Ageing and the Glass Transition

Ageing and the Glass Transition
Author: Malte Henkel
Publisher: Springer
Total Pages: 361
Release: 2007-04-11
Genre: Science
ISBN: 3540696849

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Understanding cooperative phenomena far from equilibrium is one of the fascinating challenges of present-day many-body physics. Glassy behaviour and the physical ageing process of such materials are paradigmatic examples. The present volume, primarily intended as introduction and reference, collects six extensive lectures addressing selected experimental and theoretical issues in the field of glassy systems.

Ageing and the Glass Transition

Ageing and the Glass Transition
Author: Malte Henkel
Publisher: Springer Science & Business Media
Total Pages: 362
Release: 2007-04-24
Genre: Science
ISBN: 3540696830

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Understanding cooperative phenomena far from equilibrium is one of the fascinating challenges of present-day many-body physics. Glassy behaviour and the physical ageing process of such materials are paradigmatic examples. The present volume, primarily intended as introduction and reference, collects six extensive lectures addressing selected experimental and theoretical issues in the field of glassy systems.

Glass Transition on Cooling and Aging for Structural Glasses

Glass Transition on Cooling and Aging for Structural Glasses
Author: Hiroshi Kobayashi
Publisher: Eliva Press
Total Pages: 0
Release: 2023-01-12
Genre:
ISBN: 9789994985494

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Glass is out of equilibrium and reduces into an equilibrium solid. This whole process is a thermodynamical phase transition, while the so-called glass transition is an observable transition with no changes in structure. We describe that the glass transition is a purely kinetic phenomenon due to strong fluctuations in molecular configurations in supercooled liquid. Intermediate-range orders (IROs) have important roles on the glass transition process which is explained by the embryo and freezing of IROs. We conclude that the glass transition is an emergence of a new system of glass in a nonequilibrium state and a glass is a nanomaterial which is composed of a periodic nano-structure of IROs. The mean field theory introduced the random first order transition (RFOT) as the ideal glass transition which prevents the Kauzmann paradox. Recently, an ideal glass was realized using silicate glass during long aging below the Kauzmann temperature. An ideal glass is a nanomaterial which is composed of a periodic nano-structure of intermediate-range orders in an amorphous phase. The results identified the (spontaneous) dissipative structure as an equilibrium state of an ideal glass. An ideal glass is a temporal steady state toward the ground state of materials, which is a polycrystal.

Glasses and the Glass Transition

Glasses and the Glass Transition
Author: Ivan S. Gutzow
Publisher: John Wiley & Sons
Total Pages: 360
Release: 2011-04-27
Genre: Technology & Engineering
ISBN: 3527636544

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Written by renowned researchers in the field, this up-to-date treatise fills the gap for a high-level work discussing current materials and processes. It covers all the steps involved, from vitrification, relaxation and viscosity, right up to the prediction of glass properties, paving the way for improved methods and applications. For solid state physicists and chemists, materials scientists, and those working in the ceramics industry. With a preface by L. David Pye and a foreword by Edgar D. Zanotto

Polymer Glasses

Polymer Glasses
Author: Connie B. Roth
Publisher: CRC Press
Total Pages: 587
Release: 2016-12-12
Genre: Science
ISBN: 1315305135

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"the present book will be of great value for both newcomers to the field and mature active researchers by serving as a coherent and timely introduction to some of the modern approaches, ideas, results, emerging understanding, and many open questions in this fascinating field of polymer glasses, supercooled liquids, and thin films" –Kenneth S. Schweizer, Morris Professor of Materials Science & Engineering, University of Illinois at Urbana-Champaign (from the Foreword) This book provides a timely and comprehensive overview of molecular level insights into polymer glasses in confined geometries and under deformation. Polymer glasses have become ubiquitous to our daily life, from the polycarbonate eyeglass lenses on the end of our nose to large acrylic glass panes holding water in aquarium tanks, with advantages over glass in that they are lightweight and easy to manufacture, while remaining transparent and rigid. The contents include an introduction to the field, as well as state of the art investigations. Chapters delve into studies of commonalities across different types of glass formers (polymers, small molecules, colloids, and granular materials), which have enabled microscopic and molecular level frameworks to be developed. The authors show how glass formers are modeled across different systems, thereby leading to treatments for polymer glasses with first-principle based approaches and molecular level detail. Readers across disciplines will benefit from this topical overview summarizing the key areas of polymer glasses, alongside an introduction to the main principles and approaches.

Handbook of Thermal Analysis and Calorimetry

Handbook of Thermal Analysis and Calorimetry
Author:
Publisher: Elsevier
Total Pages: 862
Release: 2018-03-12
Genre: Technology & Engineering
ISBN: 0444640630

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Handbook of Thermal Analysis and Calorimetry: Recent Advances, Techniques and Applications, Volume Six, Second Edition, presents the latest in a series that has been well received by the thermal analysis and calorimetry community. This volume covers recent advances in techniques and applications that complement the earlier volumes. There has been tremendous progress in the field in recent years, and this book puts together the most high-impact topics selected for their popularity by new editors Sergey Vyazovkin, Nobuyoshi Koga and Christoph Schick—all editors of Thermochimica Acta. Among the important new techniques covered are biomass conversion; sustainable polymers; polymer nanocompsoties; nonmetallic glasses; phase change materials; propellants and explosives; applications to pharmaceuticals; processes in ceramics, metals, and alloys; ionic liquids; fast-scanning calorimetry, and more. Features 19 all-new chapters to bring readers up to date on the current status of the field Provides a broad overview of recent progress in the most popular techniques and applications Includes chapters authored by a recognized leader in each field and compiled by a new team of editors, each with at least 20 years of experience in the field of thermal analysis and calorimetry Enables applications across a wide range of modern materials, including polymers, metals, alloys, ceramics, energetics and pharmaceutics Overviews the current status of the field and summarizes recent progress in the most popular techniques and applications

The Glass Transition

The Glass Transition
Author: E. Donth
Publisher: Springer Science & Business Media
Total Pages: 433
Release: 2013-04-17
Genre: Science
ISBN: 3662043653

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Describes and interrelates the following processes: cooperative alpha processes in a cold liquid, structural relaxation in the glass near Tg, the Johari-Goldstein beta process, the Williams-Götze process in a warm liquid, fast nonactivated cage rattling and boson peak, and ultraslow Fischer modes.

Thermodynamic and Kinetic Aspects of the Vitreous State

Thermodynamic and Kinetic Aspects of the Vitreous State
Author: S.V. Nemilov
Publisher: CRC Press
Total Pages: 222
Release: 2018-01-18
Genre: Science
ISBN: 1351085735

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This is the first book to logically present the major problems of the vitreous state within the framework of irreversible thermodynamics. Filled with elementary explanations for difficult problems, this easily understood text/reference treats in detail the criteria of glass transition, the peculiarities of relaxing structural parameters, and the Prigogine-Defay ratio. Based on the author's rigorous generalization of the Second Law for non-equilibrium, the book systematizes all known thermodynamic data for glasses and melts. The thermodynamic essence of structural relaxation and memory effects are considered. The viscous flow theories are treated as a constituent of the kinetic description. All theoretical questions are illustrated by comparison of calculations with the experiments for glasses of inorganic and organic nature, with special attention to structural classification. An informative review of modern structural investigations is included. The bibliography follows the history of the main problems from the nineteenth century.