Coal Liquefaction Catalyst Development. Quarterly Progress Report

Coal Liquefaction Catalyst Development. Quarterly Progress Report
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Release: 1979
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Work in Catalyst Preparation and Screening was concerned with modification of product workup procedure and elimination or reduction of uncertainties in the analysis of data from batch autoclave screening runs. Toluene was substituted for benzene as a solvent in the product workup because of the health hazard associated with the use of benzene and was added to the product prior to filtration in order to expose both liquid and solid product to the solvent. The conversion was about the same, using either the old benzene or new toluene product workup. The Engelhard dry coal charging device was used in an attempt to eliminate uncertainties in the batch screening data analysis. After considerable experimentation, use of the charging device was abandoned because of problems with plugging, temperature upsets, and catalyst coking. The effort in Catalyst Aging Tests with Eastern and Western Coal was centered around preparation of enough liquefaction solvent for the DOE program. In the application of new catalysts to the H-Coal process work centered around the 500 pound batch Amocat-1A (CoMo) received from W.R. Grace Company Catalyst inspection data were acceptable and, according to a recent HRI report, the performance results of the 500 pound batch were equivalent to or better than those of an earlier experiment Amocat-1A that HRI tested. The batch of catalyst was also tested in our continuous flow pilot plant, but results were inconclusive since lined-out slurry oil contained unconverted coal particles.

Advanced Coal Liquefaction Catalyst Development. Quarterly Progress Report

Advanced Coal Liquefaction Catalyst Development. Quarterly Progress Report
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Release: 1983
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Coal liquefaction results with and without Amocat catalysts at various conditions (especially with respect to variations of hydrogen pressure and organic solvent) are reported. (LTN).

Coal Liquefaction Catalyst Development. Quarterly Progress Report No. 3, October 1-December 31, 1979

Coal Liquefaction Catalyst Development. Quarterly Progress Report No. 3, October 1-December 31, 1979
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Release: 1980
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Catalytic baseline runs continued with HDS-1442A in order to improve our baseline statistics as well as to monitor batch reactor performance. Testing of several new catalyst formulations was completed. No promising candidates for testing in the continuous aging unit were identified. The new SRC-II slurry oil was evaluated as a hydrogen donor liquefaction solvent. Our data indicates that the SRC-II heavy distillate oil is not as effective a hydrogen donor solvent as the hydrogenated anthracene oil. It is possible that the catalyst plays a key role in the thermal liquefaction reactions by improving the hydrogen donor properties of the slurry oil through in-situ hydrogenation. The differences in liquefaction behavior between Illinois No. 6 and Wyodak coal were determined. A major portion of our effort was concerned with ascertaining the liquefaction behavior of a Western coal such as Wyodak with AMOCAT type catalysts. A two-month program to determine the feasibility of using the Amoco continuous aging unit for SRC-I product upgrading was outlined.

Coal Liquefaction Catalyst Development. Quarterly Progress Report No. 2, July 1-September 30, 1979

Coal Liquefaction Catalyst Development. Quarterly Progress Report No. 2, July 1-September 30, 1979
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Release: 1979
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The thermal and catalytic baseline runs continued with HDS-1442A as the reference catalyst and toluene soluble conversion as the basis for liquefaction performance. Results from these experiments suggested that a 30-minute run time should be selected for screening experiments. No promising candidates for testing in the continuous aging unit were identified. Catalyst Aging Tests: Eastern Coal was centered around evaluation of the new SRC II slurry oil as a liquefaction solvent as well as a design change in the catalyst basket for the continuous aging unit. Uncertainties in Run 5188 clouded the assessment of the slurry oil effect. Subsequent runs with the new SRC II solvent indicated that slurry oil effects are small. Catalyst Aging Tests: Western Coal concentrated on ascertaining the liquefaction behavior of a Western Coal such as Wyodak with AMOCAT type catalysts. Simplifications were made in the composition of our synthetic coal feed to improve analytical and kinetic accuracy. Using SRC II heavy distillate as the slurry oil and Illinois No. 6 coal feed, the results from the aging test are quite clear. The recently prepared 500 pound batch of AMOCAT 1A is good quality and exhibits highly improved performance over the H-Coal catalyst, HDS-1442A. Benzene and hexane soluble conversion are markedly higher with hexane soluble conversion declining less rapidly with time. The highly improved catalyst should be considered for future evaluation in the larger H-Coal process development unit.

Coal-liquefaction-catalyst Development. Quarterly Progress Report

Coal-liquefaction-catalyst Development. Quarterly Progress Report
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Release: 1980
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The catalyst prepared by dispersing cobalt boride and moly boride in an alumina matrix continues to exhibit acceptable liquefaction and desulfurization activity and superior denitrogenation activity. If an extrudate can be prepared from these materials having the correct pore structure, pilot plant testing should be conducted to evaluate activity maintenance. The cobalt sodium alumina/moly alumina mixed system has been optimized to give superior liquefaction and denitrogenation activity. A larger batch of coextruded mixture has been prepared and screened and is available for pilot plant testing. A thermally stable supported tin chloride ctalyst has been prepared and exhibits superior liquefaction and denitrogenation activity. An optimized catalyst contains 5% stannous chloride supported on a molybdenum alumina catalyst such as Amocat 1B. The system maintains its superior performance even after calcination at 1000°F for 3 hours. A large batch is now being prepared for pilot plant testing. The cobalt samarium moly catalyst prepared on extrudates had very poor metal distributions. This may be responsible for the poor performance of this batch of catalyst. If metals can be successfully distributed throughout an extrudate, the samarium modified catalyst should be retested in the pilot plant.

Energy Research Abstracts

Energy Research Abstracts
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Total Pages: 872
Release: 1988
Genre: Power resources
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Energy Research Abstracts

Energy Research Abstracts
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Total Pages: 660
Release: 1985
Genre: Power resources
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Includes all works deriving from DOE, other related government-sponsored information and foreign nonnuclear information.

Fossil Energy Update

Fossil Energy Update
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Total Pages: 944
Release: 1978
Genre: Fossil fuels
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