Bio Inspired Catalysts
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Author | : Thomas R. Ward |
Publisher | : Springer |
Total Pages | : 122 |
Release | : 2009-02-19 |
Genre | : Science |
ISBN | : 3540877576 |
Download Bio-inspired Catalysts Book in PDF, Epub and Kindle
In order to meet the ever-increasing demands for enantiopure compounds, heteroge- ous, homogeneous and enzymatic catalysis evolved independently in the past. Although all three approaches have yielded industrially viable processes, the latter two are the most widely used and can be regarded as complementary in many respects. Despite the progress in structural, computational and mechanistic studies, however, to date there is no universal recipe for the optimization of catalytic processes. Thus, a trial-and-error approach remains predominant in catalyst discovery and optimization. With the aim of complementing the well-established fields of homogeneous and enzymatic catalysis, organocatalysis and artificial metalloenzymes have enjoyed a recent revival. Artificial metalloenzymes, which are the focus of this book, result from comb- ing an active but unselective organometallic moiety with a macromolecular host. Kaiser and Whitesides suggested the possibility of creating artificial metallo- zymes as long ago as the late 1970s. However, there was a widespread belief that proteins and organometallic catalysts were incompatible with each other. This severely hampered research in this area at the interface between homogeneous and enzymatic catalysis. Since 2000, however, there has been a growing interest in the field of artificial metalloenzymes for enantioselective catalysis. The current state of the art and the potential for future development are p- sented in five well-balanced chapters. G. Roelfes, B. Feringa et al. summarize research relying on DNA as a macromolecular host for enantioselective catalysis.
Author | : Thomas R. Ward |
Publisher | : Springer Science & Business Media |
Total Pages | : 122 |
Release | : 2009-02-05 |
Genre | : Science |
ISBN | : 3540877568 |
Download Bio-inspired Catalysts Book in PDF, Epub and Kindle
In order to meet the ever-increasing demands for enantiopure compounds, heteroge- ous, homogeneous and enzymatic catalysis evolved independently in the past. Although all three approaches have yielded industrially viable processes, the latter two are the most widely used and can be regarded as complementary in many respects. Despite the progress in structural, computational and mechanistic studies, however, to date there is no universal recipe for the optimization of catalytic processes. Thus, a trial-and-error approach remains predominant in catalyst discovery and optimization. With the aim of complementing the well-established fields of homogeneous and enzymatic catalysis, organocatalysis and artificial metalloenzymes have enjoyed a recent revival. Artificial metalloenzymes, which are the focus of this book, result from comb- ing an active but unselective organometallic moiety with a macromolecular host. Kaiser and Whitesides suggested the possibility of creating artificial metallo- zymes as long ago as the late 1970s. However, there was a widespread belief that proteins and organometallic catalysts were incompatible with each other. This severely hampered research in this area at the interface between homogeneous and enzymatic catalysis. Since 2000, however, there has been a growing interest in the field of artificial metalloenzymes for enantioselective catalysis. The current state of the art and the potential for future development are p- sented in five well-balanced chapters. G. Roelfes, B. Feringa et al. summarize research relying on DNA as a macromolecular host for enantioselective catalysis.
Author | : Wolfgang Weigand |
Publisher | : John Wiley & Sons |
Total Pages | : 438 |
Release | : 2014-08-18 |
Genre | : Science |
ISBN | : 3527664181 |
Download Bioinspired Catalysis Book in PDF, Epub and Kindle
This book provides an overview of bioinspired metal-sulfur catalysis by covering structures, activities and model complexes of enzymes exhibiting metal sulphur moieties in their active center.
Author | : Gerhard Swiegers |
Publisher | : John Wiley & Sons |
Total Pages | : 532 |
Release | : 2012-09-17 |
Genre | : Science |
ISBN | : 1118310071 |
Download Bioinspiration and Biomimicry in Chemistry Book in PDF, Epub and Kindle
Can we emulate nature's technology in chemistry? Through billions of years of evolution, Nature has generated some remarkable systems and substances that have made life on earth what it is today. Increasingly, scientists are seeking to mimic Nature's systems and processes in the lab in order to harness the power of Nature for the benefit of society. Bioinspiration and Biomimicry in Chemistry explores the chemistry of Nature and how we can replicate what Nature does in abiological settings. Specifically, the book focuses on wholly artificial, man-made systems that employ or are inspired by principles of Nature, but which do not use materials of biological origin. Beginning with a general overview of the concept of bioinspiration and biomimicry in chemistry, the book tackles such topics as: Bioinspired molecular machines Bioinspired catalysis Biomimetic amphiphiles and vesicles Biomimetic principles in macromolecular science Biomimetic cavities and bioinspired receptors Biomimicry in organic synthesis Written by a team of leading international experts, the contributed chapters collectively lay the groundwork for a new generation of environmentally friendly and sustainable materials, pharmaceuticals, and technologies. Readers will discover the latest advances in our ability to replicate natural systems and materials as well as the many impediments that remain, proving how much we still need to learn about how Nature works. Bioinspiration and Biomimicry in Chemistry is recommended for students and researchers in all realms of chemistry. Addressing how scientists are working to reverse engineer Nature in all areas of chemical research, the book is designed to stimulate new discussion and research in this exciting and promising field.
Author | : Gerhard Swiegers |
Publisher | : John Wiley & Sons |
Total Pages | : 532 |
Release | : 2012-10-30 |
Genre | : Science |
ISBN | : 0470566671 |
Download Bioinspiration and Biomimicry in Chemistry Book in PDF, Epub and Kindle
Can we emulate nature's technology in chemistry? Through billions of years of evolution, Nature has generated some remarkable systems and substances that have made life on earth what it is today. Increasingly, scientists are seeking to mimic Nature's systems and processes in the lab in order to harness the power of Nature for the benefit of society. Bioinspiration and Biomimicry in Chemistry explores the chemistry of Nature and how we can replicate what Nature does in abiological settings. Specifically, the book focuses on wholly artificial, man-made systems that employ or are inspired by principles of Nature, but which do not use materials of biological origin. Beginning with a general overview of the concept of bioinspiration and biomimicry in chemistry, the book tackles such topics as: Bioinspired molecular machines Bioinspired catalysis Biomimetic amphiphiles and vesicles Biomimetic principles in macromolecular science Biomimetic cavities and bioinspired receptors Biomimicry in organic synthesis Written by a team of leading international experts, the contributed chapters collectively lay the groundwork for a new generation of environmentally friendly and sustainable materials, pharmaceuticals, and technologies. Readers will discover the latest advances in our ability to replicate natural systems and materials as well as the many impediments that remain, proving how much we still need to learn about how Nature works. Bioinspiration and Biomimicry in Chemistry is recommended for students and researchers in all realms of chemistry. Addressing how scientists are working to reverse engineer Nature in all areas of chemical research, the book is designed to stimulate new discussion and research in this exciting and promising field.
Author | : Kristin Schröder |
Publisher | : |
Total Pages | : 228 |
Release | : 2010 |
Genre | : |
ISBN | : |
Download Development of Novel Bio-inspired Iron-based Catalysts for the Oxidation of Olefins with H_1tn2O_1tn2 Or Air Book in PDF, Epub and Kindle
Author | : Koichiro Nakamura |
Publisher | : |
Total Pages | : |
Release | : 2011 |
Genre | : |
ISBN | : 9789533072715 |
Download Biomimetic and Bio-inspired Catalytic System for Arsenic Detoxification: Bio-inspired Catalysts with Vitamin-B12 Cofactor Book in PDF, Epub and Kindle
Author | : Paul David Oldenburg |
Publisher | : |
Total Pages | : 418 |
Release | : 2007 |
Genre | : |
ISBN | : |
Download Design of Bio-inspired Nonheme Iron Oxidation Catalysts Book in PDF, Epub and Kindle
Author | : Cheng-Yong Su |
Publisher | : |
Total Pages | : 550 |
Release | : 2020-03-13 |
Genre | : Science |
ISBN | : 9789811217791 |
Download Supramolecular Catalysts Book in PDF, Epub and Kindle
The construction of catalysts by supramolecular forces has recently become a powerful tool and the role of noncovalent interactions can assist in designing new tools for the construction of effective and selective catalytic systems. It is unquestionably, vastly important to understand how different noncovalent interactions can be controlled or manipulated under appropriate reaction conditions. Supramolecular catalysts have had a tremendous impact on the syntheses of both chemical commodities and fine chemicals over the last 50 years, leading to the discovery of new reactions that were previously deemed impossible. This means that supramolecular chemistry plays a predominant role in accelerating or understanding chemical reactions.This book which addresses the above points is written by some of the leading contributors in this field and is intended for graduate students, researchers and academics working in supramolecular chemistry, organic chemistry, inorganic chemistry, and physical chemistry as well as researchers with an interest in the area of catalysis. The authors give examples illustrating the growth of the field, especially with special emphasis on new results published over the last decade. They also provide an explanation of fundamentals and topical research.
Author | : |
Publisher | : |
Total Pages | : |
Release | : 2014 |
Genre | : |
ISBN | : |
Download Theoretical Research Program on Bio-inspired Inorganic Hydrogen Generating Catalysts and Electrodes Book in PDF, Epub and Kindle
In this project, we have successfully designed and characterized a promising biomimetic catalyst/electrode complex, [FeFe]P/FeS2 for producing hydrogen from water. It is comprised of earth-abundant materials and, with a diffusion-limited rate in acidified water, is efficient as well as oxygen tolerant. The theoretical techniques we have developed and the experience we have gained are broadly applicable for the design and analysis of biomimetic electrochemically active catalysts.