Evaluation of Corrosion Inhibitors in Chloride-contaminated Reinforced Concrete

Evaluation of Corrosion Inhibitors in Chloride-contaminated Reinforced Concrete
Author: Roumiana Hristova
Publisher:
Total Pages: 0
Release: 1996
Genre:
ISBN:

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The report describes research to determine the effectiveness of commercial corrosion-inhibiting admixtures on the corrosion of reinforcing steel in chloride contaminated concrete. Domestic and foreign publications were reviewed to locate performance data and current practices related to the use, testing and evaluation of corrosion inhibiting admixtures. The study consisted of identification and evaluation of the currently used corrosion-inhibiting admixtures in the United States and other countries. A list of available corrosion-inhibiting admixtures were appraised. Consideration was given to performance predictability, practicality, cost, and other pertinent factors. Five-year old "lollipop" concrete speciments containing sodium nitrite and dinitrobenzoic acid as corrosion inhibitors, and comparison with control specimens were studied using linear polarization and impedance spectroscopy. All mixes had different amounts of calcium chloride added. An equivalent circuit model considering the physical characteristics of the rebar/concrete interface was used to simulate the impedance spectra. The RC parameters obtained from the impedance simulation, including maximum phase angle shift, surface impedance and capacitive responses, were utilized to characterize the surface corrosion of embedded steel and to evaluate the effect of inhibitors with chloride content. The corrosion current densities determined by impedance measurement were compared with those determined using linear polarization and good agreement between the two methods was obtained.

Evaluation of Two Corrosion Inhibitors Using Two Surface Application Methods for Reinforced Concrete Structures

Evaluation of Two Corrosion Inhibitors Using Two Surface Application Methods for Reinforced Concrete Structures
Author: Stephen R. Sharp
Publisher:
Total Pages: 38
Release: 2004
Genre: Concrete bridges
ISBN:

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This study investigated the use of penetrating corrosion inhibitors to extend the life of existing reinforced concrete bridge decks. The use of assisted (vacuum/pressure injection) and unassisted (diffusion) treatment methods and two inhibitors were evaluated. The inhibitors were FerroGard 903, from Sika Corp., and TPS-II, from Surtreat International. Testing was performed on exposure slabs with 15 lb/yd3 of NaCl in the top layer and no NaCl in the bottom layer. The slab design was a variation of the specimen design provided in ASTM G109, with each slab containing nine steel reinforcing rods instead of three. The exposure slabs had either a uniform cover over the top pieces of steel or an inclined cover over the steel. TPS-II was also evaluated on the deck of a bridge in Orange County, Virginia. The study found that when applied to the concrete surface, neither inhibitor penetrated the concrete to reach the steel reinforcement. The vacuum/pressure injection method showed promise but requires refinement. In addition, based on macro-cell measurements, a sufficient quantity of inhibitor can be injected into the concrete to reduce the charge passed.

Performance Evaluation of Corrosion Inhibitors and Galvanized Steel in Concrete Exposure Specimens

Performance Evaluation of Corrosion Inhibitors and Galvanized Steel in Concrete Exposure Specimens
Author: Jerzy Zemajtis
Publisher:
Total Pages: 80
Release: 1999
Genre: Concrete bridges
ISBN:

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Corrosion inhibitor admixtures (CIA) and galvanized reinforcing steel (GS) are used for the corrosion protection for reinforced concrete bridges. The results of a 3.5-year evaluation of exposure specimens containing CIA from three different manufacturers and GS are presented. The specimens were built to simulate four exposure conditions typical for concrete bridges located in the coastal region or inland where deicing salts are used. The exposure conditions were Horizontal, Vertical, Tidal, and Immersed Zones. The specimens were kept inside the laboratory and were exposed to weekly ponding cycles of 6% sodium chloride solution by weight. The methods used to assess the condition of the specimens included chloride concentration measurements, corrosion potentials, and corrosion rates. Additionally, visual observations were performed for identification of rust stains and cracking on concrete surfaces. The results of chloride testing indicate that the amount of chlorides present at the bar level is more than sufficient to initiate corrosion. Chloride and rapid permeability data indicate no significant difference either in a rate of chloride ingress or in the diffusion coefficients for concretes with and without CIA. Corrosion potentials were the most negative for the Bare Steel (BS) specimen prepared with the Armatec 2000 corrosion inhibitor and generally indicated a 90% probability of active corrosion. Corrosion potentials were similar for the two BS control specimens and the BS specimen prepared with Rheocrete 222 and generally indicated an uncertain probability of corrosion. Corrosion potentials were the least negative for the BS specimen prepared with DCI-S corrosion inhibitor and generally indicated a 90% probability of no corrosion. Rate of corrosion measurements were the highest for the BS control specimens and the one prepared with A2000 and the most recent data suggest corrosion damage in 2 to 10 years. Although early rate of corrosion measurements were higher or about the same as for BS control specimens, recent measurements were slightly lower for the specimen prepared with Rheocrete 222 and suggest corrosion damage in 10 to 15 years. Rate of corrosion measurements were consistently the lowest for the BS specimens prepared with DCI-S and indicate corrosion damage is expected in 10 to 15 years. The corrosion potential and rate of corrosion data indicate that DCI-S is the only CIA evaluated that clearly provides some level of corrosion protection. A direct comparison of the GS specimens to the BS specimens is not possible because the measured potential refers to the zinc oxide and not to the steel. Nevertheless, the potential data agree with the chloride and permeability data, as well as with the visual observations, and indicate the damaging effect of a high concentration of chloride ions on the GS. At low and moderate chloride exposures, however, GS does provide corrosion protection. Recommendations are to continue monitoring until sufficient cracking has occurred in all specimens to provide for making a better estimate of the service lives of CIA and GS used in the construction of concrete bridge components in Virginia. The specimens with CIA and one control (continuous reinforcement in the legs) should be taken to the Hampton Road North Tunnel Island and placed in the brackish water to a depth of the Immersed Zone at low tide for further exposure to chloride. The specimens with GS and the other control (non-continuous reinforcement in the legs) should remain in an outdoor exposure in Southwest Virginia like the Civil Engineering Materials Research Laboratory in Blacksburg, Virginia.

Field Evaluation of Corrosion Inhibitors for Concrete

Field Evaluation of Corrosion Inhibitors for Concrete
Author: Michael M. Sprinkel
Publisher:
Total Pages: 58
Release: 1998
Genre: Epoxy coatings
ISBN:

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One hundred and fifty-six exposure slabs have been constructed with and without a variety of combinations of corrosion inhibiting admixtures and topically applied inhibitors. To accelerate corrosion one hundred and thirty-six of the slabs were constructed with concrete that surrounded the top mat of reinforcement with chloride contents of 3,6, 10, and 15 Ib/yd3 (1.8,3.5,5.9, and 8.9 kg/m3). This paper presents the results from measurements made on the slabs in May 1998 after approximately 1 year of exposure. The measurements show that as the chloride ion content in the slabs increases, the macrocell current, macrocell potential, half-cell potential, and rate of corrosion increase and the resistance decreases. Macrocell currents exceed 10 uA, indicating corrosion activity, in slabs cast with chloride in the concrete except those with 3 Ib/yd3 (1.8 kg/m3 ) of chloride that were overlayed and patched or patched. Measurements taken to determine the rate of corrosion indicate high, moderate, low, and passive states of corrosion in 63,22, 12, and 3 percent, respectively, of the slabs. The measurements also show no significant difference between the slabs repaired with and without corrosion inhibitor admixtures and topical treatments. Slabs repaired with 7% silica fume showed half-cell potentials that were less negative than those repaired without silica fume.

An Evaluation of New Inhibitors for Rebar Corrosion in Concrete

An Evaluation of New Inhibitors for Rebar Corrosion in Concrete
Author: Brian D. Chambers
Publisher:
Total Pages: 68
Release: 2003
Genre: Corrosion and anti-corrosives
ISBN:

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The corrosion of reinforcing steel in concrete is estimated to affect more than 50% of the 575,000 bridges in the United States. One approach to mitigating this problem is to use corrosion-inhibitive compounds admixed into the concrete paste. This study sought to examine the corrosion inhibition performance of a series of compounds admixed into high-quality concrete and to delineate the effects of these compounds on the concrete with regard to the corrosion process. A series of eight compounds were admixed into Type A4 concrete. The compounds tested were aminoethylethanolamine, aminothiophenol, di-sodium Beta-glycerophosphate, calcium nitrite, di-n-butyl sulfoxide, lithium nitrate, sodium metasilicate, and nitrilotriphosphonic acid. Concrete blocks were cast, into which were placed 0.009-in.-diameter 1040 steel wires. The corrosion rate was assessed via a resistance change measurement (RCM) of these wires over time using a temperature-corrected four-point resistance measurement. The time-to-open circuit for the wires was also monitored. RCM was compared to (1) electrochemical impedance spectroscopy results of tests conducted in a simulated pore solution, and (2) chloride permeability measurements of the concrete as per ASTM C 1202. The effect of the admixtures on the compressive strength and density of the concrete was also assessed. RCM and time-to-open circuit results showed that four test inhibitors had equal or better corrosion prevention at 2 years of testing compared to a widely used commercial mix (DCI). These test inhibitors included di-sodium Beta-glycerophosphate (0.283 mol/cu ft and 0.815 mol/cu ft), aminoethylethanolamine (0.815 mol/cu ft), lithium nitrate (0.815 mol/cu ft), and sodium metasilicate (0.815 mol/cu ft). After 100 weeks, 33% to 44% of the wires were active in concrete admixed with these test compounds, whereas only 25% of the wires were active in concrete admixed with DCI. This research has also shown that the performance of a corrosion inhibitor in high-quality concrete is a function of numerous interrelated factors that are not predicted from any single laboratory test. These tests provide promising results for alternative inhibitive admixtures for standard Type A4 concrete. It is recommended that additional tests be conducted on concrete mixtures containing slag and fly ash using multiple concentrations of the four most promising inhibitors. Further testing may lead to the implementation of a better corrosion-inhibiting admixture, thus increasing the service life of bridges.

Corrosion Inhibitors for Steel in Concrete

Corrosion Inhibitors for Steel in Concrete
Author: Bernhard Elsener
Publisher: CRC Press
Total Pages: 84
Release: 2001
Genre: Business & Economics
ISBN:

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The use of inhibitors for rehabilitation of reinforced concrete structures is a new field of application and this new volume provides a State of the Art Report on this subject. Corrosion of steel in concrete is one of the major problems for infrastructure such as bridges, tunnels, housing etc. since it leads to spalling of the concrete and loss in cross section of the steel that may cause structural and safety problems. The steel in concrete generally resists corrosion as a result of a passive layer that develops on the metal surface in the alkaline environment of the concrete. Corrosion can occur if these conditions are disturbed, for example, in the presence of chlorides or with carbonation of concrete. Traditional repair methods consist in removing the deteriorated concrete and replacing it but these can be laborious, noisy and very costly. To avoid these disadvantages new methods have been developed in recent years. These include electrochemical procedures and, increasingly, the use of inhibitors. The use of inhibitors for rehabilitation of reinforced concrete structures is a new field of application and this new volume provides a State of the Art Report on this subject.The report, under the editorship of Prof. Bernhard Elsener, was prepared by a Task Group of the EFC Working Party on Corrosion of Reinforcement in Concrete. In a literature review it describes inorganic and organic chemicals that have been proposed and examined as well as the commercial corrosion inhibitors that are available on the market. Protection mechanism and possible effects of inhibitors on concrete properties are described. Practical experience with inhibitors for steel in concrete and the long term effectiveness are considered. The various test methods for evaluating the behaviour of the inhibitors are described and critically assessed. In a rapidly evolving field this State of the Art Report, based mainly on independent not commercial literature, will be of value to corrosion engineers and civil engineers concerned with maintenance and repair of reinforced concrete structures.

Corrosion Inhibitors, Principles and Recent Applications

Corrosion Inhibitors, Principles and Recent Applications
Author: Mahmood Aliofkhazraei
Publisher: BoD – Books on Demand
Total Pages: 264
Release: 2018-04-04
Genre: Technology & Engineering
ISBN: 9535139177

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To protect metals or alloys from corrosion, some methods can be used such as isolating the structure from the aggressive media or compensating the loss of electrons from the corroded structure. The use of corrosion inhibitors may include organic and inorganic compounds that adsorb on the metallic structure to isolate it from its surrounding media to decrease oxidation-reduction processes. This book collects new developments about corrosion inhibitors and their recent applications.

Evaluation of Corrosion Inhibitors for Concrete Bridge Deck Patches and Overlays

Evaluation of Corrosion Inhibitors for Concrete Bridge Deck Patches and Overlays
Author: Michael M. Sprinkel
Publisher:
Total Pages: 33
Release: 2003
Genre: Concrete
ISBN:

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This report presents the results to date of a national pooled fund study initiated in August 1996 to evaluate the long-term performance of bridges and outdoor exposure slabs damaged by chloride-induced corrosion that have concrete containing corrosion inhibiting admixtures and that had topical applications of inhibitors prior to being patched and overlaid. The study includes 156 exposure slabs, 4 bridge decks with overlays, and 1 patched bridge substructure. A total of 136 exposure slabs were constructed to simulate overlay and patch repairs, and 20 full-depth slabs were constructed to simulate new construction. Each repaired slab was constructed with one of four levels of chloride to cause corrosion. The new slabs were ponded to cause corrosion. Previous reports provide details on the construction and initial condition of the exposure slabs and the construction and initial condition of the repaired bridges. The results presented here are based on quarterly nondestructive measurements between September 1997 and June 2001, visual inspections of the exposure slabs, and tensile bond test results and visual inspections of reinforcement removed from the exposure slabs that were patched and overlaid. Overlays cracked and delaminated on exposure slabs that were fabricated with 15 lb/yd3 of chloride ion because of corrosion of the top mat of reinforcement. There was no difference in the performance of overlays constructed with and without inhibitors and topical treatments. Overlays and patches with and without inhibitor treatments placed on and in slabs with 3, 6, and 10 lb/yd3 of chloride are performing satisfactorily. However, results do not show reductions in the tendency for corrosion that can be attributed to the inhibitors. Overlays and patches with and without inhibitor treatments on and in the five bridges indicate mixed results. Corrosion is occurring in the majority of the repairs done with and without inhibitor treatments. The corrosion-inhibiting treatments do not seem to be reducing corrosion in the bridges and, in fact, may be increasing corrosion. It is not obvious that corrosion is occurring in the full-depth slabs constructed with and without inhibitors to represent new construction. The slabs do not show signs of corrosion-induced cracking after 5 years of ponding. Topical applications of inhibitors did not affect the bond strength of the overlays. Overlays containing Rheocrete 222+ and 7 percent silica fume had lower bond strengths. Overlays on base concretes with the higher chloride content had lower bond strengths. In summary, this project does not show any benefit from the use of the corrosion inhibiting admixtures and the topical applications made to the chloride-contaminated concrete surfaces prior to placement of the patches and overlays. Additional years of monitoring of the exposure slabs and bridges may provide useful results.