Mössbauer Spectroscopy and Transition Metal Chemistry

Mössbauer Spectroscopy and Transition Metal Chemistry
Author: P. Gütlich
Publisher: Springer Science & Business Media
Total Pages: 292
Release: 2013-11-11
Genre: Science
ISBN: 3662125455
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Two decades have passed since the original discovery of recoilless nuclear gamma resonance by Rudolf Mossbauer; the spectroscopic method based on this resonance effect - referred to as Mossbauer spectroscopy - has developed into a powerful tool in solid-state research. The users are chemists, physicists, biologists, geologists, and scientists from other disciplines, and the spectrum of problems amenable to this method has become extraordinarily broad. In the present volume we have confined ourselves to applications of Mossbauer spectroscopy to the area of transition elements. We hope that the book will be useful not only to non-Mossbauer special ists with problem-Oriented activities in the chemistry and physics of transition elements, but also to those actively working in the field of Mossbauer spectroscopy on systems (compounds as well as alloys) of transition elements. The first five chapters are directed to introducing the reader who is not familiar with the technique to the principles of the recoilless nuclear resonance effect, the hyperfme interactions between nuclei and electronic properties such as electric and magnetic fields, some essential aspects about measurements, and the evaluation of Moss bauer spectra. Chapter 6 deals with the interpretation of Mossbauer parameters of iron compounds. Here we have placed emphasis on the information about the electronic structure, in correlation with quantum chemical methods, because of its importance for chemical bonding and magnetic properties.

Applications of Mossbauer Spectroscopy

Applications of Mossbauer Spectroscopy
Author: Richard L. Cohen
Publisher: Elsevier
Total Pages: 363
Release: 2012-12-02
Genre: Science
ISBN: 0323154093
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Applications of Mössbauer Spectroscopy, Volume I is a collection of essays that discusses the research performed using Mössbauer spectroscopy. The book presents the effect of some stabilizers of polyethylene. It demonstrates the polymerization processes and structure of catalytically active centers. The text also describes the chemical processes in butyl rubber vulcanization. It discusses the experimental studies of iron transport proteins and the thermal decomposition of solids. The section that follows describes the paramagnetic hyperfine structure. The book will provide valuable insights for scientists, chemists, students, and researchers in the field of organic chemistry.

Mossbauer Spectroscopy

Mossbauer Spectroscopy
Author: A. G. Maddock
Publisher: Elsevier
Total Pages: 273
Release: 1997-01-01
Genre: Science
ISBN: 1782420606
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Mossbauer spectroscopy has proved itself a versatile technique, finding applications in diverse areas of science and industry. Starting from physics and chemistry it spread into biochemistry, mineralogy, biochemistry, corrosion science, geochemistry and archaeology, with applications in industrial and scientific research. The author aims to help advanced university students, professionals and research workers who ask the question "what's in it for us?". After a concise account of experimental techniques, he emphasizes those applications in which there are few, if any, alternative ways of obtaining the same information about electron fields and the nuclei. He explains areas of industrial interest, including the important applications related to tin and iron on which there is much activity in research and development, and interprets the extension of Mossbauer techniques to main group, transitional and other suitable elements. Attention is paid to factors which may lead to misinterpretation of spectra and another chapter covers the complexities of interpreting emission spectra. Discusses the appearance of Mossbauer spectroscopy in biochemistry, mineralogy, biochemistry, corrosion science, geochemistry and archaeology, with applications in industrial and scientific research Emphasizes the applications in which there are few, if any, alternative ways of obtaining the same information about electron fields and the nuclei Attention is paid to the complexities of interpreting emission spectra and the factors which may lead to misinterpretation of spectra

Mössbauer Spectroscopy

Mössbauer Spectroscopy
Author: Virender K. Sharma
Publisher: John Wiley & Sons
Total Pages: 1018
Release: 2013-08-13
Genre: Science
ISBN: 1118771974
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Providing a modern update of the field, Mossbauer Spectroscopy focuses on applications across a broad range of fields, including analysis of inorganic elements, nanoparticles, metalloenzymyes, biomolecules (including proteins), glass, coal, and iron. Ideal for a broad range of scientists, this one-stop reference presents advances gained in the field over past two decades, including a detailed theoretical description of Mossbauer spectroscopy, an extensive treatment of Mossbauer spectroscopy in applied areas, and challenges and future opportunities for the further development of this technique.

Mössbauer Spectroscopy

Mössbauer Spectroscopy
Author: Yutaka Yoshida
Publisher: Springer Science & Business Media
Total Pages: 321
Release: 2012-11-08
Genre: Science
ISBN: 3642322204
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Tutorials on Mössbauer Spectroscopy Since the discovery of the Mössbauer Effect many excellent books have been published for researchers and for doctoral and master level students. However, there appears to be no textbook available for final year bachelor students, nor for people working in industry who have received only basic courses in classical mechanics, electromagnetism, quantum mechanics, chemistry and materials science. The challenge of this book is to give an introduction to Mössbauer Spectroscopy for this level. The ultimate goal of this book is to give this audience not only a scientific introduction to the technique, but also to demonstrate in an attractive way the power of Mössbauer Spectroscopy in many fields of science, in order to create interest among the readers in joining the community of Mössbauer spectroscopists. This is particularly important at times where in many Mössbauer laboratories succession is at stake. This book will be used as a textbook for the tutorial sessions, organized at the occasion of the 2011 International Conference on the Application of Mössbauer Spectroscopy (ICAME2011) in Tokyo.

Chemical Mössbauer Spectroscopy

Chemical Mössbauer Spectroscopy
Author: R.H. Herber
Publisher: Springer Science & Business Media
Total Pages: 381
Release: 2012-12-06
Genre: Science
ISBN: 1461324319
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The past twenty five years - roughly the period from 1960 to 1985 - have been by all measures among the most exciting and challenging times of our science. The increasing sensitivity of chemical instrumentation, the introduction of the routine use of computers for data reduction and of microprocessors for instrumental control, the wide-spread utilization of lasers, and the disappearance of traditional disciplinary boundaries between scientific fields are but a few of the examples one could cite to support the introductory contention. Almost all of these developments have had their impact on the development of Mossbauer Effect Spectroscopy into a technique par excellence for the elucidation of problems in all areas of chemistry and its associated sister sciences. Indeed, because this spectroscopy is based on fundamental phenomena in nuclear physics, is described in terms of the theory of the solid state and structural chemistry, is useful in the understanding of chemical reactivity and biological phenomena, and can serve to supplement information developed by many other experimental techniques, it has provided an unparalleled opportunity for the exchange of ideas among practitioners of a very wide variety of subfields of the physical and biological sciences. The present collection of contributions is the direct result of such an interaction.

Principles of Mössbauer Spectroscopy

Principles of Mössbauer Spectroscopy
Author: T. C. Gibb
Publisher: Springer
Total Pages: 262
Release: 2013-11-21
Genre: Technology & Engineering
ISBN: 148993023X
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The emergence of M6ssbauer spectroscopy as an important experi mental technique for the study of solids has resulted in a wide range of applications in chemistry, physics, metallurgy and biophysics. This book is intended to summarize the elementary principles of the technique at a level appropriate to the advanced student or experienced chemist requiring a moderately comprehensive but basically non-mathematical introduction. Thus the major part of the book is concerned with the practical applications of Mossbauer spectroscopy, using carefully selected examples to illustrate the concepts. The references cited and the bibliography are intended to provide a bridge to the main literature for those who subseouent ly require a deeper knowledge. The text is complementary to the longer research monograph, 'Mossbauer Spectroscopy', which was written a few years ago in co-authorship with Professor N.N. Greenwood, and to whom I am deeply indebted for reading the preliminary draft of the present volume. I also wish to thank my many colleagues over the past ten years, and in particular Dr. R. Greatrex, for the many stimu lating discussions which we have had together. However my greatest debt is to my wife, who not only had to tolerate my eccen tricities during the gestation period, but being a chemist herself was also able to provide much useful criticism of the penultirna te draft.

Mössbauer Spectroscopy and Transition Metal Chemistry

Mössbauer Spectroscopy and Transition Metal Chemistry
Author: Philipp Gütlich
Publisher: Springer Science & Business Media
Total Pages: 581
Release: 2010-12-25
Genre: Science
ISBN: 3540884289
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concentrates on teaching techniques using as much theory as needed. application of the techniques to many problems of materials characterization. Mössbauer spectroscopy is a profound analytical method which has nevertheless continued to develop. The authors now present a state-of-the art book which consists of two parts. The first part details the fundamentals of Mössbauer spectroscopy and is based on a book published in 1978 in the Springer series 'Inorganic Chemistry Concepts' by P. Gütlich, R. Link and A.X. Trautwein. The second part covers useful practical aspects of measurements, and the application of the techniques to many problems of materials characterization. The update includes the use of synchroton radiation and many instructive and illustrative examples in fields such as solid state chemistry, biology and physics, materials and the geosciences, as well as industrial applications. Special chapters on magnetic relaxation phenomena (S. Morup) and computation of hyperfine interaction parameters (F. Neese) are also included. The book concentrates on teaching the technique using theory as much as needed and as little as possible. The reader will learn the fundamentals of the technique and how to apply it to many problems of materials characterization. Transition metal chemistry, studied on the basis of the most widely used Mössbauer isotopes, will be in the foreground.