an updated overview. The main objective is to introduce them to recent innovations and current trends in spectroscopy applied to molecules and materials. The book also brings together experimentalists and theoreticians to highlight the multidimensional aspects of spectroscopy and discuss the latest issues. Accordingly, it provides insights not only into the general goals of spectroscopy, but also into how the various spectroscopic techniques represent a toolbox that can be used to gain a more detailed understanding of molecular systems and complex chemical problems. Besides technical aspects, basic theoretical interpretations of spectroscopic results are also presented. The spectroscopy techniques discussed include UV-visible absorption spectroscopy, Raman spectroscopy, IR absorption spectroscopy, fluorescence spectroscopy, and time-resolved spectroscopy. In turn, basic tools like lasers and theoretical modeling approaches are also presented. Lastly, applications for the characterization of fundamental properties of molecules (environmental aspects, biomolecules, pharmaceutical drugs, hazardous molecules, etc.) and materials (nanomaterials, nuclear chemistry materials, biomaterials, etc.) are discussed. Given its scope, the book offers a valuable resource for researchers from various branches of science, and presents new techniques that can be applied to their specific problems.