Olefins Polymerization Reactivity of Niobium-Based Metal Complexes

Olefins Polymerization Reactivity of Niobium-Based Metal Complexes
Author: Yogesh Raghunath Patil
Publisher: LAP Lambert Academic Publishing
Total Pages: 192
Release: 2011-09
Genre:
ISBN: 9783846510292

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This book describes the synthesis and characterization of niobium-based metal complexes and their usefulness as catalysts for the polymerization of ethylene, norbornene, beta pinene and vinyl monomers. The polymerization of above described monomers was studied using niobium complexes based on N, N dialkylcarbamates, mixed chloro alkoxides, simple oxygen-containing ligands and the starting material for the preparation of such derivatives, i.e. NbCl5.Niobium N, N-dialkylcarbamates exhibited high activity for polymerization of ethylene when activated with TMA-depleted MAO and 1,2-dichloroethane as activator working at 1 bar ethylene pressure. These novel catalytic systems resulted very active in Ring-opening metathesis polymerization (ROMP) of norbornene (NBE)with the highest activity never reported up to now for any transition metal catalysts. The dinuclear niobium compounds and simple oxygen-containing derivatives of niobium pentachloride were tested for ethylene polymerization and produced satisfactory results.In this context, it was found that easily accessible NbCl5 works as an excellent catalyst for the polymerization of β-pinene styrene and butylvinyl ethers

Transition Metals and Organometallics as Catalysts for Olefin Polymerization

Transition Metals and Organometallics as Catalysts for Olefin Polymerization
Author: Walter Kaminsky
Publisher: Springer Science & Business Media
Total Pages: 443
Release: 2012-12-06
Genre: Science
ISBN: 3642832768

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More than 30 years after the discovery of transition metals and organometal lics as catalysts for olefin polymerization these catalysts did not have lost their fascination. Since 1953 when Karl Ziegler has discovered the catalytic polymerization of ethylene leading to plastically formable polymers which are mechanically stable up to temperatures of about 100°C, synthetic polymers and rubbers have made their way right into private houses. This discovery has been a main impetus for the fast growing production of plastics. The stereoselective poly merization of propylene and other long-chain a-olefins first detected by Giulio Natta leads to an even broadened field of applications. Another enforcing factor were the developments of Standard Oil of Indiana and Phillipps Petroleum Company who engaged in the polymerization of a-olefins supported molybdenum, cobalt and later on chromium catalysts which clearly indicates the wide variety of suitable systems. This kind of research acknowledged merit when in 1963 the Nobel prize of chemistry was awarded to Ziegler and Natta. Although to a great extent there is a technical application for these catalysts, up to now the nature of the active centres and many reaction mechanisms are not completely known.

Organometallic Reactions and Polymerization

Organometallic Reactions and Polymerization
Author: Kohtaro Osakada
Publisher: Springer
Total Pages: 307
Release: 2014-07-15
Genre: Technology & Engineering
ISBN: 366243539X

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This compilation provides advanced graduate students and researchers with a structured overview of olefin polymerization. Divided into eight chapters written by international experts, this book covers polymerization using various organotransition-metal catalysts, including early and late transition metal complexes, new trends in olefin oligomerization and related reactions. All authors address the historic and scientific backgrounds of the field as well as current research progress and potential for further research. The complete book is designed to present eight independent lectures and, because all authors are well versed in organometallic chemistry, each is based on a profound understanding of the reactions and structures of organotransition metal complexes. This book is an ideal accompaniment for researchers taking courses in olefin polymerization and also serves as a valuable resource for teachers and lecturers of chemistry when planning and researching material for advanced lecture courses.

Olefin Metathesis and Polymerization Catalysts

Olefin Metathesis and Polymerization Catalysts
Author: Yavuz Imamogammalu
Publisher: Springer Science & Business Media
Total Pages: 602
Release: 1990-11-30
Genre: Gardening
ISBN: 9780792310402

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Proceedings of the NATO Advanced Study Institute, Akçay, Turkey, September 10-22, 1989

Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes I

Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes I
Author: Giuliano Giambastiani
Publisher: Springer Science & Business Media
Total Pages: 296
Release: 2011-04-29
Genre: Science
ISBN: 9048138159

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This book highlights key advances that have occurred in the field of olefin conversion in recent years. The role of homogenous transition metal catalysts which contain an imine functionality is emphasized; their potential applications in the processing and upgrade of olefins to a wide variety of commodity products of very high industrial value is also explored. On the threshold of the fiftieth anniversary of the Noble Prize to Ziegler and Natta, this book gives a critical summary of the state of the art developments in the fascinating and rapidly developing field of the olefin polymerization, oligomerization, and co-polymerization catalysis.

Beyond Metallocenes

Beyond Metallocenes
Author: Abhimanyu O. Patil
Publisher:
Total Pages: 272
Release: 2003
Genre: Language Arts & Disciplines
ISBN:

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The past 15 years have witnessed tremendous advances in the design and use of organometallic complexes as precatalysts for olefin polymerization. Most recently, an intense search has been started in next-generation single-site catalysts. New approaches have been taken to ligand design. This research has yielded extraordinary results such as catalysts with activities as high or higher than those of conventional metallocenes, stereospecific and living polymerizations, and amazing new polymer structures such as highly-branched ethylene homopolymers. This volume presents some of the recent disclosures in this exciting and rapidly expanding field, featuring papers by some of the leading investigators.

Organotitanium and Niobium Chemistry. I. Structure and Reactivity of a Titanium Ethylene Complex. II. Reactivity of Decamethyl Niobocene Derivatives

Organotitanium and Niobium Chemistry. I. Structure and Reactivity of a Titanium Ethylene Complex. II. Reactivity of Decamethyl Niobocene Derivatives
Author: Steven Alan Cohen
Publisher:
Total Pages: 294
Release: 1982
Genre: Electronic dissertations
ISBN:

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The synthesis and X-ray diffraction study of bis(pentamethylcyclopentadienyl) ethylene titanium (I) are reported. This complex represents the first example of an isolable ethylene adduct of a group IV metal, a key intermediate in Ziegler-Natta olefin polymerization schemes.

Isospecific Polymerization of Olefins

Isospecific Polymerization of Olefins
Author: Y.V. Kissin
Publisher: Springer
Total Pages: 464
Release: 1985-08-07
Genre: Science
ISBN:

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The discoveries of organometallic catalysts for olefin polymerization by Karl Ziegler and that of stereoregular olefin polymers by Giulio Natta are probably the two most important achievements in the areas of catalysis and polymer chemistry in the second half of this century. They led to the development of a new branch of chemical industry, and to a large volume production of high-density and linear low-density polyethylene, isotactic polypropylene, ethylene-propylene rubbers, isotactic poly I-butene, and poly-4-methyl-l-pentene. These discoveries merited the Nobel prize, which was awarded to K. Ziegler and G. Natta in 1963. The initial works of Ziegler and Natta were followed by an "explosion" of scientific papers and patents covering all aspects of polymerization chemistry, catalyst synthesis, and polymerization kinetics as well as the structural, chemical, physical, and technological characteristics of stereo regular polyolefins, polydienes, and olefin copolymers. It is sufficient to say that in the twenty-five years after the first publications more than 15,000 papers and patents appeared on subjects related to the area. . The development brought about the establishment of several prominent groups of scientists occupied with the study of olefin polymerization. The most important of these were scientific schools in Italy, Germany, England, the United States, Japan, the Soviet Union, Czechoslovakia, and Venezuela. In addition, many major chemical and petrochemical corporations throughout the world established labora tories devoted to the development of the technology of catalyst synthesis and olefin polymerization.

Catalytic Polymerization of Olefins

Catalytic Polymerization of Olefins
Author: T. Keii
Publisher: Elsevier
Total Pages: 505
Release: 1986-04-01
Genre: Technology & Engineering
ISBN: 0080960596

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This book covers the proceedings of a symposium which was attended by researchers from all over the world who reported on and discussed recent advances in the field of catalytic polymerization of olefins. Over two decades have elapsed since the discovery of the Ziegler-Natta catalyst. Tremendous research effort has been aimed at improving this marvelous catalyst. In twenty-five years since the first publication, more than 15,000 papers and patents on the subject and on related subjects have appeared. This effort has yielded new generations of Ziegler-Natta catalysts with superior activity and stereospecificity. The complexities arising from the heterogeneity of the catalyst, however, have hindered understanding of the catalytic processes which take place on the catalyst surface. Nevertheless, many fundamental features of the catalyst system have now been clarified reasonably well. Recently a highly active homogeneous catalytic system has been developed, which is capable of catalyzing even isotactic polymerization of propene. There is no doubt that this finding will not only contribute to our understanding of the detailed mechanism of polymerization but also stimulate the development of various kinds of tailored polymers. Thus this subject will remain of paramount importance in the development of chemistry and polymer science for a long time to come.