Homogeneous Catalysis with Metal Complexes

Homogeneous Catalysis with Metal Complexes
Author: Gheorghe Duca
Publisher: Springer Science & Business Media
Total Pages: 484
Release: 2012-06-15
Genre: Science
ISBN: 364224629X

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The book about homogeneous catalysis with metal complexes deals with the description of the reductive-oxidative, metal complexes in a liquid phase (in polar solvents, mainly in water, and less in nonpolar solvents). The exceptional importance of the redox processes in chemical systems, in the reactions occuring in living organisms, the environmental processes, atmosphere, water, soil, and in industrial technologies (especially in food-processing industries) is discussed. The detailed practical aspects of the established regularities are explained for solving the specific practical tasks in various fields of industrial chemistry, biochemistry, medicine, analytical chemistry and ecological chemistry. The main scope of the book is the survey and systematization of the latest advances in homogeneous catalysis with metal complexes. It gives an overview of the research results and practical experience accumulated by the author during the last decade.

Catalysis by Polymer-Immobilized Metal Complexes

Catalysis by Polymer-Immobilized Metal Complexes
Author: Anatoly D. Pomogailo
Publisher: CRC Press
Total Pages: 424
Release: 2020-08-18
Genre: Science
ISBN: 1000124711

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Deals with a new and promising field developed during the last two decades on the boundary between homogeneous and heterogeneous catalysis. This book presents general information on catalysis for a wide range of organic reactions, e.g., hydrogenation and oxidation reactions, and polymerization transformations. Special attention is paid to electro- and photochemical stimulation of catalytic processes in the presence of immobilized metal complexes. Other topics covered are the quantitative data on the comparison of catalyses by mobile and immobilized metal complexes; main factors affecting the activity of these catalytic systems and methods of optimizing their control; and specific problems of catalysis by fixed complexes (e.g., ligand exchange and electron transfer in metal polymer systems, macromolecular effects and polyfunctional catalysis).

Advances in Catalysis

Advances in Catalysis
Author:
Publisher: Academic Press
Total Pages: 417
Release: 1980-01-23
Genre: Technology & Engineering
ISBN: 0080565328

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Advances in Catalysis

Bioinspired Catalysis

Bioinspired Catalysis
Author: Wolfgang Weigand
Publisher: John Wiley & Sons
Total Pages: 438
Release: 2014-11-24
Genre: Science
ISBN: 3527333088

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This book provides an overview of bioinspired metal-sulfur catalysis by covering structures, activities and model complexes of enzymes exhibiting metal sulphur moieties in their active center.

Early Main Group Metal Catalysis

Early Main Group Metal Catalysis
Author: Sjoerd Harder
Publisher: John Wiley & Sons
Total Pages: 400
Release: 2020-04-06
Genre: Technology & Engineering
ISBN: 3527344489

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Early Main Group Metal Catalysis gives a comprehensive overview of catalytic reactions in the presence of group 1 and group 2 metals. Chapters are ordered to reaction type, contain educational elements and deal with concepts illustrated by examples that cover the main developments. After a short introduction on polar organometallic chemistry and synthesis of early main group metal complexes, a variety of catalytic reactions are described, e.g. polymerization of alkenes, hydroamination and phosphination reactions, hydrosilylation, hydroboration and hydrogenation catalysis, as well as enantioselective and Lewis-acid catalysis. The book addresses organic chemists and researchers in industry interested in the state-of-the-art and new possibilities of early main group metal catalysis as well as newcomers to the field. Written by a team of leaders in the field, it is a very welcome addition to the area of main group metal chemistry, and to the field of catalysis.

Catalysis by Di- and Polynuclear Metal Cluster Complexes

Catalysis by Di- and Polynuclear Metal Cluster Complexes
Author: Richard D. Adams
Publisher: Wiley-VCH
Total Pages: 586
Release: 1998-03-16
Genre: Science
ISBN:

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A pioneer work on catalysis of organic chemical reactions involving multinuclear metal complexes. Catalysis by Di- and Polynuclear Metal Cluster Complexes surveys the latest developments at the frontier of this exciting field, combining theory with new and original examples of catalytic processes produced by polynuclear metal complexes. An invaluable resource for inorganic and organometallic chemists in industry and R&D, it contains chapters from world experts and scholars on: Concepts and models for characterizing homogeneous reactions catalyzed by transition metal cluster complexes Activation of ruthenium clusters for use in catalysis Catalysis by mixed metal clusters containing gold phosphine groupings Catalysis by sulfido bridged dimolybdenum complexes Dimolybdenum and ditungsten complexes Synthesis of organic compounds catalyzed by transition metal clusters Catalysis with dirhodium (II) complexes Catalytic synthesis of polythioether macrocycles Catalysis of Rh, Rh-Co, and Ir-Co multinuclear complexes and its applications to organic syntheses Bimetallic hydroformylation catalysis Catalysis by colloids Catalysis with palladium clusters Heterometallic clusters for heterogeneous catalysis Supported clusters in catalysis.

New Horizons in Modern Catalysis: Five Different Perspectives

New Horizons in Modern Catalysis: Five Different Perspectives
Author:
Publisher: Elsevier
Total Pages: 196
Release: 2023-11-24
Genre: Science
ISBN: 0443186723

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New Horizons in Modern Catalysis: Six Different Perspectives, Volume 72 in the Advances in Catalysis series, highlights new advances in the field, with this new volume presenting interesting chapters on Carbanion-functionalized phosphines: New design elements for catalyst development, Molecular Electrocatalysts for Organic Electrosynthesis, Mechanistic aspects of secondary sphere modification in organocatalysis, Earth-Abundant Transition Metal-Catalyzed reactions with Iodine(III) reagents: from catalysis to mechanistic studies, Design of metal nanoparticles for better performance in catalysis, and Computational design of industrially relevant enzymes. Provides the authority and expertise of leading contributors from an international board of authors Presents the latest release in the Advances in Catalysis series Acts as a comprehensive platform for experimental and theoretical researchers

New and Future Developments in Catalysis

New and Future Developments in Catalysis
Author: Liang Zhang
Publisher: Elsevier Inc. Chapters
Total Pages: 38
Release: 2013-07-11
Genre: Science
ISBN: 0128082283

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Homogeneous Catalysis with Metal Complexes

Homogeneous Catalysis with Metal Complexes
Author: Oleg N. Temkin
Publisher: John Wiley & Sons
Total Pages: 963
Release: 2012-02-08
Genre: Science
ISBN: 1119966825

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Homogeneous catalysis by soluble metal complexes has gained considerable attention due to its unique applications and features such as high activity and selectivity. Catalysis of this type has demonstrated impressive achievements in synthetic organic chemistry and commercial chemical technology. Homogeneous Catalysis with Metal Complexes: Kinetic Aspects and Mechanisms presents a comprehensive summary of the results obtained over the last sixty years in the field of the kinetics and mechanisms of organic and inorganic reactions catalyzed with metal complexes. Topics covered include: Specific features of catalytic reaction kinetics in the presence of various mono- and polynuclear metal complexes and nanoclusters Multi-route mechanisms and the methods of their identification, as well as approaches to the kinetics of polyfunctional catalytic systems Principles and features of the dynamic behavior of nonlinear kinetic models The potential, achievements, and limitations of applying the kinetic approach to the identification of complex reaction mechanisms The development of a rational strategy for designing kinetic models The kinetic models and mechanisms of many homogeneous catalytic processes employed in synthetic and commercial chemistry Written for specialists in the field of kinetics and catalysis, this book is also relevant for post-graduates engaged in the study