Aryl Substituted Imino N Heterocyclic Carbene Complexes Of Late Transition Metals
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Author | : Anna Candace Badaj |
Publisher | : |
Total Pages | : |
Release | : 2014 |
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Download Aryl-Substituted Imino-N-Heterocyclic Carbene Complexes Of Late Transition Metals Book in PDF, Epub and Kindle
Author | : Timothy Gordon Larocque |
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Total Pages | : |
Release | : 2013 |
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Download Transition Metal Complexes of N-heterocyclic Carbenes and Derivatives Thereof Book in PDF, Epub and Kindle
N-heterocyclic carbenes (NHCs) have played a dominant role in organometallic chemistry for decades and revolutionized the field of homogenous catalysis. NHCs have been thoroughly studied, both experimentally and theoretically, and have shown unique reactivity towards transition metals, chalcogens, azides and pnictogens. This thesis is aimed at utilizing the unique reactivity of N-heterocyclic carbenes to develop novel, robust catalysts to mediate organic transformations. The multi-faceted work within this thesis explores the use of NHCs as ancillary ligands on early and late transition metals as potential catalysts for olefin polymerization and ring-closing metathesis, respectively. This work also includes exploring the synthesis and coordination of ancillary ligands derived from the unique reactivity of NHCs towards azides, chalcogens and pnictinidenes. The reactivity of a novel aryl-substituted acyclic imino-N-heterocyclic carbene to early transition metals, cyclooctasulfur and Grubbs-type ruthenium benzylidene complexes was explored. The reactivity of imidazol-2-imide towards Grubbs-type ruthenium benzylidene complexes and the synthesis and coordination of a novel group of ligands bearing an imidazol-2-imine scaffold were also explored. Lastly, this work will include the reactivity of IMes=PPh to Grubbs-type ruthenium benzylidene complexes.
Author | : Jay James Dunsford |
Publisher | : |
Total Pages | : 496 |
Release | : 2012 |
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Download Expanded Ring N-heterocyclic Carbene Complexes of the Late Transition Metals Book in PDF, Epub and Kindle
Author | : Remi Chauvin |
Publisher | : Springer |
Total Pages | : 260 |
Release | : 2009-12-18 |
Genre | : Science |
ISBN | : 364204722X |
Download Transition Metal Complexes of Neutral eta1-Carbon Ligands Book in PDF, Epub and Kindle
Contents: Yves Canac and Remi Chauvin: Neutral eta1-carbon ligands: beyond carbon monoxide; Esteban P. Urriolabeitia: Ylide Ligands; Wolfgang Petz and Gernot Frenking: Carbodiphosphoranes and related ligands; Mareike C. Jahnke and F. Ekkehardt Hahn: Chemistry of N-Heterocyclic Carbene Ligands; Tsuyoshi Kato, Eddy Maerten, Antoine Baceiredo: Non-NHCs stable singlet carbene ligands; Victorio Cadierno, Sergio E. García-Garrido: All-Carbon-Substituted Allenylidene and Related Cumulenylidene Ligands; Victorio Cadierno, Sergio E. García-Garrido: Heteroatom-Conjugated Allenylidene and Related Cumulenylidene Ligands.
Author | : Uli Kazmaier |
Publisher | : Springer |
Total Pages | : 354 |
Release | : 2011-10-28 |
Genre | : Science |
ISBN | : 364222749X |
Download Transition Metal Catalyzed Enantioselective Allylic Substitution in Organic Synthesis Book in PDF, Epub and Kindle
Giovanni Poli, Guillaume Prestat, Frédéric Liron, Claire Kammerer-Pentier: Selectivity in Palladium Catalyzed Allylic Substitution.- Jonatan Kleimark and Per-Ola Norrby: Computational Insights into Palladium-mediated Allylic Substitution Reactions.- Ludovic Milhau, Patrick J. Guiry: Palladium-catalyzed enantioselective allylic substitution.- Wen-Bo Liu, Ji-Bao Xia, Shu-Li You: Iridium-Catalyzed Asymmetric Allylic Substitutions.- Christina Moberg: Molybdenum- and Tungsten-Catalyzed Enantioselective Allylic Substitutions.- Jean-Baptiste Langlois, Alexandre Alexakis: Copper-catalyzed enantioselective allylic substitution.- Jeanne-Marie Begouin, Johannes E. M. N. Klein, Daniel Weickmann, B. Plietker: Allylic Substitutions Catalyzed by Miscellaneous Metals.- Barry M. Trost, Matthew L. Crawley: Enantioselective Allylic Substitutions in Natural Product Synthesis.
Author | : Jameel Raddah Al-Thagfi |
Publisher | : |
Total Pages | : |
Release | : 2014 |
Genre | : |
ISBN | : |
Download Synthesis, Characterization and Reactivity Study of Bis (Imino)-N-Heterocyclic Carbene Transition Metal Complexes Book in PDF, Epub and Kindle
Author | : |
Publisher | : |
Total Pages | : 122 |
Release | : 2012 |
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Download Synthesis and Characterisation of Late Transition Metal Complexes Containing Novel Mixed N-heterocyclic Carbene and Thione Donors Book in PDF, Epub and Kindle
Author | : Korbinian Riener |
Publisher | : |
Total Pages | : |
Release | : 2016 |
Genre | : |
ISBN | : 9783843926225 |
Download Mechanistic Insights Into Late Transition Metal-Catalyzed Olefin Hydrosilylation and Synthesis of New N-Heterocyclic Carbene and Dinuclear Complexes Book in PDF, Epub and Kindle
Author | : María Dolores Ibarra Arias |
Publisher | : |
Total Pages | : 142 |
Release | : 2007 |
Genre | : |
ISBN | : |
Download Synthesis of Unsymmetrically Substituted Free N-heterocyclic Carbenes, Electron Rich Olefines and Their Transition Metal Complexes Book in PDF, Epub and Kindle
Author | : Li Min Serena Goh |
Publisher | : |
Total Pages | : 161 |
Release | : 2012 |
Genre | : |
ISBN | : 9783843904919 |
Download N-heterocyclic carbenes of late transition metals in catalysis Book in PDF, Epub and Kindle