Coal Liquefaction Catalyst Development
Author | : D. K. Kim |
Publisher | : |
Total Pages | : 32 |
Release | : 1980 |
Genre | : Catalysts |
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Author | : D. K. Kim |
Publisher | : |
Total Pages | : 32 |
Release | : 1980 |
Genre | : Catalysts |
ISBN | : |
Author | : |
Publisher | : |
Total Pages | : |
Release | : 1980 |
Genre | : |
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Catalytic baseline runs continued with HDS-1442A in order to improve our baseline statistics as well as to monitor batch reactor performance. Testing of several new catalyst formulations was completed. No promising candidates for testing in the continuous aging unit were identified. The new SRC-II slurry oil was evaluated as a hydrogen donor liquefaction solvent. Our data indicates that the SRC-II heavy distillate oil is not as effective a hydrogen donor solvent as the hydrogenated anthracene oil. It is possible that the catalyst plays a key role in the thermal liquefaction reactions by improving the hydrogen donor properties of the slurry oil through in-situ hydrogenation. The differences in liquefaction behavior between Illinois No. 6 and Wyodak coal were determined. A major portion of our effort was concerned with ascertaining the liquefaction behavior of a Western coal such as Wyodak with AMOCAT type catalysts. A two-month program to determine the feasibility of using the Amoco continuous aging unit for SRC-I product upgrading was outlined.
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Total Pages | : 504 |
Release | : 1986 |
Genre | : Power resources |
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Author | : |
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Total Pages | : 474 |
Release | : 1981 |
Genre | : Power resources |
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Includes all works deriving from DOE, other related government-sponsored information and foreign nonnuclear information.
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Total Pages | : 886 |
Release | : 1981 |
Genre | : Fossil fuels |
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Total Pages | : |
Release | : 1979 |
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The thermal and catalytic baseline runs continued with HDS-1442A as the reference catalyst and toluene soluble conversion as the basis for liquefaction performance. Results from these experiments suggested that a 30-minute run time should be selected for screening experiments. No promising candidates for testing in the continuous aging unit were identified. Catalyst Aging Tests: Eastern Coal was centered around evaluation of the new SRC II slurry oil as a liquefaction solvent as well as a design change in the catalyst basket for the continuous aging unit. Uncertainties in Run 5188 clouded the assessment of the slurry oil effect. Subsequent runs with the new SRC II solvent indicated that slurry oil effects are small. Catalyst Aging Tests: Western Coal concentrated on ascertaining the liquefaction behavior of a Western Coal such as Wyodak with AMOCAT type catalysts. Simplifications were made in the composition of our synthetic coal feed to improve analytical and kinetic accuracy. Using SRC II heavy distillate as the slurry oil and Illinois No. 6 coal feed, the results from the aging test are quite clear. The recently prepared 500 pound batch of AMOCAT 1A is good quality and exhibits highly improved performance over the H-Coal catalyst, HDS-1442A. Benzene and hexane soluble conversion are markedly higher with hexane soluble conversion declining less rapidly with time. The highly improved catalyst should be considered for future evaluation in the larger H-Coal process development unit.
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Total Pages | : 1236 |
Release | : 1985 |
Genre | : Government reports announcements & index |
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Total Pages | : 676 |
Release | : 1985 |
Genre | : Power resources |
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Total Pages | : 108 |
Release | : 1981 |
Genre | : Energy policy |
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Total Pages | : 588 |
Release | : 1980-10 |
Genre | : Solar energy |
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