Collodial Particles

Collodial Particles
Author: Sven Holger Behrens
Publisher:
Total Pages: 223
Release: 1999
Genre:
ISBN:

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Suspensions of Colloidal Particles and Aggregates

Suspensions of Colloidal Particles and Aggregates
Author: Frank Babick
Publisher: Springer
Total Pages: 358
Release: 2016-04-04
Genre: Technology & Engineering
ISBN: 3319306634

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This book addresses the properties of particles in colloidal suspensions. It has a focus on particle aggregates and the dependency of their physical behaviour on morphological parameters. For this purpose, relevant theories and methodological tools are reviewed and applied to selected examples. The book is divided into four main chapters. The first of them introduces important measurement techniques for the determination of particle size and interfacial properties in colloidal suspensions. A further chapter is devoted to the physico-chemical properties of colloidal particles—highlighting the interfacial phenomena and the corresponding interactions between particles. The book’s central chapter examines the structure-property relations of colloidal aggregates. This comprises concepts to quantify size and structure of aggregates, models and numerical tools for calculating the (light) scattering and hydrodynamic properties of aggregates, and a discussion on van-der-Waals and double layer interactions between aggregates. It is illustrated how such knowledge may significantly enhance the characterisation of colloidal suspensions. The final part of the book refers to the information, ideas and concepts already presented in order to address technical aspects of the preparation of colloidal suspensions—in particular the performance of relevant dispersion techniques and the stability of colloidal suspensions.

Surface and Colloid Science

Surface and Colloid Science
Author: Egon Matijevic
Publisher: Springer Science & Business Media
Total Pages: 384
Release: 2012-12-06
Genre: Science
ISBN: 1441991220

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Particles at Fluid Interfaces and Membranes

Particles at Fluid Interfaces and Membranes
Author: P. Kralchevsky
Publisher: Elsevier
Total Pages: 669
Release: 2001-01-22
Genre: Science
ISBN: 0080538479

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In the small world of micrometer to nanometer scale many natural and industrial processes include attachment of colloid particles (solid spheres, liquid droplets, gas bubbles or protein macromolecules) to fluid interfaces and their confinement in liquid films. This may lead to the appearance of lateral interactions between particles at interfaces, or between inclusions in phospholipid membranes, followed eventually by the formation of two-dimensional ordered arrays. The book is devoted to the description of such processes, their consecutive stages, and to the investigation of the underlying physico-chemical mechanisms. The first six chapters give a concise but informative introduction to the basic knowledge in surface and colloid science, which includes both traditional concepts and some recent results. Chapters 1 and 2 are devoted to the basic theory of capillarity, kinetics of surfactant adsorption, shapes of axisymmetric fluid interfaces, contact angles and line tension. Chapters 3 and 4 present a generalization of the theory of capillarity to the case, in which the variation of the interfacial (membrane) curvature contributes to the total energy of the system. The generalized Laplace equation is applied to determine the configurations of free and adherent biological cells. Chapters 5 and 6 are focused on the role of thin liquid films and hydrodynamic factors in the attachment of solid and fluid particles to an interface. Surface forces of various physical nature are presented and their relative importance is discussed. Hydrodynamic interactions of a colloidal particle with an interface (or another particle) are also considered.Chapters 7 to 10 are devoted to the theoretical foundation of various kinds of capillary forces. When two particles are attached to the same interface (membrane), capillary interactions, mediated by the interface or membrane, appear between them. Two major kinds of capillary interactions are described: (i) capillary immersion force related to the surface wettability (Chapter 7), (ii) capillary flotation force originating from interfacial deformations due to particle weight (Chapter 8). Special attention is paid to the theory of capillary immersion forces between particles entrapped in spherical liquid films (Chapter 9). A generalization of the theory of immersion forces allows one to describe membrane-mediated interactions between protein inclusions into a lipid bilayer (Chapter 10).Chapter 11 is devoted to the theory of the capillary bridges and the capillary-bridge forces, whose importance has been recognized in phenomena like consolidation of granules and soils, wetting of powders, capillary condensation, long-range hydrophobic attraction, etc. The nucleation of capillary bridges is also examined.Chapter 12 considers solid particles, which have an irregular wetting perimeter upon attachment to a fluid interface. The undulated contact line induces interfacial deformations, which engender a special lateral capillary force between the particles. The latter contributes to the dilatational and shear elastic moduli of particulate adsorption monolayers.Chapter 13 describes how lateral capillary forces, facilitated by convective flows and some specific and non-specific interactions, can lead to the aggregation and ordering of various particles at fluid interfaces or in thin liquid films. Recent results on fabricating two-dimensional (2D) arrays from micrometer and sub-micrometer latex particles, as well as 2D crystals from proteins and protein complexes, are reviewed. Chapter 14 presents applied aspects of the particle-surface interaction in antifoaming and defoaming. The mechanisms of antifoaming action involve as a necessary step the entering of an antifoam particle at the air-water interface. The considered mechanisms indicate the factors for control of foaminess.

The Langevin Equation

The Langevin Equation
Author: William Coffey
Publisher: World Scientific
Total Pages: 436
Release: 1996
Genre: Mathematics
ISBN: 9789810216511

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The book is suitable for a lecture course on the theory of Brownian motion, being based on final year undergraduate lectures given at Trinity College, Dublin. Topics that are discussed include: white noise; the Chapman-Kolmogorov equation ? Kramers-Moyal expansion; the Langevin equation; the Fokker-Planck equation; Brownian motion of a free particle; spectral density and the Wiener-Khintchin theorem ? Brownian motion in a potential application to the Josephson effect, ring laser gyro; Brownian motion in two dimensions; harmonic oscillators; itinerant oscillators; linear response theory; rotational Brownian motion; application to loss processes in dielectric and ferrofluids; superparamagnetism and nonlinear relaxation processes.As the first elementary book on the Langevin equation approach to Brownian motion, this volume attempts to fill in all the missing details which students find particularly hard to comprehend from the fundamental papers contained in the Dover reprint ? Selected Papers on Noise and Stochastic Processes, ed. N Wax (1954) ? together with modern applications particularly to relaxation in ferrofluids and polar dielectrics.

Particle Deposition and Aggregation

Particle Deposition and Aggregation
Author: Menachem Elimelech
Publisher: Butterworth-Heinemann
Total Pages: 520
Release: 1995
Genre: Science
ISBN:

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Very Good,No Highlights or Markup,all pages are intact.

Particle Deposition and Aggregation

Particle Deposition and Aggregation
Author: M. Elimelech
Publisher: Butterworth-Heinemann
Total Pages: 458
Release: 2013-10-22
Genre: Science
ISBN: 1483161374

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Particle Deposition and Aggregation: Measurement, Modelling and Simulation describes how particle deposition and aggregation can be measured, modeled, and simulated in a systematic manner. It brings together the necessary disciplines of colloid and surface chemistry, hydrodynamics, experimental methods, and computational methods to present a unified approach to this problem. The book is divided into four parts. Part I presents the theoretical principles governing deposition and aggregation phenomena, including a discussion of the forces that exist between particles and the hydrodynamic factors that control the movement of the particles and suspending fluid. Part II introduces methods for modeling the processes, first at a simple level (e.g. single particle-surface, single particle-single particle interactions in model flow conditions) and then describes the simulation protocols and computation tools which may be employed to describe more complex (multiple-particle interaction) systems. Part III summarizes the experimental methods of quantifying aggregating and depositing systems and concludes with a comparison of experimental results with those predicted using simple theoretical predictions. Part IV is largely based on illustrative examples to demonstrate the application of simulation and modeling methods to particle filtration, aggregation, and transport processes. This book should be useful to graduates working in process and environmental engineering research or industrial development at a postgraduate level, and to scientists who wish to extend their knowledge into more realistic process conditions in which the fluid hydrodynamics and other complicating factors must be accommodated.

Coagulation Kinetics and Structure Formation

Coagulation Kinetics and Structure Formation
Author: H. Sonntag
Publisher: Springer Science & Business Media
Total Pages: 189
Release: 2013-11-11
Genre: Science
ISBN: 1475706170

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Colloidal dispersions play a very important role in nature, industry, and daily life. Sometimes, long-term stability is observed or desired as in ferrotluids (composed of very small magnetic particles with radii of ~ 10 nm), which must be stable even in external fields. On the other hand, only short-term stable dispersions may be necessary during actual processing operations, for example, dispersions of magnetite particles during tape manufacture. The stability of dispersions and many of their physical properties are related to the interaction between the particles in the dispersion medium, which may contain surfactants or macromolecular species. If the net interparticle interaction forces are attractive, then aggregation may occur. Two general types of aggregation behavior may be distinguished: coagulation and flocculation. These two terms are frequently used synonymously but IUPAC has recommended the following definitions: Coagulation implies formation of compact aggregates, leading to the macroscopic separation. Flocculation implies the formation of a loose or open network, floc, which may or may not separate macroscopically. Flocculation brought about by the simultaneous coadsorption of polymer molecules on two (or more) particles is referred to as bridging flocculation. If coagulation results in the merging of two particles into one, as may occur with liquid droplets in emulsions, this process is referred to as coalescence.