Mixed Ligand Complex of Copper (II) Containing O-N Donor Ligands

Mixed Ligand Complex of Copper (II) Containing O-N Donor Ligands
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In chemistry, a complex, also called a "coordination compound" or "metal complex", is a structure consisting of a central atom or molecule connected to surrounding atoms or molecules. Originally, a complex implied a reversible association of molecules, atoms, or ions through weak chemical bonds. As applied to coordination chemistry, this meaning has evolved. Some metal complexes are formed virtually irreversibly and many are bound together by bonds that are quite strong. Copper is a transition metal, which in the zero oxidation state has an electron configuration of [Ar]4s24p63d9. Copper is found in three different oxidation states: Cu(I), Cu(II), and Cu(III). Copper (I) atoms have 10 d electrons. Cu(I) complexes being d10 have no Jahn-Teller distortion. Cu (I) complexes are diamagnetic and typically colorless. If a Cu(I) complex is colored, the color is a result of a charge transfer band or an internal transition in a ligand. In the copper(II) oxidation state, the metal has 9 d electrons. Jahn- Teller distortion causes a splitting of eg and t2g orbitals. Most Cu(II) complexes are square planar for this reason. Usually observed in the electronic spectra of Cu(II) complexes is a single broad, poorly resolved band envelope. This envelope is typical of Cu(II) complexes in tetragonal complexes. These complexes are generally blue or green because of an absorption band in the 600-900 nm region of the spectrum. Reproducing complex biological reactivity within a simple synthetic molecule is a challenging endeavor with both intellectual and aesthetic goals. The sequence of examining biological reactivity, creating similar chemical architectures, and determining functional reaction conditions for model systems is a process that allows the biological code of reactivity to be deciphered. In the past years the report on the crystal structures of type 3 copper enzymes (e.g. catechol oxidase, hemocyanins, and tyrosinase), as too type 2 - type 3 copper enzymes (e.g. ascorbate oxida.

Comprehensive Coordination Chemistry II

Comprehensive Coordination Chemistry II
Author: J. A. McCleverty
Publisher: Newnes
Total Pages: 11845
Release: 2003-12-03
Genre: Science
ISBN: 0080913164

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Comprehensive Coordination Chemistry II (CCC II) is the sequel to what has become a classic in the field, Comprehensive Coordination Chemistry, published in 1987. CCC II builds on the first and surveys new developments authoritatively in over 200 newly comissioned chapters, with an emphasis on current trends in biology, materials science and other areas of contemporary scientific interest.

Synthesis and Characterization of Mixed Donor Ligands and Their Corresponding Metal Complexes

Synthesis and Characterization of Mixed Donor Ligands and Their Corresponding Metal Complexes
Author: Timothy Michael Erasmus Jugovic
Publisher:
Total Pages: 132
Release: 2017
Genre:
ISBN: 9780355341706

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Presented in this thesis is the synthesis and characterization of two new classes of mixed donor ligands, as well as several copper(II) and nickel(II) complexes. Chapter II details the synthesis and characterization of thiosemicarbazates, which are tridentate ONS (oxygen, nitrogen, sulfur) donor compounds. In Chapter III complexes of these thiosemicarbazate ligands with nickel(II) and copper(II) are prepared and characterized. Chapter IV discusses the synthesis and characterization of several different amidothiocrown and amidoazathiocrown ethers.

Synthesis and Reactivity of BIS(PYRIDYL) and BIS(PICOLYL) Mercaptoimidazoles

Synthesis and Reactivity of BIS(PYRIDYL) and BIS(PICOLYL) Mercaptoimidazoles
Author: Jessica Marie Hanley
Publisher:
Total Pages: 194
Release: 2012
Genre:
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Mixed-donor ligands are particularly attractive in inorganic chemistry due to their steric and electronic versatility and the multiple coordination modes they may exercise when bound to metal centers. Although pyridines are arguably the most common nitrogen-donor ligands and the coordination chemistry of heterocyclic thiones is well-established, the reactivity of simple tridentate ligands containing a combination of such functionalities is virtually unknown. The synthesis and reactivity of two new mixed-donor ligands, the bis(pyridyl)mercaptoimidazole (2-py)2m, and the bis(picolyl)mercaptoimidazole (2-pic)2m, have been developed. Several coordination complexes of (2-py)2m and (2-pic)2m have been prepared and fully characterized, including the complete series of group 12 metal compounds {(2-py)2m}MX2 and {(2-pic)2m}MX2 (M = Zn, Cd, Hg; X = CI, Br, I). In addition, an investigation of the coordination of these two N2S donor ligands with copper(I) was pursued because one of the key goals of this project is the preparation of synthetic analogues of methanobactin (mb), a small protein responsible for the uptake and delivery of copper(I) ions to various copper-dependent enzymes such as the particulate form of methane monooxygenase (pMMO). The copper(I) derivatives {(2-py)2m}CuX (X = Br, I) and {(2-pic)2m}CuX (X.

Artificial Metalloenzymes and MetalloDNAzymes in Catalysis

Artificial Metalloenzymes and MetalloDNAzymes in Catalysis
Author: Montserrat Diéguez
Publisher: John Wiley & Sons
Total Pages: 431
Release: 2018-02-21
Genre: Technology & Engineering
ISBN: 3527804072

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An important reference for researchers in the field of metal-enzyme hybrid catalysis Artificial Metalloenzymes and MetalloDNAzymes in Catalysis offers a comprehensive review of the most current strategies, developed over recent decades, for the design, synthesis, and optimization of these hybrid catalysts as well as material about their application. The contributors—noted experts in the field—present information on the preparation, characterization, and optimization of artificial metalloenzymes in a timely and authoritative manner. The authors present a thorough examination of this interesting new platform for catalysis that combines the excellent selective recognition/binding properties of enzymes with transition metal catalysts. The text includes information on the various applications of metal-enzyme hybrid catalysts for novel reactions, offers insights into the latest advances in the field, and contains an informative perspective on the future: Explores the development of artificial metalloenzymes, the modern and strongly evolving research field on the verge of industrial application Contains a comprehensive reference to the research area of metal-enzyme hybrid catalysis that has experienced tremendous growth in recent years Includes contributions from leading researchers in the field Shows how this new catalysis combines the selective recognition/binding properties of enzymes with transition metal catalysts Written for catalytic chemists, bioinorganic chemists, biochemists, and organic chemists, Artificial Metalloenzymes and MetalloDNAzymes in Catalysis offers a unique reference to the fundamentals, concepts, applications, and the most recent developments for more efficient and sustainable synthesis.

Surface Organometallic Chemistry: Molecular Approaches to Surface Catalysis

Surface Organometallic Chemistry: Molecular Approaches to Surface Catalysis
Author: Jean-Marie Basset
Publisher: Springer Science & Business Media
Total Pages: 340
Release: 2012-12-06
Genre: Science
ISBN: 9400929714

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Surface organometallic chemistry is a new field bringing together researchers from organometallic, inorganic, and surface chemistry and catalysis. Topics ranging from reaction mechanisms to catalyst preparation are considered from a molecular basis, according to which the "active site" on a catalyst surface has a supra-molecular character. This. the first book on the subject, is the outcome of a NATO Workshop held in Le Rouret. France, in May. 1986. It is our hope that the following chapters and the concluding summary of recommendations for research may help to provide a definition of surface organometallic chemistry. Besides catalysis. the central theme of the Workshop, four main topics are considered: 1) Reactions of organometallics with surfaces of metal oxides, metals. and zeolites; 2) Molecular models of surfaces, metal oxides, and metals; 3) Molecular approaches to the mechanisms of surface reactions; 4) Synthesis and modification of zeolites and related microporous solids. Most surface organometallic chemistry has been carried out on amorphous high-surf ace-area metal oxides such as silica. alumina. magnesia, and titania. The first chapter. contributed by KNOZINGER. gives a short summary of the structure and reactivity of metal oxide surfaces. Most of our understanding of these surfaces is based on acid base and redox chemistry; this chemistry has developed from X-ray and spectroscopic data, and much has been inferred from the structures and reactivities of adsorbed organic probe molecules. There are major opportunities for extending this understanding by use of well-defined (single crystal) oxide surfaces and organometallic probe molecules.