Classical Thermodynamics of Non-Electrolyte Solutions

Classical Thermodynamics of Non-Electrolyte Solutions
Author: H. C. Van Ness
Publisher: Elsevier
Total Pages: 176
Release: 2013-10-22
Genre: Science
ISBN: 148322547X

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Classical Thermodynamics of Non-Electrolyte Solutions covers the historical development of classical thermodynamics that concerns the properties of vapor and liquid solutions of non-electrolytes. Classical thermodynamics is a network of equations, developed through the formal logic of mathematics from a very few fundamental postulates and leading to a great variety of useful deductions. This book is composed of seven chapters and begins with discussions on the fundamentals of thermodynamics and the thermodynamic properties of fluids. The succeeding chapter presents the equations of state for the calculation of the thermodynamic behavior of constant-composition fluids, both liquid and gaseous. These topics are followed by surveys of the mixing of pure materials to form a solution under conditions of constant temperature and pressure. The discussion then shifts to general equations for calculation of partial molal properties of homogeneous binary systems. The last chapter considers the approach to equilibrium of systems within which composition changes are brought about either by mass transfer between phases or by chemical reaction within a phase, or by both.

Thermodynamic Properties of Nonelectrolyte Solutions

Thermodynamic Properties of Nonelectrolyte Solutions
Author: William Acree
Publisher: Academic Press
Total Pages: 319
Release: 2012-12-02
Genre: Science
ISBN: 032314067X

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Thermodynamic Properties of Nonelectrolyte Solutions reviews several of the more classical theories on the thermodynamics of nonelectrolyte solutions. Basic thermodynamic principles are discussed, along with predictive methods and molecular thermodynamics. This book is comprised of 12 chapters; the first of which introduces the reader to mathematical relationships, such as concentration variables, homogeneous functions, Euler’s theorem, exact differentials, and method of least squares. The discussion then turns to partial molar quantities, ideal and nonideal solutions, and empirical expressions for predicting the thermodynamic properties of multicomponent mixtures from binary data. The chapters that follow explore binary and ternary mixtures containing only nonspecific interactions; the thermodynamic excess properties of liquid mixtures and ternary alcohol-hydrocarbon systems; and solubility behavior of nonelectrolytes. This book concludes with a chapter describing the use of gas-liquid chromatography in determining the activity coefficients of liquid mixtures and mixed virial coefficients of gaseous mixtures. This text is intended primarily for professional chemists and researchers, and is invaluable to students in chemistry or chemical engineering who have background in physical chemistry and classical thermodynamics.

Thermodynamics with Chemical Engineering Applications

Thermodynamics with Chemical Engineering Applications
Author: Elias I. Franses
Publisher: Cambridge University Press
Total Pages: 469
Release: 2014-08-25
Genre: Technology & Engineering
ISBN: 1316061841

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Master the principles of thermodynamics with this comprehensive undergraduate textbook, carefully developed to provide students of chemical engineering and chemistry with a deep and intuitive understanding of the practical applications of these fundamental ideas and principles. Logical and lucid explanations introduce core thermodynamic concepts in the context of their measurement and experimental origin, giving students a thorough understanding of how theoretical concepts apply to practical situations. A broad range of real-world applications relate key topics to contemporary issues, such as energy efficiency, environmental engineering and climate change, and further reinforce students' understanding of the core material. This is a carefully organized, highly pedagogical treatment, including over 500 open-ended study questions for discussion, over 150 varied homework problems, clear and objective standards for measuring student progress, and a password-protected solution manual for instructors.

Thermodynamics of Phase Equilibria in Food Engineering

Thermodynamics of Phase Equilibria in Food Engineering
Author: Camila Gambini Pereira
Publisher: Academic Press
Total Pages: 684
Release: 2018-10-17
Genre: Technology & Engineering
ISBN: 0128115572

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Thermodynamics of Phase Equilibria in Food Engineering is the definitive book on thermodynamics of equilibrium applied to food engineering. Food is a complex matrix consisting of different groups of compounds divided into macronutrients (lipids, carbohydrates, and proteins), and micronutrients (vitamins, minerals, and phytochemicals). The quality characteristics of food products associated with the sensorial, physical and microbiological attributes are directly related to the thermodynamic properties of specific compounds and complexes that are formed during processing or by the action of diverse interventions, such as the environment, biochemical reactions, and others. In addition, in obtaining bioactive substances using separation processes, the knowledge of phase equilibria of food systems is essential to provide an efficient separation, with a low cost in the process and high selectivity in the recovery of the desired component. This book combines theory and application of phase equilibria data of systems containing food compounds to help food engineers and researchers to solve complex problems found in food processing. It provides support to researchers from academia and industry to better understand the behavior of food materials in the face of processing effects, and to develop ways to improve the quality of the food products. Presents the fundamentals of phase equilibria in the food industry Describes both classic and advanced models, including cubic equations of state and activity coefficient Encompasses distillation, solid-liquid extraction, liquid-liquid extraction, adsorption, crystallization and supercritical fluid extraction Explores equilibrium in advanced systems, including colloidal, electrolyte and protein systems

Thermodynamics Of Fluids: Measurement And Correlation

Thermodynamics Of Fluids: Measurement And Correlation
Author: A Anderko
Publisher: World Scientific
Total Pages: 526
Release: 1990-03-01
Genre:
ISBN: 9814611778

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This volume is a collection of papers, mostly state-of-the-art reviews, describing main topics of current research in Applied Thermodynamics. The papers deal with measurements of thermodynamic properties which are important for process design in chemical and related industries as well as for theoretical investigations of pure fluids and mixtures. Besides measuring techniques, methods are reviewed for the processing and correlation of experimental data.

Handbook of Separation Process Technology

Handbook of Separation Process Technology
Author: Ronald W. Rousseau
Publisher: John Wiley & Sons
Total Pages: 1028
Release: 1987-05-13
Genre: Technology & Engineering
ISBN: 9780471895589

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Surveys the selection, design, and operation of most of the industrially important separation processes. Discusses the underlying principles on which the processes are based, and provides illustrative examples of the use of the processes in a modern context. Features thorough treatment of newer separation processes based on membranes, adsorption, chromatography, ion exchange, and chemical complexation. Includes a review of historically important separation processes such as distillation, absorption, extraction, leaching, and crystallization and considers these techniques in light of recent developments affecting them.