Studies On The Hydrolysis Of Metal Ions Potentiometric Study Of The Argentatei Complex In Alkaline Solution
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Author | : P. J. Antikainen |
Publisher | : |
Total Pages | : 18 |
Release | : 1959 |
Genre | : |
ISBN | : |
Download Studies on the Hydrolysis of Metal Ions. Potentiometric Study of the Argentate(i) Complex in Alkaline Solution Book in PDF, Epub and Kindle
The composition of the argentate(I) complex formed in alkaline solutions of silver oxide has been studied by emf titrations with constant ionic medium (0.95 and 12.6 M NaOH, 1.15 and 11.5 M KOH) using Ag-AgI electrodes. The data indicate that only mononuclear complexes are formed; from this result, together with the solubility data of other workers, it is concluded that the formula of the complex is Ag(OH)2( - ). No evidence has been found for the presence of the polynuclear argentate complexes proposed by some previous workers. The solubility product of Ag2O(s) in 3 M Na(ClO4) at 25C was determined as log K(sO) = log (Ag(+) conc.)(OH( - ) conc.) = -7.42 AG(OH)2( - ). (Author).
Author | : Paul L. Brown |
Publisher | : John Wiley & Sons |
Total Pages | : 954 |
Release | : 2016-05-31 |
Genre | : Science |
ISBN | : 3527330100 |
Download Hydrolysis of Metal Ions Book in PDF, Epub and Kindle
Filling the need for a comprehensive treatment that covers the theory, methods and the different types of metal ion complexes with water (hydrolysis), this handbook and ready reference is authored by a nuclear chemist from academia and an industrial geochemist. The book includes both cation and anion complexes, and approaches the topic of metal ion hydrolysis by first covering the background, before proceeding with an overview of the dissociation of water and then all different metal-water hydrolysis complexes and compounds. A must-have for scientists in academia and industry working on this interdisciplinary topic.
Author | : George Biedermann |
Publisher | : |
Total Pages | : 10 |
Release | : 1960 |
Genre | : |
ISBN | : |
Download Studies on the Hydrolysis of Metal Ions. Part 34. the Hydrolysis of the Indium(iii)ion, In(3+), in 3 M (na(+)) Cl ( - )medium Book in PDF, Epub and Kindle
The hydrolysis equilibria of In(III) were studied at 25C in the ionic medium 3 M(Na(+)Cl( - ) by measuring the hydrogen ion concentration with a glass electrode. The (In(III)) ranged from 0.001 to 0.04 M, and the hydrogen ion concentration was varied from values high enough for the hydrolysis to be negligible to those low enough for a precipitate to be formed. Comparison with the equilibrium constants for the formation of the species InOH(2+) and In(OH)2(4+) in 3 M(Na(+))Cl4( - ) indicates that in 3 M (Na(+)Cl( - ) medium the species denoted by the collective formulas 'InOH(2+)' and In(OH)2(4+) are in reality mainly mixed Cl( - )-OH( - ) complexes (just as 'In(3+)' denotes mainly Cl( - ) complexes). (Author).
Author | : Paul Leslie Brown |
Publisher | : |
Total Pages | : 512 |
Release | : 1984 |
Genre | : Hydrolysis |
ISBN | : |
Download Studies on the Hydrolysis of Metal Ions Book in PDF, Epub and Kindle
Author | : Amelia Boon Hoo |
Publisher | : |
Total Pages | : 60 |
Release | : 2006 |
Genre | : |
ISBN | : |
Download Study on the Hydrolysis of Some Iron (II) Complexes in Alkaline Solution Book in PDF, Epub and Kindle
Author | : Åke Olin |
Publisher | : |
Total Pages | : 19 |
Release | : 1961 |
Genre | : Hydrolysis |
ISBN | : |
Download Studies on the hydrolysis of metal ions Book in PDF, Epub and Kindle
Author | : Pier Roberto Danesi |
Publisher | : |
Total Pages | : 32 |
Release | : 1966 |
Genre | : |
ISBN | : |
Download Studies on the hydrolysis of metal ions 57 Book in PDF, Epub and Kindle
Author | : Cotton Terence Hewitt |
Publisher | : |
Total Pages | : 112 |
Release | : 1962 |
Genre | : Hydrolysis |
ISBN | : |
Download The Hydrolysis Of Metal Ions In Aqueous Solution Book in PDF, Epub and Kindle
Author | : George Biedermann |
Publisher | : |
Total Pages | : 20 |
Release | : 1961 |
Genre | : |
ISBN | : |
Download Studies on the Hydrolysis of Metal Ions, Part 35. the Hydrolysis of the Lanthanum Ion, La3+. Book in PDF, Epub and Kindle
The hydrolysis equilibria of the La(III) ion have been studied at 25C by hydrogen ion concentration measurements, using a glass electrode. The total (La(III)) was varied between 0.1 and 1.0 M, whilst the concentration of the ClO4- ion was held constant at 3 M by the addition of LiClO4. The experimental conditions necessary for accurate results to be obtained, when the hydrolysis equilibria must be studied in poorly buffered solutions, are discussed in some detail.