Catalysis of Organic Reactions

Catalysis of Organic Reactions
Author: Dennis G. Morrell
Publisher: CRC Press
Total Pages: 868
Release: 2002-11-13
Genre: Science
ISBN: 9780203911013

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This text offers authoritative contributions from nearly 200 leaders in the field and new methods to enhance catalytic reactions. "Catalysis of Organic Reactions" covers approaches for designing, modifying, and altering catalysts for improved function, performance, and stability, procedures to reduce by-product formation, and cost-effective alterna

Catalysis of Organic Reactions

Catalysis of Organic Reactions
Author: Mike G. Scaros
Publisher: CRC Press
Total Pages: 632
Release: 1994-10-20
Genre: Science
ISBN: 9780824793647

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Based on the papers and posters presented at the 15th Conference on Catalysis of Organic Reactions, this work covers developments in the study of catalysis as it relates to organic synthesis, emphasizing applications in industrial processes. Over 1000 bibliographic citations and over 250 tables, drawings, and photographs are provided. Theoretical and practical aspects of the field are highlighted.

Heterogeneous Catalysis in Organic Chemistry

Heterogeneous Catalysis in Organic Chemistry
Author: Gerard V. Smith
Publisher: Academic Press
Total Pages: 363
Release: 1999-06-30
Genre: Science
ISBN: 008052480X

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The features of this book which will be of special interest to academic organic chemists are the introduction (Chapter 1), which presents a short course on the concepts and language of heterogeneous catalysis, covers organic reaction mechanisms of hydrogenation (Chapter 2), hydrogenolysis (Chapter 4), and oxidation (Chapter 6), a presents problems and solutions specific for running heterogeneous catalytic organic reactions in solution. These materials can supplement advanced chemistry courses. Most synthetic organic chemists use a variety of "protecting groups" which they attach to functional groups (reactive groups of atoms) while some reaction is being conducted on another part of the molecule. These protecting groups prevent reactions of the functional groups during other reactions and are removed later by a heterogeneous catalytic method called hydrogenolysis. One unique feature of this book, not found in other books on catalysis, is an exhaustive chapter (Chapter 4) on hydrogenolysis, which is dredged from the recent synthetic literature published by modern organic chemists. Academic organic chemists should find this chapter extremely useful and may wish to adopt the book as a supplement for advanced organic chemistry courses designed for seniors and for graduate students. It will also be useful for professors and their research groups engaged in synthetic organic chemistry. Many academic organic chemists are not aware of recent advances in heterogeneous enantioselective catalysis (Chapter 3) or in selective low temperature, liquid phase heterogeneous catalytic oxidations by hydrogen peroxide (Chapter 6). These specialty topics are timely and may be new to academic organic chemists and can be used to supplement their advanced courses. Several features of this book will also be of special interest to industrial chemists who are unfamiliar with heterogeneous catalysis. Many good organic chemists are hire by industry. They synthesize a new compound using standard organic synthetic techniques but are informed by their supervisor that they must convert some of their synthetic steps into heterogeneous catalytic steps. They may not have been exposed to heterogeneous catalysis and have few places to turn. This book offers them a crash course in heterogeneous catalysis as well as many examples of reactions and conditions with which they can start their search. Those industrial organic chemists already familiar with heterogeneous catalysis will find this book useful as a reference to many examples in the recent literature. They will find recent surface science discoveries correlated with heterogeneous catalysis or organic reactions and mechanistic suggestions designed to stimulate innovative nontraditional thinking about organic reactions on surfaces. Written by organic chemists for organic chemists Introduces heterogeneous catalysis concepts and language Presents a comprehensive compilation of protecting group removal procedures Covers liquid-phase hydrogenations, hydrogenolysis, and oxidations Addresses heterogeneous methods for producing pure enantiomers of chiral products Examines the emerging field of heterogenized homogeneous catalysts Mixes practical applications with mechanistic interpretations

Organic Chemistry of Enzyme-Catalyzed Reactions, Revised Edition

Organic Chemistry of Enzyme-Catalyzed Reactions, Revised Edition
Author: Richard B. Silverman
Publisher: Elsevier
Total Pages: 736
Release: 2002-03-07
Genre: Technology & Engineering
ISBN: 0080513360

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The Organic Chemistry of Enzyme-Catalyzed Reactions is not a book on enzymes, but rather a book on the general mechanisms involved in chemical reactions involving enzymes. An enzyme is a protein molecule in a plant or animal that causes specific reactions without itself being permanently altered or destroyed. This is a revised edition of a very successful book, which appeals to both academic and industrial markets. Illustrates the organic mechanism associated with each enzyme-catalyzed reaction Makes the connection between organic reaction mechanisms and enzyme mechanisms Compiles the latest information about molecular mechanisms of enzyme reactions Accompanied by clearly drawn structures, schemes, and figures Includes an extensive bibliography on enzyme mechanisms covering the last 30 years Explains how enzymes can accelerate the rates of chemical reactions with high specificity Provides approaches to the design of inhibitors of enzyme-catalyzed reactions Categorizes the cofactors that are appropriate for catalyzing different classes of reactions Shows how chemical enzyme models are used for mechanistic studies Describes catalytic antibody design and mechanism Includes problem sets and solutions for each chapter Written in an informal and didactic style

Nickel Catalysis in Organic Synthesis

Nickel Catalysis in Organic Synthesis
Author: Sensuke Ogoshi
Publisher: John Wiley & Sons
Total Pages: 348
Release: 2020-03-09
Genre: Science
ISBN: 3527344071

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A comprehensive reference to nickel chemistry for every scientist working with organometallic catalysts Written by one of the world?s leading reseachers in the field, Nickel Catalysis in Organic Synthesis presents a comprehensive review of the high potential of modern nickel catalysis and its application in synthesis. Structured in a clear and assessible manner, the book offers a collection of various reaction types, such as cross-coupling reactions, reactions for the activation of unreactive bonds, carbon dioxide fixation, and many more. Nickel has been recognized as one of the most interesting transition metals for homogeneous catalysis. This book offers an overview to the recently developed new ligands, new reaction conditions, and new apparatus to control the reactivity of nickel catalysts, allowing scientists to apply nickel catalysts to a variety of bond-forming reactions. A must-read for anyone working with organometallic compounds and their application in organic synthesis, this important guide: -Reviews the numerous applications of nickel catalysis in synthesis -Explores the use of nickel as a relatively cheap and earth-abundant metal -Examines the versatility of nickel catalysis in reactions like cross-coupling reactions and CH activations -Offers a resource for academics and industry professionals Written for catalytic chemists, organic chemists, inorganic chemists, structural chemists, and chemists in industry, Nickel Catalysis in Organic Synthesis provides a much-needed overview of the most recent developments in modern nickel catalysis and its application in synthesis.

Metal-Based Catalysts in Organic Synthesis

Metal-Based Catalysts in Organic Synthesis
Author: Manas Sutradhar
Publisher: MDPI
Total Pages: 68
Release: 2021-08-30
Genre: Science
ISBN: 3036510621

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Catalysts play a crucial role in the path towards the transformation of organic compounds. This book describes the recent development of metal-based catalysis in organic synthesis. Applications of various catalysts to interesting organic transformations are discussed. It covers important organic reactions such as cyclohexane oxidation under different energy stimuli, use of Pd-nanoparticles for carbonylation of aniline, ammoximation of methyl ethyl ketone by Ni-modified TS-1 and carbozincation of substituted 2-alkynylamines. This book will be a useful reference for researchers in the field of catalysis, organic chemistry and materials science. It is also intended to attract the attention of researchers with an industrial interest.

Clay Mineral Catalysis of Organic Reactions

Clay Mineral Catalysis of Organic Reactions
Author: BENNY K.G. THENG
Publisher: CRC Press
Total Pages: 426
Release: 2020-06-30
Genre:
ISBN: 9780367571290

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Clay minerals are layer silicates with a large propensity for adsorbing and intercalating simple and polymeric organic molecules. Because of their fine particle size, extensive surface area, layer structure, and peculiar charge characteristics, clay minerals can also act as efficient solid acid catalysts and catalyst carriers/supports. Besides being easy to separate from the reaction mixture and recyclable, clay minerals are abundant, inexpensive, and nonpolluting. Moreover, layer silicates offer a reduced dimensionality of reaction space in which introduced organic species can meet and collide. This book provides an insight into the relationship between the surface properties of clay minerals and their catalytic activity. Organized into eight comprehensive chapters, the volume describes and discusses the ability of clay minerals to serve as solid acid catalysts for a large range and variety of organic conversions and transformations. This book is a valuable reference for research scientists and industrial chemists who use, or contemplate using, clay minerals as catalysts for targeted organic reactions and syntheses. The present text will also be of interest to environmental and soil chemists as well as teachers and postgraduate students of organic geochemistry and solid acid catalysis. Book jacket.

Catalysis of Organic Reactions

Catalysis of Organic Reactions
Author: Michael L. Prunier
Publisher: CRC Press
Total Pages: 679
Release: 2008-12-24
Genre: Science
ISBN: 1439857709

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Apply an Omnibus of Knowledge from Leaders in the Field The unexpected diversity of topics presented at previous gatherings forced organizers of 2008’s 22nd Conference on Catalysis of Organic Reactions to expand its format to reflect the remarkable current degree of specialization in the field. Catalysis of Organic Reactions contains a compilation of papers presented at the event, and subsequently, few books will be able to match the breadth and depth of its content. Featuring papers by respected scientists from academia, industry, and the governmental research-and-development sector, it covers various aspects of the production, sale, and use of catalysts for practical purposes. Articles concentrate on the general area of catalyzed synthesis, emphasizing the production of organic chemicals. With a focus on application rather than theory, the dominant theme is the traditionally practiced area of heterogeneous catalysis. Topics include: Hydrogenation and hydrogenolysis C-C coupling Amination and oxidation (including the precious metal, supported base metal, and sponge metal, Raney process, and homogeneous catalyst types) End uses of products, including industrial petrochemicals, fine chemicals, and pharma intermediates Those working with applied catalysis will benefit greatly from this consolidation of insights and reviews of the latest developments in the field. Each of the papers presented were edited by ORCS members, drawn from both academia and industry, and peer-reviewed by experts in related fields of study.

Iron Catalysis in Organic Chemistry

Iron Catalysis in Organic Chemistry
Author: Bernd Plietker
Publisher: John Wiley & Sons
Total Pages: 295
Release: 2008-09-08
Genre: Science
ISBN: 3527623280

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This first comprehensive book to cover this exciting field also deals with the biological aspects, such as enzymes with iron. Following an introduction, this handy reference and handbook goes on to deal with reductions, oxidations of C, H- and C=C bonds, oxidative allylic oxygenation and amination, the oxidation of heteroatoms, cross coupling reactions, aromatic and nucleophilic substitutions, addition to carbonyl compounds, and cyclisations as well as ring opening reactions. The chapters are clearly classified according to the reaction type, allowing readers to quickly locate the desired information.

Catalysis of Organic Reactions

Catalysis of Organic Reactions
Author: Dale W. Blackburn
Publisher: CRC Press
Total Pages: 377
Release: 2020-07-24
Genre: Science
ISBN: 1000104370

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This volume is a collection of the papers presented at the Twelfth Conference on the Catalysis of Organic Reactions, where all phases of catalysis, including heterogeneous catalytic hydrogenation, catalytic oxidation, homogeneous catalysis, carbonylation, and amination have been discussed.