The aim of this work is to present several new results concerning duality in scalar convex optimization, the formulation of sequential optimality conditions and some applications of the duality to the theory of maximal monotone operators. After recalling some properties of the classical generalized interiority notions which exist in the literature, we give some properties of the quasi interior and quasi-relative interior, respectively. By means of these notions we introduce several generalized interior-point regularity conditions which guarantee Fenchel duality. By using an approach due to Magnanti, we derive corresponding regularity conditions expressed via the quasi interior and quasi-relative interior which ensure Lagrange duality. These conditions have the advantage to be applicable in situations when other classical regularity conditions fail. Moreover, we notice that several duality results given in the literature on this topic have either superfluous or contradictory assumptions, the investigations we make offering in this sense an alternative. Necessary and sufficient sequential optimality conditions for a general convex optimization problem are established via perturbation theory. These results are applicable even in the absence of regularity conditions. In particular, we show that several results from the literature dealing with sequential optimality conditions are rediscovered and even improved. The second part of the thesis is devoted to applications of the duality theory to enlargements of maximal monotone operators in Banach spaces. After establishing a necessary and sufficient condition for a bivariate infimal convolution formula, by employing it we equivalently characterize the $\varepsilon$-enlargement of the sum of two maximal monotone operators. We generalize in this way a classical result concerning the formula for the $\varepsilon$-subdifferential of the sum of two proper, convex and lower semicontinuous functions. A characterization of fully en.